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Aqua­bis­(4-chloro­benzoato)-κ(2) O,O′;κO-bis­(pyridine-κN)cobalt(II)

In the title compound, [Co(C(7)H(4)ClO(2))(2)(C(5)H(5)N)(2)(H(2)O)], the Co(II) atom is six-coordinated by three O atoms from a bidentate and a monodentate 4-chloro­benzoate ligand, two N atoms from two pyridine ligands and a water O atom, giving a distorted octa­hedral geometry. In the crystal, the...

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Detalles Bibliográficos
Autores principales: Chen, Ya-Li, Zhang, Chun-E, Fei, Peng, Deng, Chao, Su, Bi-Tao
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3629487/
https://www.ncbi.nlm.nih.gov/pubmed/23634005
http://dx.doi.org/10.1107/S1600536813006752
Descripción
Sumario:In the title compound, [Co(C(7)H(4)ClO(2))(2)(C(5)H(5)N)(2)(H(2)O)], the Co(II) atom is six-coordinated by three O atoms from a bidentate and a monodentate 4-chloro­benzoate ligand, two N atoms from two pyridine ligands and a water O atom, giving a distorted octa­hedral geometry. In the crystal, the complex mol­ecules are connected by O—H⋯O hydrogen bonds and π–π interactions between the benzene rings [centroid–centroid distance = 3.8924 (17) Å] into a chain along [010]. Between adjacent chains, π–π inter­actions occur between the pyridine rings [centroid–centroid distance = 3.898 (2) Å], giving an overall two-dimensional architecture.