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Aquabis(4-chlorobenzoato)-κ(2) O,O′;κO-bis(pyridine-κN)cobalt(II)
In the title compound, [Co(C(7)H(4)ClO(2))(2)(C(5)H(5)N)(2)(H(2)O)], the Co(II) atom is six-coordinated by three O atoms from a bidentate and a monodentate 4-chlorobenzoate ligand, two N atoms from two pyridine ligands and a water O atom, giving a distorted octahedral geometry. In the crystal, the...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2013
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3629487/ https://www.ncbi.nlm.nih.gov/pubmed/23634005 http://dx.doi.org/10.1107/S1600536813006752 |
| _version_ | 1782266589420191744 |
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| author | Chen, Ya-Li Zhang, Chun-E Fei, Peng Deng, Chao Su, Bi-Tao |
| author_facet | Chen, Ya-Li Zhang, Chun-E Fei, Peng Deng, Chao Su, Bi-Tao |
| author_sort | Chen, Ya-Li |
| collection | PubMed |
| description | In the title compound, [Co(C(7)H(4)ClO(2))(2)(C(5)H(5)N)(2)(H(2)O)], the Co(II) atom is six-coordinated by three O atoms from a bidentate and a monodentate 4-chlorobenzoate ligand, two N atoms from two pyridine ligands and a water O atom, giving a distorted octahedral geometry. In the crystal, the complex molecules are connected by O—H⋯O hydrogen bonds and π–π interactions between the benzene rings [centroid–centroid distance = 3.8924 (17) Å] into a chain along [010]. Between adjacent chains, π–π interactions occur between the pyridine rings [centroid–centroid distance = 3.898 (2) Å], giving an overall two-dimensional architecture. |
| format | Online Article Text |
| id | pubmed-3629487 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2013 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-36294872013-04-30 Aquabis(4-chlorobenzoato)-κ(2) O,O′;κO-bis(pyridine-κN)cobalt(II) Chen, Ya-Li Zhang, Chun-E Fei, Peng Deng, Chao Su, Bi-Tao Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Co(C(7)H(4)ClO(2))(2)(C(5)H(5)N)(2)(H(2)O)], the Co(II) atom is six-coordinated by three O atoms from a bidentate and a monodentate 4-chlorobenzoate ligand, two N atoms from two pyridine ligands and a water O atom, giving a distorted octahedral geometry. In the crystal, the complex molecules are connected by O—H⋯O hydrogen bonds and π–π interactions between the benzene rings [centroid–centroid distance = 3.8924 (17) Å] into a chain along [010]. Between adjacent chains, π–π interactions occur between the pyridine rings [centroid–centroid distance = 3.898 (2) Å], giving an overall two-dimensional architecture. International Union of Crystallography 2013-03-16 /pmc/articles/PMC3629487/ /pubmed/23634005 http://dx.doi.org/10.1107/S1600536813006752 Text en © Chen et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Chen, Ya-Li Zhang, Chun-E Fei, Peng Deng, Chao Su, Bi-Tao Aquabis(4-chlorobenzoato)-κ(2) O,O′;κO-bis(pyridine-κN)cobalt(II) |
| title | Aquabis(4-chlorobenzoato)-κ(2)
O,O′;κO-bis(pyridine-κN)cobalt(II) |
| title_full | Aquabis(4-chlorobenzoato)-κ(2)
O,O′;κO-bis(pyridine-κN)cobalt(II) |
| title_fullStr | Aquabis(4-chlorobenzoato)-κ(2)
O,O′;κO-bis(pyridine-κN)cobalt(II) |
| title_full_unstemmed | Aquabis(4-chlorobenzoato)-κ(2)
O,O′;κO-bis(pyridine-κN)cobalt(II) |
| title_short | Aquabis(4-chlorobenzoato)-κ(2)
O,O′;κO-bis(pyridine-κN)cobalt(II) |
| title_sort | aquabis(4-chlorobenzoato)-κ(2)
o,o′;κo-bis(pyridine-κn)cobalt(ii) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3629487/ https://www.ncbi.nlm.nih.gov/pubmed/23634005 http://dx.doi.org/10.1107/S1600536813006752 |
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