Dichloridobis(1,3-diisopropyl-4,5-di­methyl-1H-imidazol-3-ium-2-thiol­ate-κS)copper(II)

The mol­ecular structure of the title compound, [CuCl(2)(C(11)H(20)N(2)S)(2)], shows the Cu(II) atom with a distorted tetra­hedral geometry from two Cl atoms [Cu—Cl = 2.2182 (6) Å] and two thione S atoms [Cu—S = 2.3199 (6) Å]. The angles at the copper cation, which lies on a twofold rotation axis, a...

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Autores principales: Flörke, Ulrich, Ahmida, Aziza, Schröder, Jörg, Egold, Hans, Henkel, Gerald
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3629488/
https://www.ncbi.nlm.nih.gov/pubmed/23634006
http://dx.doi.org/10.1107/S1600536813006879
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author Flörke, Ulrich
Ahmida, Aziza
Schröder, Jörg
Egold, Hans
Henkel, Gerald
author_facet Flörke, Ulrich
Ahmida, Aziza
Schröder, Jörg
Egold, Hans
Henkel, Gerald
author_sort Flörke, Ulrich
collection PubMed
description The mol­ecular structure of the title compound, [CuCl(2)(C(11)H(20)N(2)S)(2)], shows the Cu(II) atom with a distorted tetra­hedral geometry from two Cl atoms [Cu—Cl = 2.2182 (6) Å] and two thione S atoms [Cu—S = 2.3199 (6) Å]. The angles at the copper cation, which lies on a twofold rotation axis, are Cl—Cu—Cl = 142.84 (4)°, Cl—Cu—S = 94.80 (2) and 99.97 (2)°, and S—Cu—S = 132.46 (4)°. The planes of the two imidazolium rings make a dihedral angle of 76.92 (8)°.
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spelling pubmed-36294882013-04-30 Dichloridobis(1,3-diisopropyl-4,5-di­methyl-1H-imidazol-3-ium-2-thiol­ate-κS)copper(II) Flörke, Ulrich Ahmida, Aziza Schröder, Jörg Egold, Hans Henkel, Gerald Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The mol­ecular structure of the title compound, [CuCl(2)(C(11)H(20)N(2)S)(2)], shows the Cu(II) atom with a distorted tetra­hedral geometry from two Cl atoms [Cu—Cl = 2.2182 (6) Å] and two thione S atoms [Cu—S = 2.3199 (6) Å]. The angles at the copper cation, which lies on a twofold rotation axis, are Cl—Cu—Cl = 142.84 (4)°, Cl—Cu—S = 94.80 (2) and 99.97 (2)°, and S—Cu—S = 132.46 (4)°. The planes of the two imidazolium rings make a dihedral angle of 76.92 (8)°. International Union of Crystallography 2013-03-16 /pmc/articles/PMC3629488/ /pubmed/23634006 http://dx.doi.org/10.1107/S1600536813006879 Text en © Flörke et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Flörke, Ulrich
Ahmida, Aziza
Schröder, Jörg
Egold, Hans
Henkel, Gerald
Dichloridobis(1,3-diisopropyl-4,5-di­methyl-1H-imidazol-3-ium-2-thiol­ate-κS)copper(II)
title Dichloridobis(1,3-diisopropyl-4,5-di­methyl-1H-imidazol-3-ium-2-thiol­ate-κS)copper(II)
title_full Dichloridobis(1,3-diisopropyl-4,5-di­methyl-1H-imidazol-3-ium-2-thiol­ate-κS)copper(II)
title_fullStr Dichloridobis(1,3-diisopropyl-4,5-di­methyl-1H-imidazol-3-ium-2-thiol­ate-κS)copper(II)
title_full_unstemmed Dichloridobis(1,3-diisopropyl-4,5-di­methyl-1H-imidazol-3-ium-2-thiol­ate-κS)copper(II)
title_short Dichloridobis(1,3-diisopropyl-4,5-di­methyl-1H-imidazol-3-ium-2-thiol­ate-κS)copper(II)
title_sort dichloridobis(1,3-diisopropyl-4,5-di­methyl-1h-imidazol-3-ium-2-thiol­ate-κs)copper(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3629488/
https://www.ncbi.nlm.nih.gov/pubmed/23634006
http://dx.doi.org/10.1107/S1600536813006879
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