Diaqua­bis­{5-(pyridin-2-yl-κN)-3-[4-(pyri­din-4-yl)phenyl]-1H-1,2,4-triazol-1-ido-κN (1)}zinc

The asymmetric unit of the title compound, [Zn(C(18)H(12)N(5))(2)(H(2)O)(2)], consists a Zn(II) ion, located on an inversion center, a deprotonated 5-pyridin-2-yl-3-[4-(pyridin-4-yl)phen­yl]-1H-1,2,4-triazol-1-ido ligand and a water mol­ecule. The whole mol­ecule is generated by inversion symmetry....

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Detalles Bibliográficos
Autor principal: Li, Bin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3629490/
https://www.ncbi.nlm.nih.gov/pubmed/23634008
http://dx.doi.org/10.1107/S1600536813005916
Descripción
Sumario:The asymmetric unit of the title compound, [Zn(C(18)H(12)N(5))(2)(H(2)O)(2)], consists a Zn(II) ion, located on an inversion center, a deprotonated 5-pyridin-2-yl-3-[4-(pyridin-4-yl)phen­yl]-1H-1,2,4-triazol-1-ido ligand and a water mol­ecule. The whole mol­ecule is generated by inversion symmetry. The Zn(II) ion has a distorted octa­hedral coordination geometry, defined by four N atoms from the two deprotonated organic ligands and two water O atoms. In the crystal, O—H⋯N hydrogen bonds link the mol­ecules, forming a three-dimensional network.

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