Diaqua­bis­{5-(pyridin-2-yl-κN)-3-[4-(pyri­din-4-yl)phenyl]-1H-1,2,4-triazol-1-ido-κN (1)}zinc

The asymmetric unit of the title compound, [Zn(C(18)H(12)N(5))(2)(H(2)O)(2)], consists a Zn(II) ion, located on an inversion center, a deprotonated 5-pyridin-2-yl-3-[4-(pyridin-4-yl)phen­yl]-1H-1,2,4-triazol-1-ido ligand and a water mol­ecule. The whole mol­ecule is generated by inversion symmetry....

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Detalles Bibliográficos
Autor principal: Li, Bin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3629490/
https://www.ncbi.nlm.nih.gov/pubmed/23634008
http://dx.doi.org/10.1107/S1600536813005916
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author Li, Bin
author_facet Li, Bin
author_sort Li, Bin
collection PubMed
description The asymmetric unit of the title compound, [Zn(C(18)H(12)N(5))(2)(H(2)O)(2)], consists a Zn(II) ion, located on an inversion center, a deprotonated 5-pyridin-2-yl-3-[4-(pyridin-4-yl)phen­yl]-1H-1,2,4-triazol-1-ido ligand and a water mol­ecule. The whole mol­ecule is generated by inversion symmetry. The Zn(II) ion has a distorted octa­hedral coordination geometry, defined by four N atoms from the two deprotonated organic ligands and two water O atoms. In the crystal, O—H⋯N hydrogen bonds link the mol­ecules, forming a three-dimensional network.
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spelling pubmed-36294902013-04-30 Diaqua­bis­{5-(pyridin-2-yl-κN)-3-[4-(pyri­din-4-yl)phenyl]-1H-1,2,4-triazol-1-ido-κN (1)}zinc Li, Bin Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, [Zn(C(18)H(12)N(5))(2)(H(2)O)(2)], consists a Zn(II) ion, located on an inversion center, a deprotonated 5-pyridin-2-yl-3-[4-(pyridin-4-yl)phen­yl]-1H-1,2,4-triazol-1-ido ligand and a water mol­ecule. The whole mol­ecule is generated by inversion symmetry. The Zn(II) ion has a distorted octa­hedral coordination geometry, defined by four N atoms from the two deprotonated organic ligands and two water O atoms. In the crystal, O—H⋯N hydrogen bonds link the mol­ecules, forming a three-dimensional network. International Union of Crystallography 2013-03-16 /pmc/articles/PMC3629490/ /pubmed/23634008 http://dx.doi.org/10.1107/S1600536813005916 Text en © Bin Li 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Li, Bin
Diaqua­bis­{5-(pyridin-2-yl-κN)-3-[4-(pyri­din-4-yl)phenyl]-1H-1,2,4-triazol-1-ido-κN (1)}zinc
title Diaqua­bis­{5-(pyridin-2-yl-κN)-3-[4-(pyri­din-4-yl)phenyl]-1H-1,2,4-triazol-1-ido-κN (1)}zinc
title_full Diaqua­bis­{5-(pyridin-2-yl-κN)-3-[4-(pyri­din-4-yl)phenyl]-1H-1,2,4-triazol-1-ido-κN (1)}zinc
title_fullStr Diaqua­bis­{5-(pyridin-2-yl-κN)-3-[4-(pyri­din-4-yl)phenyl]-1H-1,2,4-triazol-1-ido-κN (1)}zinc
title_full_unstemmed Diaqua­bis­{5-(pyridin-2-yl-κN)-3-[4-(pyri­din-4-yl)phenyl]-1H-1,2,4-triazol-1-ido-κN (1)}zinc
title_short Diaqua­bis­{5-(pyridin-2-yl-κN)-3-[4-(pyri­din-4-yl)phenyl]-1H-1,2,4-triazol-1-ido-κN (1)}zinc
title_sort diaqua­bis­{5-(pyridin-2-yl-κn)-3-[4-(pyri­din-4-yl)phenyl]-1h-1,2,4-triazol-1-ido-κn (1)}zinc
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3629490/
https://www.ncbi.nlm.nih.gov/pubmed/23634008
http://dx.doi.org/10.1107/S1600536813005916
work_keys_str_mv AT libin diaquabis5pyridin2ylkn34pyridin4ylphenyl1h124triazol1idokn1zinc

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