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Tetra­aqua­bis­(3,5-dinitro­benzoato-κO (1))magnesium tetra­hydrate

In the structure of the title compound, [Mg(C(7)H(3)N(2)O(6))(2)(H(2)O)(4)]·4H(2)O, the slightly distorted octa­hedral MgO(6) coord­in­ation polyhedron comprises two trans-related carboxyl­ate O-atom donors from mononodentate 3,5-dinitro­benzoate ligands, and four water mol­ecules. The coordinating...

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Detalles Bibliográficos
Autor principal: Smith, Graham
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3629491/
https://www.ncbi.nlm.nih.gov/pubmed/23634009
http://dx.doi.org/10.1107/S160053681300682X
Descripción
Sumario:In the structure of the title compound, [Mg(C(7)H(3)N(2)O(6))(2)(H(2)O)(4)]·4H(2)O, the slightly distorted octa­hedral MgO(6) coord­in­ation polyhedron comprises two trans-related carboxyl­ate O-atom donors from mononodentate 3,5-dinitro­benzoate ligands, and four water mol­ecules. The coordinating water mol­ecules and the four water mol­ecules of solvation give both intra- and inter-unit O—H⋯O hydrogen-bonding inter­actions with carboxyl­ate, water and nitro O-atom acceptors, forming a three-dimensional structure.