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Tetraaquabis(3,5-dinitrobenzoato-κO (1))magnesium tetrahydrate
In the structure of the title compound, [Mg(C(7)H(3)N(2)O(6))(2)(H(2)O)(4)]·4H(2)O, the slightly distorted octahedral MgO(6) coordination polyhedron comprises two trans-related carboxylate O-atom donors from mononodentate 3,5-dinitrobenzoate ligands, and four water molecules. The coordinating...
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3629491/ https://www.ncbi.nlm.nih.gov/pubmed/23634009 http://dx.doi.org/10.1107/S160053681300682X |
Sumario: | In the structure of the title compound, [Mg(C(7)H(3)N(2)O(6))(2)(H(2)O)(4)]·4H(2)O, the slightly distorted octahedral MgO(6) coordination polyhedron comprises two trans-related carboxylate O-atom donors from mononodentate 3,5-dinitrobenzoate ligands, and four water molecules. The coordinating water molecules and the four water molecules of solvation give both intra- and inter-unit O—H⋯O hydrogen-bonding interactions with carboxylate, water and nitro O-atom acceptors, forming a three-dimensional structure. |
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