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catena-Poly[[[bis­(4-pyridine­aldoxime-κN (1))zinc]-μ-benzene-1,4-dicarboxyl­ato-κ(2) O (1):O (4)] 4-pyridine­aldoxime monosolvate]

In the title compound, {[Zn(C(8)H(4)O(4))(C(6)H(6)N(2)O)(2)]·C(6)H(6)N(2)O}(n), the Zn(II) ion exhibits a tetra­hedral coordination environment defined by two benzene-1,4-dicarboxylate dianions and two 4-pyridinealdoxime ligands. The dianions bridge the Zn(II) ions, giving a zigzag chain along the b...

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Detalles Bibliográficos
Autores principales: Kumagai, Hitoshi, Kawata, Satoshi, Sakamoto, Yoshiyuki
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3629492/
https://www.ncbi.nlm.nih.gov/pubmed/23634010
http://dx.doi.org/10.1107/S1600536813006107
Descripción
Sumario:In the title compound, {[Zn(C(8)H(4)O(4))(C(6)H(6)N(2)O)(2)]·C(6)H(6)N(2)O}(n), the Zn(II) ion exhibits a tetra­hedral coordination environment defined by two benzene-1,4-dicarboxylate dianions and two 4-pyridinealdoxime ligands. The dianions bridge the Zn(II) ions, giving a zigzag chain along the b axis. Adjacent chains are connected by O—H⋯O hydrogen bonds, forming a cavity in which an uncoordinating 4-pyridine­aldoxime mol­ecule is located; this mol­ecule is linked by O—H⋯O and O—H⋯N hydrogen bonds to the zigzag chain.