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catena-Poly[[[bis(4-pyridinealdoxime-κN (1))zinc]-μ-benzene-1,4-dicarboxylato-κ(2) O (1):O (4)] 4-pyridinealdoxime monosolvate]
In the title compound, {[Zn(C(8)H(4)O(4))(C(6)H(6)N(2)O)(2)]·C(6)H(6)N(2)O}(n), the Zn(II) ion exhibits a tetrahedral coordination environment defined by two benzene-1,4-dicarboxylate dianions and two 4-pyridinealdoxime ligands. The dianions bridge the Zn(II) ions, giving a zigzag chain along the b...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3629492/ https://www.ncbi.nlm.nih.gov/pubmed/23634010 http://dx.doi.org/10.1107/S1600536813006107 |
Sumario: | In the title compound, {[Zn(C(8)H(4)O(4))(C(6)H(6)N(2)O)(2)]·C(6)H(6)N(2)O}(n), the Zn(II) ion exhibits a tetrahedral coordination environment defined by two benzene-1,4-dicarboxylate dianions and two 4-pyridinealdoxime ligands. The dianions bridge the Zn(II) ions, giving a zigzag chain along the b axis. Adjacent chains are connected by O—H⋯O hydrogen bonds, forming a cavity in which an uncoordinating 4-pyridinealdoxime molecule is located; this molecule is linked by O—H⋯O and O—H⋯N hydrogen bonds to the zigzag chain. |
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