catena-Poly[[[bis­(4-pyridine­aldoxime-κN (1))zinc]-μ-benzene-1,4-dicarboxyl­ato-κ(2) O (1):O (4)] 4-pyridine­aldoxime monosolvate]

In the title compound, {[Zn(C(8)H(4)O(4))(C(6)H(6)N(2)O)(2)]·C(6)H(6)N(2)O}(n), the Zn(II) ion exhibits a tetra­hedral coordination environment defined by two benzene-1,4-dicarboxylate dianions and two 4-pyridinealdoxime ligands. The dianions bridge the Zn(II) ions, giving a zigzag chain along the b...

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Detalles Bibliográficos
Autores principales: Kumagai, Hitoshi, Kawata, Satoshi, Sakamoto, Yoshiyuki
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3629492/
https://www.ncbi.nlm.nih.gov/pubmed/23634010
http://dx.doi.org/10.1107/S1600536813006107
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author Kumagai, Hitoshi
Kawata, Satoshi
Sakamoto, Yoshiyuki
author_facet Kumagai, Hitoshi
Kawata, Satoshi
Sakamoto, Yoshiyuki
author_sort Kumagai, Hitoshi
collection PubMed
description In the title compound, {[Zn(C(8)H(4)O(4))(C(6)H(6)N(2)O)(2)]·C(6)H(6)N(2)O}(n), the Zn(II) ion exhibits a tetra­hedral coordination environment defined by two benzene-1,4-dicarboxylate dianions and two 4-pyridinealdoxime ligands. The dianions bridge the Zn(II) ions, giving a zigzag chain along the b axis. Adjacent chains are connected by O—H⋯O hydrogen bonds, forming a cavity in which an uncoordinating 4-pyridine­aldoxime mol­ecule is located; this mol­ecule is linked by O—H⋯O and O—H⋯N hydrogen bonds to the zigzag chain.
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spelling pubmed-36294922013-04-30 catena-Poly[[[bis­(4-pyridine­aldoxime-κN (1))zinc]-μ-benzene-1,4-dicarboxyl­ato-κ(2) O (1):O (4)] 4-pyridine­aldoxime monosolvate] Kumagai, Hitoshi Kawata, Satoshi Sakamoto, Yoshiyuki Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, {[Zn(C(8)H(4)O(4))(C(6)H(6)N(2)O)(2)]·C(6)H(6)N(2)O}(n), the Zn(II) ion exhibits a tetra­hedral coordination environment defined by two benzene-1,4-dicarboxylate dianions and two 4-pyridinealdoxime ligands. The dianions bridge the Zn(II) ions, giving a zigzag chain along the b axis. Adjacent chains are connected by O—H⋯O hydrogen bonds, forming a cavity in which an uncoordinating 4-pyridine­aldoxime mol­ecule is located; this mol­ecule is linked by O—H⋯O and O—H⋯N hydrogen bonds to the zigzag chain. International Union of Crystallography 2013-03-16 /pmc/articles/PMC3629492/ /pubmed/23634010 http://dx.doi.org/10.1107/S1600536813006107 Text en © Kumagai et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Kumagai, Hitoshi
Kawata, Satoshi
Sakamoto, Yoshiyuki
catena-Poly[[[bis­(4-pyridine­aldoxime-κN (1))zinc]-μ-benzene-1,4-dicarboxyl­ato-κ(2) O (1):O (4)] 4-pyridine­aldoxime monosolvate]
title catena-Poly[[[bis­(4-pyridine­aldoxime-κN (1))zinc]-μ-benzene-1,4-dicarboxyl­ato-κ(2) O (1):O (4)] 4-pyridine­aldoxime monosolvate]
title_full catena-Poly[[[bis­(4-pyridine­aldoxime-κN (1))zinc]-μ-benzene-1,4-dicarboxyl­ato-κ(2) O (1):O (4)] 4-pyridine­aldoxime monosolvate]
title_fullStr catena-Poly[[[bis­(4-pyridine­aldoxime-κN (1))zinc]-μ-benzene-1,4-dicarboxyl­ato-κ(2) O (1):O (4)] 4-pyridine­aldoxime monosolvate]
title_full_unstemmed catena-Poly[[[bis­(4-pyridine­aldoxime-κN (1))zinc]-μ-benzene-1,4-dicarboxyl­ato-κ(2) O (1):O (4)] 4-pyridine­aldoxime monosolvate]
title_short catena-Poly[[[bis­(4-pyridine­aldoxime-κN (1))zinc]-μ-benzene-1,4-dicarboxyl­ato-κ(2) O (1):O (4)] 4-pyridine­aldoxime monosolvate]
title_sort catena-poly[[[bis­(4-pyridine­aldoxime-κn (1))zinc]-μ-benzene-1,4-dicarboxyl­ato-κ(2) o (1):o (4)] 4-pyridine­aldoxime monosolvate]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3629492/
https://www.ncbi.nlm.nih.gov/pubmed/23634010
http://dx.doi.org/10.1107/S1600536813006107
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AT kawatasatoshi catenapolybis4pyridinealdoximekn1zincmbenzene14dicarboxylatok2o1o44pyridinealdoximemonosolvate
AT sakamotoyoshiyuki catenapolybis4pyridinealdoximekn1zincmbenzene14dicarboxylatok2o1o44pyridinealdoximemonosolvate

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