Bis(3-aza­niumylpyridin-1-ium) hexa­chloridostannate(IV) dichloride

The asymmetric unit of the title compound, (C(5)H(8)N(2))(2)[SnCl(6)]Cl(2), consists of one 3-aza­niumylpyridin-1-ium dication and one chloride ion in a general position and a hexa­chloridostannate(IV) dianion lying about a centre of inversion. The [SnCl(6)](2−) anion exhibits almost perfect octa­he...

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Detalles Bibliográficos
Autores principales: van Megen, Martin, Prömper, Stephan, Reiss, Guido J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3629493/
https://www.ncbi.nlm.nih.gov/pubmed/23634011
http://dx.doi.org/10.1107/S1600536813006806
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author van Megen, Martin
Prömper, Stephan
Reiss, Guido J.
author_facet van Megen, Martin
Prömper, Stephan
Reiss, Guido J.
author_sort van Megen, Martin
collection PubMed
description The asymmetric unit of the title compound, (C(5)H(8)N(2))(2)[SnCl(6)]Cl(2), consists of one 3-aza­niumylpyridin-1-ium dication and one chloride ion in a general position and a hexa­chloridostannate(IV) dianion lying about a centre of inversion. The [SnCl(6)](2−) anion exhibits almost perfect octa­hedral geometry. The 3-aza­niumylpyridin-1-ium and chloride ions are connected via medium–strong charge-supported N—H⋯Cl hydrogen bonds, forming undulating layers in the (110) plane. The [SnCl(6)](2−) ions are located between these layers and occupy cavities formed by two facing layer puckers.
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spelling pubmed-36294932013-04-30 Bis(3-aza­niumylpyridin-1-ium) hexa­chloridostannate(IV) dichloride van Megen, Martin Prömper, Stephan Reiss, Guido J. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, (C(5)H(8)N(2))(2)[SnCl(6)]Cl(2), consists of one 3-aza­niumylpyridin-1-ium dication and one chloride ion in a general position and a hexa­chloridostannate(IV) dianion lying about a centre of inversion. The [SnCl(6)](2−) anion exhibits almost perfect octa­hedral geometry. The 3-aza­niumylpyridin-1-ium and chloride ions are connected via medium–strong charge-supported N—H⋯Cl hydrogen bonds, forming undulating layers in the (110) plane. The [SnCl(6)](2−) ions are located between these layers and occupy cavities formed by two facing layer puckers. International Union of Crystallography 2013-03-16 /pmc/articles/PMC3629493/ /pubmed/23634011 http://dx.doi.org/10.1107/S1600536813006806 Text en © Megen et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
van Megen, Martin
Prömper, Stephan
Reiss, Guido J.
Bis(3-aza­niumylpyridin-1-ium) hexa­chloridostannate(IV) dichloride
title Bis(3-aza­niumylpyridin-1-ium) hexa­chloridostannate(IV) dichloride
title_full Bis(3-aza­niumylpyridin-1-ium) hexa­chloridostannate(IV) dichloride
title_fullStr Bis(3-aza­niumylpyridin-1-ium) hexa­chloridostannate(IV) dichloride
title_full_unstemmed Bis(3-aza­niumylpyridin-1-ium) hexa­chloridostannate(IV) dichloride
title_short Bis(3-aza­niumylpyridin-1-ium) hexa­chloridostannate(IV) dichloride
title_sort bis(3-aza­niumylpyridin-1-ium) hexa­chloridostannate(iv) dichloride
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3629493/
https://www.ncbi.nlm.nih.gov/pubmed/23634011
http://dx.doi.org/10.1107/S1600536813006806
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AT promperstephan bis3azaniumylpyridin1iumhexachloridostannateivdichloride
AT reissguidoj bis3azaniumylpyridin1iumhexachloridostannateivdichloride

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