Chlorido[1,1′-(5-methyl-1,3-phenyl­ene)bis­(3,5-dimethyl-1H-imidazol-2-yl­idene)]platinum(II)

In the title compound, [Pt(C(17)H(19)N(4))Cl], the Pt(II) cation is C,C′,C′′-chelated by the 1,1′-(5-methyl-1,3-phenyl­ene)bis­(3,5-dimethyl-1H-imidazolyl­idene) anion and coordinated by a Cl(−) anion in a distorted square-planar coordination geometry. π–π stacking is observed between nearly paralle...

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Detalles Bibliográficos
Autores principales: Peng, Kui-Juan, Wang, Zi-Xing, Wan, Wen
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3629494/
https://www.ncbi.nlm.nih.gov/pubmed/23634012
http://dx.doi.org/10.1107/S1600536813006545
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author Peng, Kui-Juan
Wang, Zi-Xing
Wan, Wen
author_facet Peng, Kui-Juan
Wang, Zi-Xing
Wan, Wen
author_sort Peng, Kui-Juan
collection PubMed
description In the title compound, [Pt(C(17)H(19)N(4))Cl], the Pt(II) cation is C,C′,C′′-chelated by the 1,1′-(5-methyl-1,3-phenyl­ene)bis­(3,5-dimethyl-1H-imidazolyl­idene) anion and coordinated by a Cl(−) anion in a distorted square-planar coordination geometry. π–π stacking is observed between nearly parallel imidazole and benzene rings of adjacent mol­ecules, the centroid–centroid distance being 3.802 (4) Å.
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spelling pubmed-36294942013-04-30 Chlorido[1,1′-(5-methyl-1,3-phenyl­ene)bis­(3,5-dimethyl-1H-imidazol-2-yl­idene)]platinum(II) Peng, Kui-Juan Wang, Zi-Xing Wan, Wen Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Pt(C(17)H(19)N(4))Cl], the Pt(II) cation is C,C′,C′′-chelated by the 1,1′-(5-methyl-1,3-phenyl­ene)bis­(3,5-dimethyl-1H-imidazolyl­idene) anion and coordinated by a Cl(−) anion in a distorted square-planar coordination geometry. π–π stacking is observed between nearly parallel imidazole and benzene rings of adjacent mol­ecules, the centroid–centroid distance being 3.802 (4) Å. International Union of Crystallography 2013-03-16 /pmc/articles/PMC3629494/ /pubmed/23634012 http://dx.doi.org/10.1107/S1600536813006545 Text en © Peng et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Peng, Kui-Juan
Wang, Zi-Xing
Wan, Wen
Chlorido[1,1′-(5-methyl-1,3-phenyl­ene)bis­(3,5-dimethyl-1H-imidazol-2-yl­idene)]platinum(II)
title Chlorido[1,1′-(5-methyl-1,3-phenyl­ene)bis­(3,5-dimethyl-1H-imidazol-2-yl­idene)]platinum(II)
title_full Chlorido[1,1′-(5-methyl-1,3-phenyl­ene)bis­(3,5-dimethyl-1H-imidazol-2-yl­idene)]platinum(II)
title_fullStr Chlorido[1,1′-(5-methyl-1,3-phenyl­ene)bis­(3,5-dimethyl-1H-imidazol-2-yl­idene)]platinum(II)
title_full_unstemmed Chlorido[1,1′-(5-methyl-1,3-phenyl­ene)bis­(3,5-dimethyl-1H-imidazol-2-yl­idene)]platinum(II)
title_short Chlorido[1,1′-(5-methyl-1,3-phenyl­ene)bis­(3,5-dimethyl-1H-imidazol-2-yl­idene)]platinum(II)
title_sort chlorido[1,1′-(5-methyl-1,3-phenyl­ene)bis­(3,5-dimethyl-1h-imidazol-2-yl­idene)]platinum(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3629494/
https://www.ncbi.nlm.nih.gov/pubmed/23634012
http://dx.doi.org/10.1107/S1600536813006545
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AT wangzixing chlorido115methyl13phenylenebis35dimethyl1himidazol2ylideneplatinumii
AT wanwen chlorido115methyl13phenylenebis35dimethyl1himidazol2ylideneplatinumii

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