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Tetrakis(μ-4-chlorobenzoato-κ(2) O:O′)bis[(ethanol-κO)copper(II)](Cu—Cu)
In the centrosymmetric dinuclear title Cu(II) complex, [Cu(2)(C(7)H(4)ClO(2))(C(2)H(5)OH)(2)], the Cu—Cu distance is 2.5905 (4) Å. The two metal atoms are bridged by four 4-chlorobenzoate ligands and each has an ethanol molecule in the axial position of the overall octahedral coordination environm...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3629496/ https://www.ncbi.nlm.nih.gov/pubmed/23634014 http://dx.doi.org/10.1107/S1600536813006909 |
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author | Mollica Nardo, Viviana Nicoló, Francesco Saccà, Alessandro Bruno, Giuseppe Ielo, Ileana |
author_facet | Mollica Nardo, Viviana Nicoló, Francesco Saccà, Alessandro Bruno, Giuseppe Ielo, Ileana |
author_sort | Mollica Nardo, Viviana |
collection | PubMed |
description | In the centrosymmetric dinuclear title Cu(II) complex, [Cu(2)(C(7)H(4)ClO(2))(C(2)H(5)OH)(2)], the Cu—Cu distance is 2.5905 (4) Å. The two metal atoms are bridged by four 4-chlorobenzoate ligands and each has an ethanol molecule in the axial position of the overall octahedral coordination environment. The crystal packing features O—H⋯O hydrogen bonds. |
format | Online Article Text |
id | pubmed-3629496 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2013 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-36294962013-04-30 Tetrakis(μ-4-chlorobenzoato-κ(2) O:O′)bis[(ethanol-κO)copper(II)](Cu—Cu) Mollica Nardo, Viviana Nicoló, Francesco Saccà, Alessandro Bruno, Giuseppe Ielo, Ileana Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the centrosymmetric dinuclear title Cu(II) complex, [Cu(2)(C(7)H(4)ClO(2))(C(2)H(5)OH)(2)], the Cu—Cu distance is 2.5905 (4) Å. The two metal atoms are bridged by four 4-chlorobenzoate ligands and each has an ethanol molecule in the axial position of the overall octahedral coordination environment. The crystal packing features O—H⋯O hydrogen bonds. International Union of Crystallography 2013-03-16 /pmc/articles/PMC3629496/ /pubmed/23634014 http://dx.doi.org/10.1107/S1600536813006909 Text en © Mollica Nardo et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Mollica Nardo, Viviana Nicoló, Francesco Saccà, Alessandro Bruno, Giuseppe Ielo, Ileana Tetrakis(μ-4-chlorobenzoato-κ(2) O:O′)bis[(ethanol-κO)copper(II)](Cu—Cu) |
title | Tetrakis(μ-4-chlorobenzoato-κ(2)
O:O′)bis[(ethanol-κO)copper(II)](Cu—Cu) |
title_full | Tetrakis(μ-4-chlorobenzoato-κ(2)
O:O′)bis[(ethanol-κO)copper(II)](Cu—Cu) |
title_fullStr | Tetrakis(μ-4-chlorobenzoato-κ(2)
O:O′)bis[(ethanol-κO)copper(II)](Cu—Cu) |
title_full_unstemmed | Tetrakis(μ-4-chlorobenzoato-κ(2)
O:O′)bis[(ethanol-κO)copper(II)](Cu—Cu) |
title_short | Tetrakis(μ-4-chlorobenzoato-κ(2)
O:O′)bis[(ethanol-κO)copper(II)](Cu—Cu) |
title_sort | tetrakis(μ-4-chlorobenzoato-κ(2)
o:o′)bis[(ethanol-κo)copper(ii)](cu—cu) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3629496/ https://www.ncbi.nlm.nih.gov/pubmed/23634014 http://dx.doi.org/10.1107/S1600536813006909 |
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