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catena-Poly[[[bis(methanol-κO)bis(selenocyanato-κN)manganese(II)]-μ-1,2-bis(pyridin-4-yl)ethane-κ(2) N:N′] 1,2-bis(pyridin-4-yl)ethane monosolvate]
The reaction of manganese selenocyanate with 1,2-bis(pyridin-4-yl)ethane (bpa) leads to the title compound, {[Mn(NCSe)(2)(C(12)H(12)N(2))(CH(3)OH)(2)]·C(12)H(12)N(2)}(n). The Mn(II) cation is coordinated by two N-bonded selenocyanate anions, two bpa ligands and two O-bonded methanol molecules, w...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3629498/ https://www.ncbi.nlm.nih.gov/pubmed/23634016 http://dx.doi.org/10.1107/S1600536813007150 |
Sumario: | The reaction of manganese selenocyanate with 1,2-bis(pyridin-4-yl)ethane (bpa) leads to the title compound, {[Mn(NCSe)(2)(C(12)H(12)N(2))(CH(3)OH)(2)]·C(12)H(12)N(2)}(n). The Mn(II) cation is coordinated by two N-bonded selenocyanate anions, two bpa ligands and two O-bonded methanol molecules, within a slightly distorted octahedral geometry. The Mn(II) cations and the non-coordinating N-donor ligands are located on centers of inversion while the coordinating N-donor co-ligands are located on a twofold rotation axis. In the crystal, the Mn(II) cations are linked into chains along the c-axis direction by the bpa ligands. The chains are further connected via a non-coordinating bpa ligand into layers parallel to (3-10) via O—H⋯N hydrogen-bonding interactions. |
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