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catena-Poly[[[bis­(methanol-κO)bis­(seleno­cyanato-κN)manganese(II)]-μ-1,2-bis­(pyridin-4-yl)ethane-κ(2) N:N′] 1,2-bis­(pyridin-4-yl)ethane monosolvate]

The reaction of manganese seleno­cyanate with 1,2-bis­(pyridin-4-yl)ethane (bpa) leads to the title compound, {[Mn(NCSe)(2)(C(12)H(12)N(2))(CH(3)OH)(2)]·C(12)H(12)N(2)}(n). The Mn(II) cation is coordinated by two N-bonded seleno­cyanate anions, two bpa ligands and two O-bonded methanol mol­ecules, w...

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Detalles Bibliográficos
Autores principales: Wöhlert, Susanne, Jess, Inke, Näther, Christian
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3629498/
https://www.ncbi.nlm.nih.gov/pubmed/23634016
http://dx.doi.org/10.1107/S1600536813007150
Descripción
Sumario:The reaction of manganese seleno­cyanate with 1,2-bis­(pyridin-4-yl)ethane (bpa) leads to the title compound, {[Mn(NCSe)(2)(C(12)H(12)N(2))(CH(3)OH)(2)]·C(12)H(12)N(2)}(n). The Mn(II) cation is coordinated by two N-bonded seleno­cyanate anions, two bpa ligands and two O-bonded methanol mol­ecules, within a slightly distorted octa­hedral geometry. The Mn(II) cations and the non-coordinating N-donor ligands are located on centers of inversion while the coordinating N-donor co-ligands are located on a twofold rotation axis. In the crystal, the Mn(II) cations are linked into chains along the c-axis direction by the bpa ligands. The chains are further connected via a non-coordinating bpa ligand into layers parallel to (3-10) via O—H⋯N hydrogen-bonding inter­actions.