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catena-Poly[[[bis­(methanol-κO)bis­(seleno­cyanato-κN)manganese(II)]-μ-1,2-bis­(pyridin-4-yl)ethane-κ(2) N:N′] 1,2-bis­(pyridin-4-yl)ethane monosolvate]

The reaction of manganese seleno­cyanate with 1,2-bis­(pyridin-4-yl)ethane (bpa) leads to the title compound, {[Mn(NCSe)(2)(C(12)H(12)N(2))(CH(3)OH)(2)]·C(12)H(12)N(2)}(n). The Mn(II) cation is coordinated by two N-bonded seleno­cyanate anions, two bpa ligands and two O-bonded methanol mol­ecules, w...

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Detalles Bibliográficos
Autores principales: Wöhlert, Susanne, Jess, Inke, Näther, Christian
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3629498/
https://www.ncbi.nlm.nih.gov/pubmed/23634016
http://dx.doi.org/10.1107/S1600536813007150
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author Wöhlert, Susanne
Jess, Inke
Näther, Christian
author_facet Wöhlert, Susanne
Jess, Inke
Näther, Christian
author_sort Wöhlert, Susanne
collection PubMed
description The reaction of manganese seleno­cyanate with 1,2-bis­(pyridin-4-yl)ethane (bpa) leads to the title compound, {[Mn(NCSe)(2)(C(12)H(12)N(2))(CH(3)OH)(2)]·C(12)H(12)N(2)}(n). The Mn(II) cation is coordinated by two N-bonded seleno­cyanate anions, two bpa ligands and two O-bonded methanol mol­ecules, within a slightly distorted octa­hedral geometry. The Mn(II) cations and the non-coordinating N-donor ligands are located on centers of inversion while the coordinating N-donor co-ligands are located on a twofold rotation axis. In the crystal, the Mn(II) cations are linked into chains along the c-axis direction by the bpa ligands. The chains are further connected via a non-coordinating bpa ligand into layers parallel to (3-10) via O—H⋯N hydrogen-bonding inter­actions.
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spelling pubmed-36294982013-04-30 catena-Poly[[[bis­(methanol-κO)bis­(seleno­cyanato-κN)manganese(II)]-μ-1,2-bis­(pyridin-4-yl)ethane-κ(2) N:N′] 1,2-bis­(pyridin-4-yl)ethane monosolvate] Wöhlert, Susanne Jess, Inke Näther, Christian Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The reaction of manganese seleno­cyanate with 1,2-bis­(pyridin-4-yl)ethane (bpa) leads to the title compound, {[Mn(NCSe)(2)(C(12)H(12)N(2))(CH(3)OH)(2)]·C(12)H(12)N(2)}(n). The Mn(II) cation is coordinated by two N-bonded seleno­cyanate anions, two bpa ligands and two O-bonded methanol mol­ecules, within a slightly distorted octa­hedral geometry. The Mn(II) cations and the non-coordinating N-donor ligands are located on centers of inversion while the coordinating N-donor co-ligands are located on a twofold rotation axis. In the crystal, the Mn(II) cations are linked into chains along the c-axis direction by the bpa ligands. The chains are further connected via a non-coordinating bpa ligand into layers parallel to (3-10) via O—H⋯N hydrogen-bonding inter­actions. International Union of Crystallography 2013-03-20 /pmc/articles/PMC3629498/ /pubmed/23634016 http://dx.doi.org/10.1107/S1600536813007150 Text en © Wöhlert et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wöhlert, Susanne
Jess, Inke
Näther, Christian
catena-Poly[[[bis­(methanol-κO)bis­(seleno­cyanato-κN)manganese(II)]-μ-1,2-bis­(pyridin-4-yl)ethane-κ(2) N:N′] 1,2-bis­(pyridin-4-yl)ethane monosolvate]
title catena-Poly[[[bis­(methanol-κO)bis­(seleno­cyanato-κN)manganese(II)]-μ-1,2-bis­(pyridin-4-yl)ethane-κ(2) N:N′] 1,2-bis­(pyridin-4-yl)ethane monosolvate]
title_full catena-Poly[[[bis­(methanol-κO)bis­(seleno­cyanato-κN)manganese(II)]-μ-1,2-bis­(pyridin-4-yl)ethane-κ(2) N:N′] 1,2-bis­(pyridin-4-yl)ethane monosolvate]
title_fullStr catena-Poly[[[bis­(methanol-κO)bis­(seleno­cyanato-κN)manganese(II)]-μ-1,2-bis­(pyridin-4-yl)ethane-κ(2) N:N′] 1,2-bis­(pyridin-4-yl)ethane monosolvate]
title_full_unstemmed catena-Poly[[[bis­(methanol-κO)bis­(seleno­cyanato-κN)manganese(II)]-μ-1,2-bis­(pyridin-4-yl)ethane-κ(2) N:N′] 1,2-bis­(pyridin-4-yl)ethane monosolvate]
title_short catena-Poly[[[bis­(methanol-κO)bis­(seleno­cyanato-κN)manganese(II)]-μ-1,2-bis­(pyridin-4-yl)ethane-κ(2) N:N′] 1,2-bis­(pyridin-4-yl)ethane monosolvate]
title_sort catena-poly[[[bis­(methanol-κo)bis­(seleno­cyanato-κn)manganese(ii)]-μ-1,2-bis­(pyridin-4-yl)ethane-κ(2) n:n′] 1,2-bis­(pyridin-4-yl)ethane monosolvate]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3629498/
https://www.ncbi.nlm.nih.gov/pubmed/23634016
http://dx.doi.org/10.1107/S1600536813007150
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