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Chlorido[1-(2-oxidophen­yl)ethyl­idene][tris­(3,5-dimethyl­pyrazol-1-yl)hydro­borato]iridium(III) chloro­form monosolvate

In the title compound, [Ir(C(15)H(22)BN(6))(C(8)H(7)O)Cl]·CHCl(3), the Ir atom is formally trivalent and is coordinated in a slightly distorted octa­hedral geometry by three facial N atoms, one C atom, one O atom and one Cl atom. The Ir=C(carbene) bond is strong and short and exerts a notable effect...

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Detalles Bibliográficos
Autores principales: Santos, Laura L., Paneque, Margarita, Mereiter, Kurt
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3629499/
https://www.ncbi.nlm.nih.gov/pubmed/23634017
http://dx.doi.org/10.1107/S1600536813007344
Descripción
Sumario:In the title compound, [Ir(C(15)H(22)BN(6))(C(8)H(7)O)Cl]·CHCl(3), the Ir atom is formally trivalent and is coordinated in a slightly distorted octa­hedral geometry by three facial N atoms, one C atom, one O atom and one Cl atom. The Ir=C(carbene) bond is strong and short and exerts a notable effect on the trans-Ir—N bond, which is about 0.10 Å longer than the two other Ir—N bonds. The chloro­form solvent mol­ecule is anchored via a weak C—H⋯Cl hydrogen bond to the Cl atom of the Ir complex mol­ecule. In the crystal, the constituents adopt a layer-like arrangement parallel to (010) and are held together by weak inter­molecular C—H⋯Cl hydrogen bonds, as well as weak Cl⋯Cl [3.498 (2) Å] and Cl⋯π [3.360 (4) Å] inter­actions. A weak intra­molecular C—H⋯O hydrogen bond is also observed.