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Chlorido[1-(2-oxidophen­yl)ethyl­idene][tris­(3,5-dimethyl­pyrazol-1-yl)hydro­borato]iridium(III) chloro­form monosolvate

In the title compound, [Ir(C(15)H(22)BN(6))(C(8)H(7)O)Cl]·CHCl(3), the Ir atom is formally trivalent and is coordinated in a slightly distorted octa­hedral geometry by three facial N atoms, one C atom, one O atom and one Cl atom. The Ir=C(carbene) bond is strong and short and exerts a notable effect...

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Autores principales: Santos, Laura L., Paneque, Margarita, Mereiter, Kurt
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3629499/
https://www.ncbi.nlm.nih.gov/pubmed/23634017
http://dx.doi.org/10.1107/S1600536813007344
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author Santos, Laura L.
Paneque, Margarita
Mereiter, Kurt
author_facet Santos, Laura L.
Paneque, Margarita
Mereiter, Kurt
author_sort Santos, Laura L.
collection PubMed
description In the title compound, [Ir(C(15)H(22)BN(6))(C(8)H(7)O)Cl]·CHCl(3), the Ir atom is formally trivalent and is coordinated in a slightly distorted octa­hedral geometry by three facial N atoms, one C atom, one O atom and one Cl atom. The Ir=C(carbene) bond is strong and short and exerts a notable effect on the trans-Ir—N bond, which is about 0.10 Å longer than the two other Ir—N bonds. The chloro­form solvent mol­ecule is anchored via a weak C—H⋯Cl hydrogen bond to the Cl atom of the Ir complex mol­ecule. In the crystal, the constituents adopt a layer-like arrangement parallel to (010) and are held together by weak inter­molecular C—H⋯Cl hydrogen bonds, as well as weak Cl⋯Cl [3.498 (2) Å] and Cl⋯π [3.360 (4) Å] inter­actions. A weak intra­molecular C—H⋯O hydrogen bond is also observed.
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spelling pubmed-36294992013-04-30 Chlorido[1-(2-oxidophen­yl)ethyl­idene][tris­(3,5-dimethyl­pyrazol-1-yl)hydro­borato]iridium(III) chloro­form monosolvate Santos, Laura L. Paneque, Margarita Mereiter, Kurt Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Ir(C(15)H(22)BN(6))(C(8)H(7)O)Cl]·CHCl(3), the Ir atom is formally trivalent and is coordinated in a slightly distorted octa­hedral geometry by three facial N atoms, one C atom, one O atom and one Cl atom. The Ir=C(carbene) bond is strong and short and exerts a notable effect on the trans-Ir—N bond, which is about 0.10 Å longer than the two other Ir—N bonds. The chloro­form solvent mol­ecule is anchored via a weak C—H⋯Cl hydrogen bond to the Cl atom of the Ir complex mol­ecule. In the crystal, the constituents adopt a layer-like arrangement parallel to (010) and are held together by weak inter­molecular C—H⋯Cl hydrogen bonds, as well as weak Cl⋯Cl [3.498 (2) Å] and Cl⋯π [3.360 (4) Å] inter­actions. A weak intra­molecular C—H⋯O hydrogen bond is also observed. International Union of Crystallography 2013-03-23 /pmc/articles/PMC3629499/ /pubmed/23634017 http://dx.doi.org/10.1107/S1600536813007344 Text en © Santos et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Santos, Laura L.
Paneque, Margarita
Mereiter, Kurt
Chlorido[1-(2-oxidophen­yl)ethyl­idene][tris­(3,5-dimethyl­pyrazol-1-yl)hydro­borato]iridium(III) chloro­form monosolvate
title Chlorido[1-(2-oxidophen­yl)ethyl­idene][tris­(3,5-dimethyl­pyrazol-1-yl)hydro­borato]iridium(III) chloro­form monosolvate
title_full Chlorido[1-(2-oxidophen­yl)ethyl­idene][tris­(3,5-dimethyl­pyrazol-1-yl)hydro­borato]iridium(III) chloro­form monosolvate
title_fullStr Chlorido[1-(2-oxidophen­yl)ethyl­idene][tris­(3,5-dimethyl­pyrazol-1-yl)hydro­borato]iridium(III) chloro­form monosolvate
title_full_unstemmed Chlorido[1-(2-oxidophen­yl)ethyl­idene][tris­(3,5-dimethyl­pyrazol-1-yl)hydro­borato]iridium(III) chloro­form monosolvate
title_short Chlorido[1-(2-oxidophen­yl)ethyl­idene][tris­(3,5-dimethyl­pyrazol-1-yl)hydro­borato]iridium(III) chloro­form monosolvate
title_sort chlorido[1-(2-oxidophen­yl)ethyl­idene][tris­(3,5-dimethyl­pyrazol-1-yl)hydro­borato]iridium(iii) chloro­form monosolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3629499/
https://www.ncbi.nlm.nih.gov/pubmed/23634017
http://dx.doi.org/10.1107/S1600536813007344
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AT mereiterkurt chlorido12oxidophenylethylidenetris35dimethylpyrazol1ylhydroboratoiridiumiiichloroformmonosolvate