Cargando…
Chlorido[1-(2-oxidophenyl)ethylidene][tris(3,5-dimethylpyrazol-1-yl)hydroborato]iridium(III) chloroform monosolvate
In the title compound, [Ir(C(15)H(22)BN(6))(C(8)H(7)O)Cl]·CHCl(3), the Ir atom is formally trivalent and is coordinated in a slightly distorted octahedral geometry by three facial N atoms, one C atom, one O atom and one Cl atom. The Ir=C(carbene) bond is strong and short and exerts a notable effect...
Autores principales: | , , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3629499/ https://www.ncbi.nlm.nih.gov/pubmed/23634017 http://dx.doi.org/10.1107/S1600536813007344 |
_version_ | 1782266592127614976 |
---|---|
author | Santos, Laura L. Paneque, Margarita Mereiter, Kurt |
author_facet | Santos, Laura L. Paneque, Margarita Mereiter, Kurt |
author_sort | Santos, Laura L. |
collection | PubMed |
description | In the title compound, [Ir(C(15)H(22)BN(6))(C(8)H(7)O)Cl]·CHCl(3), the Ir atom is formally trivalent and is coordinated in a slightly distorted octahedral geometry by three facial N atoms, one C atom, one O atom and one Cl atom. The Ir=C(carbene) bond is strong and short and exerts a notable effect on the trans-Ir—N bond, which is about 0.10 Å longer than the two other Ir—N bonds. The chloroform solvent molecule is anchored via a weak C—H⋯Cl hydrogen bond to the Cl atom of the Ir complex molecule. In the crystal, the constituents adopt a layer-like arrangement parallel to (010) and are held together by weak intermolecular C—H⋯Cl hydrogen bonds, as well as weak Cl⋯Cl [3.498 (2) Å] and Cl⋯π [3.360 (4) Å] interactions. A weak intramolecular C—H⋯O hydrogen bond is also observed. |
format | Online Article Text |
id | pubmed-3629499 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2013 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-36294992013-04-30 Chlorido[1-(2-oxidophenyl)ethylidene][tris(3,5-dimethylpyrazol-1-yl)hydroborato]iridium(III) chloroform monosolvate Santos, Laura L. Paneque, Margarita Mereiter, Kurt Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Ir(C(15)H(22)BN(6))(C(8)H(7)O)Cl]·CHCl(3), the Ir atom is formally trivalent and is coordinated in a slightly distorted octahedral geometry by three facial N atoms, one C atom, one O atom and one Cl atom. The Ir=C(carbene) bond is strong and short and exerts a notable effect on the trans-Ir—N bond, which is about 0.10 Å longer than the two other Ir—N bonds. The chloroform solvent molecule is anchored via a weak C—H⋯Cl hydrogen bond to the Cl atom of the Ir complex molecule. In the crystal, the constituents adopt a layer-like arrangement parallel to (010) and are held together by weak intermolecular C—H⋯Cl hydrogen bonds, as well as weak Cl⋯Cl [3.498 (2) Å] and Cl⋯π [3.360 (4) Å] interactions. A weak intramolecular C—H⋯O hydrogen bond is also observed. International Union of Crystallography 2013-03-23 /pmc/articles/PMC3629499/ /pubmed/23634017 http://dx.doi.org/10.1107/S1600536813007344 Text en © Santos et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Santos, Laura L. Paneque, Margarita Mereiter, Kurt Chlorido[1-(2-oxidophenyl)ethylidene][tris(3,5-dimethylpyrazol-1-yl)hydroborato]iridium(III) chloroform monosolvate |
title | Chlorido[1-(2-oxidophenyl)ethylidene][tris(3,5-dimethylpyrazol-1-yl)hydroborato]iridium(III) chloroform monosolvate |
title_full | Chlorido[1-(2-oxidophenyl)ethylidene][tris(3,5-dimethylpyrazol-1-yl)hydroborato]iridium(III) chloroform monosolvate |
title_fullStr | Chlorido[1-(2-oxidophenyl)ethylidene][tris(3,5-dimethylpyrazol-1-yl)hydroborato]iridium(III) chloroform monosolvate |
title_full_unstemmed | Chlorido[1-(2-oxidophenyl)ethylidene][tris(3,5-dimethylpyrazol-1-yl)hydroborato]iridium(III) chloroform monosolvate |
title_short | Chlorido[1-(2-oxidophenyl)ethylidene][tris(3,5-dimethylpyrazol-1-yl)hydroborato]iridium(III) chloroform monosolvate |
title_sort | chlorido[1-(2-oxidophenyl)ethylidene][tris(3,5-dimethylpyrazol-1-yl)hydroborato]iridium(iii) chloroform monosolvate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3629499/ https://www.ncbi.nlm.nih.gov/pubmed/23634017 http://dx.doi.org/10.1107/S1600536813007344 |
work_keys_str_mv | AT santoslaural chlorido12oxidophenylethylidenetris35dimethylpyrazol1ylhydroboratoiridiumiiichloroformmonosolvate AT panequemargarita chlorido12oxidophenylethylidenetris35dimethylpyrazol1ylhydroboratoiridiumiiichloroformmonosolvate AT mereiterkurt chlorido12oxidophenylethylidenetris35dimethylpyrazol1ylhydroboratoiridiumiiichloroformmonosolvate |