cis,cis,cis-(Acetato-κ(2) O,O′)bis­[1,2-bis­(diphenyl­phosphan­yl)ethane-κ(2) P,P′]ruthenium(II) 0.75-trifluoro­methane­sulfonate 0.25-chloride

In the title Ru(II) carboxyl­ate compound, [Ru(C(2)H(3)O(2))(C(26)H(24)P(2))(2)](CF(3)O(3)S)(0.75)Cl(0.25), the distorted tris-bidentate octa­hedral stereochemistry about the Ru(II) atom in the complex cation comprises four P-atom donors from two 1,2-bis­(diphenyl­phosphan­yl)ethane ligands [Ru—P =...

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Detalles Bibliográficos
Autores principales: Figueira, João, Rodrigues, João, Valkonen, Arto
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3629500/
https://www.ncbi.nlm.nih.gov/pubmed/23634018
http://dx.doi.org/10.1107/S160053681300737X
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author Figueira, João
Rodrigues, João
Valkonen, Arto
author_facet Figueira, João
Rodrigues, João
Valkonen, Arto
author_sort Figueira, João
collection PubMed
description In the title Ru(II) carboxyl­ate compound, [Ru(C(2)H(3)O(2))(C(26)H(24)P(2))(2)](CF(3)O(3)S)(0.75)Cl(0.25), the distorted tris-bidentate octa­hedral stereochemistry about the Ru(II) atom in the complex cation comprises four P-atom donors from two 1,2-bis­(diphenyl­phosphan­yl)ethane ligands [Ru—P = 2.2881 (13)–2.3791 (13) Å] and two O-atom donors from the acetate ligand [Ru—O = 2.191 (3) and 2.202 (3) Å]. The disordered counter-anions are located on the same site in the structure in a 3:1 ratio, the expanded formula comprising four complex cations, three trifluoro­methane­sulfonate anions and one chloride anion, with two such formula units in the unit cell.
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spelling pubmed-36295002013-04-30 cis,cis,cis-(Acetato-κ(2) O,O′)bis­[1,2-bis­(diphenyl­phosphan­yl)ethane-κ(2) P,P′]ruthenium(II) 0.75-trifluoro­methane­sulfonate 0.25-chloride Figueira, João Rodrigues, João Valkonen, Arto Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title Ru(II) carboxyl­ate compound, [Ru(C(2)H(3)O(2))(C(26)H(24)P(2))(2)](CF(3)O(3)S)(0.75)Cl(0.25), the distorted tris-bidentate octa­hedral stereochemistry about the Ru(II) atom in the complex cation comprises four P-atom donors from two 1,2-bis­(diphenyl­phosphan­yl)ethane ligands [Ru—P = 2.2881 (13)–2.3791 (13) Å] and two O-atom donors from the acetate ligand [Ru—O = 2.191 (3) and 2.202 (3) Å]. The disordered counter-anions are located on the same site in the structure in a 3:1 ratio, the expanded formula comprising four complex cations, three trifluoro­methane­sulfonate anions and one chloride anion, with two such formula units in the unit cell. International Union of Crystallography 2013-03-23 /pmc/articles/PMC3629500/ /pubmed/23634018 http://dx.doi.org/10.1107/S160053681300737X Text en © Figueira et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Figueira, João
Rodrigues, João
Valkonen, Arto
cis,cis,cis-(Acetato-κ(2) O,O′)bis­[1,2-bis­(diphenyl­phosphan­yl)ethane-κ(2) P,P′]ruthenium(II) 0.75-trifluoro­methane­sulfonate 0.25-chloride
title cis,cis,cis-(Acetato-κ(2) O,O′)bis­[1,2-bis­(diphenyl­phosphan­yl)ethane-κ(2) P,P′]ruthenium(II) 0.75-trifluoro­methane­sulfonate 0.25-chloride
title_full cis,cis,cis-(Acetato-κ(2) O,O′)bis­[1,2-bis­(diphenyl­phosphan­yl)ethane-κ(2) P,P′]ruthenium(II) 0.75-trifluoro­methane­sulfonate 0.25-chloride
title_fullStr cis,cis,cis-(Acetato-κ(2) O,O′)bis­[1,2-bis­(diphenyl­phosphan­yl)ethane-κ(2) P,P′]ruthenium(II) 0.75-trifluoro­methane­sulfonate 0.25-chloride
title_full_unstemmed cis,cis,cis-(Acetato-κ(2) O,O′)bis­[1,2-bis­(diphenyl­phosphan­yl)ethane-κ(2) P,P′]ruthenium(II) 0.75-trifluoro­methane­sulfonate 0.25-chloride
title_short cis,cis,cis-(Acetato-κ(2) O,O′)bis­[1,2-bis­(diphenyl­phosphan­yl)ethane-κ(2) P,P′]ruthenium(II) 0.75-trifluoro­methane­sulfonate 0.25-chloride
title_sort cis,cis,cis-(acetato-κ(2) o,o′)bis­[1,2-bis­(diphenyl­phosphan­yl)ethane-κ(2) p,p′]ruthenium(ii) 0.75-trifluoro­methane­sulfonate 0.25-chloride
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3629500/
https://www.ncbi.nlm.nih.gov/pubmed/23634018
http://dx.doi.org/10.1107/S160053681300737X
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