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Poly[diaqua­[μ(6)-4,4′-(1,4-phenyl­ene)bis­(2,6-dimethyl­pyridine-3,5-dicarboxyl­ato)]dilead(II)]

The asymmetric unit of the title Pb-based coordination polymer, [Pb(2)(C(24)H(16)N(2)O(8))(H(2)O)(2)](n), consists of one Pb(II) cation, half of a 4,4′-(1,4-phenyl­ene)bis­(2,6-dimethyl­pyridine-3,5-di­carb­oxyl­ate (L (4−)) ligand and one coordinating water mol­ecule. The centers of the benzene rin...

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Autores principales: Zhu, Yi, Zhang, Ming-Xing, Yang, Shan-Shan, Xiao, Feng, Zhang, Xiao-Ping, Gao, Yuan-Yuan, Li, Bing-Jie, Huang, Kun-Lin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3629504/
https://www.ncbi.nlm.nih.gov/pubmed/23634022
http://dx.doi.org/10.1107/S1600536813007733
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author Zhu, Yi
Zhang, Ming-Xing
Yang, Shan-Shan
Xiao, Feng
Zhang, Xiao-Ping
Gao, Yuan-Yuan
Li, Bing-Jie
Huang, Kun-Lin
author_facet Zhu, Yi
Zhang, Ming-Xing
Yang, Shan-Shan
Xiao, Feng
Zhang, Xiao-Ping
Gao, Yuan-Yuan
Li, Bing-Jie
Huang, Kun-Lin
author_sort Zhu, Yi
collection PubMed
description The asymmetric unit of the title Pb-based coordination polymer, [Pb(2)(C(24)H(16)N(2)O(8))(H(2)O)(2)](n), consists of one Pb(II) cation, half of a 4,4′-(1,4-phenyl­ene)bis­(2,6-dimethyl­pyridine-3,5-di­carb­oxyl­ate (L (4−)) ligand and one coordinating water mol­ecule. The centers of the benzene ring of the ligand and the four-membered Pb/O/Pb/O ring are located on centers of inversion. The Pb(II) ion is coordinated in form of a distorted polyhedron by seven O atoms from four separate L (4−) ligands and by one water O atom. The PbO(7) polyhedra share O atoms, forming infinite zigzag [PbO(4)(H(2)O)](n) chains along [100] that are bridged by L (4−) ligands, forming a two-dimensional coordination network parallel to (001). O—H⋯O hydrogen bonds involving the water mol­ecule are observed.
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spelling pubmed-36295042013-04-30 Poly[diaqua­[μ(6)-4,4′-(1,4-phenyl­ene)bis­(2,6-dimethyl­pyridine-3,5-dicarboxyl­ato)]dilead(II)] Zhu, Yi Zhang, Ming-Xing Yang, Shan-Shan Xiao, Feng Zhang, Xiao-Ping Gao, Yuan-Yuan Li, Bing-Jie Huang, Kun-Lin Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title Pb-based coordination polymer, [Pb(2)(C(24)H(16)N(2)O(8))(H(2)O)(2)](n), consists of one Pb(II) cation, half of a 4,4′-(1,4-phenyl­ene)bis­(2,6-dimethyl­pyridine-3,5-di­carb­oxyl­ate (L (4−)) ligand and one coordinating water mol­ecule. The centers of the benzene ring of the ligand and the four-membered Pb/O/Pb/O ring are located on centers of inversion. The Pb(II) ion is coordinated in form of a distorted polyhedron by seven O atoms from four separate L (4−) ligands and by one water O atom. The PbO(7) polyhedra share O atoms, forming infinite zigzag [PbO(4)(H(2)O)](n) chains along [100] that are bridged by L (4−) ligands, forming a two-dimensional coordination network parallel to (001). O—H⋯O hydrogen bonds involving the water mol­ecule are observed. International Union of Crystallography 2013-03-28 /pmc/articles/PMC3629504/ /pubmed/23634022 http://dx.doi.org/10.1107/S1600536813007733 Text en © Zhu et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zhu, Yi
Zhang, Ming-Xing
Yang, Shan-Shan
Xiao, Feng
Zhang, Xiao-Ping
Gao, Yuan-Yuan
Li, Bing-Jie
Huang, Kun-Lin
Poly[diaqua­[μ(6)-4,4′-(1,4-phenyl­ene)bis­(2,6-dimethyl­pyridine-3,5-dicarboxyl­ato)]dilead(II)]
title Poly[diaqua­[μ(6)-4,4′-(1,4-phenyl­ene)bis­(2,6-dimethyl­pyridine-3,5-dicarboxyl­ato)]dilead(II)]
title_full Poly[diaqua­[μ(6)-4,4′-(1,4-phenyl­ene)bis­(2,6-dimethyl­pyridine-3,5-dicarboxyl­ato)]dilead(II)]
title_fullStr Poly[diaqua­[μ(6)-4,4′-(1,4-phenyl­ene)bis­(2,6-dimethyl­pyridine-3,5-dicarboxyl­ato)]dilead(II)]
title_full_unstemmed Poly[diaqua­[μ(6)-4,4′-(1,4-phenyl­ene)bis­(2,6-dimethyl­pyridine-3,5-dicarboxyl­ato)]dilead(II)]
title_short Poly[diaqua­[μ(6)-4,4′-(1,4-phenyl­ene)bis­(2,6-dimethyl­pyridine-3,5-dicarboxyl­ato)]dilead(II)]
title_sort poly[diaqua­[μ(6)-4,4′-(1,4-phenyl­ene)bis­(2,6-dimethyl­pyridine-3,5-dicarboxyl­ato)]dilead(ii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3629504/
https://www.ncbi.nlm.nih.gov/pubmed/23634022
http://dx.doi.org/10.1107/S1600536813007733
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