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Poly[diaqua[μ(6)-4,4′-(1,4-phenylene)bis(2,6-dimethylpyridine-3,5-dicarboxylato)]dilead(II)]
The asymmetric unit of the title Pb-based coordination polymer, [Pb(2)(C(24)H(16)N(2)O(8))(H(2)O)(2)](n), consists of one Pb(II) cation, half of a 4,4′-(1,4-phenylene)bis(2,6-dimethylpyridine-3,5-dicarboxylate (L (4−)) ligand and one coordinating water molecule. The centers of the benzene rin...
Autores principales: | , , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3629504/ https://www.ncbi.nlm.nih.gov/pubmed/23634022 http://dx.doi.org/10.1107/S1600536813007733 |
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author | Zhu, Yi Zhang, Ming-Xing Yang, Shan-Shan Xiao, Feng Zhang, Xiao-Ping Gao, Yuan-Yuan Li, Bing-Jie Huang, Kun-Lin |
author_facet | Zhu, Yi Zhang, Ming-Xing Yang, Shan-Shan Xiao, Feng Zhang, Xiao-Ping Gao, Yuan-Yuan Li, Bing-Jie Huang, Kun-Lin |
author_sort | Zhu, Yi |
collection | PubMed |
description | The asymmetric unit of the title Pb-based coordination polymer, [Pb(2)(C(24)H(16)N(2)O(8))(H(2)O)(2)](n), consists of one Pb(II) cation, half of a 4,4′-(1,4-phenylene)bis(2,6-dimethylpyridine-3,5-dicarboxylate (L (4−)) ligand and one coordinating water molecule. The centers of the benzene ring of the ligand and the four-membered Pb/O/Pb/O ring are located on centers of inversion. The Pb(II) ion is coordinated in form of a distorted polyhedron by seven O atoms from four separate L (4−) ligands and by one water O atom. The PbO(7) polyhedra share O atoms, forming infinite zigzag [PbO(4)(H(2)O)](n) chains along [100] that are bridged by L (4−) ligands, forming a two-dimensional coordination network parallel to (001). O—H⋯O hydrogen bonds involving the water molecule are observed. |
format | Online Article Text |
id | pubmed-3629504 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2013 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-36295042013-04-30 Poly[diaqua[μ(6)-4,4′-(1,4-phenylene)bis(2,6-dimethylpyridine-3,5-dicarboxylato)]dilead(II)] Zhu, Yi Zhang, Ming-Xing Yang, Shan-Shan Xiao, Feng Zhang, Xiao-Ping Gao, Yuan-Yuan Li, Bing-Jie Huang, Kun-Lin Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title Pb-based coordination polymer, [Pb(2)(C(24)H(16)N(2)O(8))(H(2)O)(2)](n), consists of one Pb(II) cation, half of a 4,4′-(1,4-phenylene)bis(2,6-dimethylpyridine-3,5-dicarboxylate (L (4−)) ligand and one coordinating water molecule. The centers of the benzene ring of the ligand and the four-membered Pb/O/Pb/O ring are located on centers of inversion. The Pb(II) ion is coordinated in form of a distorted polyhedron by seven O atoms from four separate L (4−) ligands and by one water O atom. The PbO(7) polyhedra share O atoms, forming infinite zigzag [PbO(4)(H(2)O)](n) chains along [100] that are bridged by L (4−) ligands, forming a two-dimensional coordination network parallel to (001). O—H⋯O hydrogen bonds involving the water molecule are observed. International Union of Crystallography 2013-03-28 /pmc/articles/PMC3629504/ /pubmed/23634022 http://dx.doi.org/10.1107/S1600536813007733 Text en © Zhu et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Zhu, Yi Zhang, Ming-Xing Yang, Shan-Shan Xiao, Feng Zhang, Xiao-Ping Gao, Yuan-Yuan Li, Bing-Jie Huang, Kun-Lin Poly[diaqua[μ(6)-4,4′-(1,4-phenylene)bis(2,6-dimethylpyridine-3,5-dicarboxylato)]dilead(II)] |
title | Poly[diaqua[μ(6)-4,4′-(1,4-phenylene)bis(2,6-dimethylpyridine-3,5-dicarboxylato)]dilead(II)] |
title_full | Poly[diaqua[μ(6)-4,4′-(1,4-phenylene)bis(2,6-dimethylpyridine-3,5-dicarboxylato)]dilead(II)] |
title_fullStr | Poly[diaqua[μ(6)-4,4′-(1,4-phenylene)bis(2,6-dimethylpyridine-3,5-dicarboxylato)]dilead(II)] |
title_full_unstemmed | Poly[diaqua[μ(6)-4,4′-(1,4-phenylene)bis(2,6-dimethylpyridine-3,5-dicarboxylato)]dilead(II)] |
title_short | Poly[diaqua[μ(6)-4,4′-(1,4-phenylene)bis(2,6-dimethylpyridine-3,5-dicarboxylato)]dilead(II)] |
title_sort | poly[diaqua[μ(6)-4,4′-(1,4-phenylene)bis(2,6-dimethylpyridine-3,5-dicarboxylato)]dilead(ii)] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3629504/ https://www.ncbi.nlm.nih.gov/pubmed/23634022 http://dx.doi.org/10.1107/S1600536813007733 |
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