Cargando…

2-Amino-4-(4-chloro­phen­yl)-4H-chromeno[8,7-b]pyridine-3-carbonitrile

The asymmetric unit of the title compound, C(19)H(12)ClN(3)O, contains two mol­ecules with similar conformations. The 14 non-H atoms comprising the 4H-chromeno[8,7-b]pyridine residue are essentially coplanar (r.m.s. deviations = 0.037 and 0.042 Å for the two mol­ecules) and the main difference betwe...

Descripción completa

Detalles Bibliográficos
Autores principales: Amr, Abd El-Galil E., El-Agrody, Ahmed M., Sabry, Nermien M., Ng, Seik Weng, Tiekink, Edward R. T.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3629505/
https://www.ncbi.nlm.nih.gov/pubmed/23634023
http://dx.doi.org/10.1107/S1600536813005217
_version_ 1782266593518026752
author Amr, Abd El-Galil E.
El-Agrody, Ahmed M.
Sabry, Nermien M.
Ng, Seik Weng
Tiekink, Edward R. T.
author_facet Amr, Abd El-Galil E.
El-Agrody, Ahmed M.
Sabry, Nermien M.
Ng, Seik Weng
Tiekink, Edward R. T.
author_sort Amr, Abd El-Galil E.
collection PubMed
description The asymmetric unit of the title compound, C(19)H(12)ClN(3)O, contains two mol­ecules with similar conformations. The 14 non-H atoms comprising the 4H-chromeno[8,7-b]pyridine residue are essentially coplanar (r.m.s. deviations = 0.037 and 0.042 Å for the two mol­ecules) and the main difference between them is seen in the twist about the bond linking the main residue to the attached chloro­benzene rings [dihedral angles = 79.01 (12) and 76.22 (11)° for the two mol­ecules]. Zigzag supra­molecular chains along the a-axis direction mediated by amino–pyridine N—H⋯N hydrogen bonds feature in the crystal packing; these are connected into a three-dimensional architecture by C—H⋯π inter­actions and Cl⋯Cl contacts [Cl⋯Cl = 3.3896 (14) Å].
format Online
Article
Text
id pubmed-3629505
institution National Center for Biotechnology Information
language English
publishDate 2013
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-36295052013-04-30 2-Amino-4-(4-chloro­phen­yl)-4H-chromeno[8,7-b]pyridine-3-carbonitrile Amr, Abd El-Galil E. El-Agrody, Ahmed M. Sabry, Nermien M. Ng, Seik Weng Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Organic Papers The asymmetric unit of the title compound, C(19)H(12)ClN(3)O, contains two mol­ecules with similar conformations. The 14 non-H atoms comprising the 4H-chromeno[8,7-b]pyridine residue are essentially coplanar (r.m.s. deviations = 0.037 and 0.042 Å for the two mol­ecules) and the main difference between them is seen in the twist about the bond linking the main residue to the attached chloro­benzene rings [dihedral angles = 79.01 (12) and 76.22 (11)° for the two mol­ecules]. Zigzag supra­molecular chains along the a-axis direction mediated by amino–pyridine N—H⋯N hydrogen bonds feature in the crystal packing; these are connected into a three-dimensional architecture by C—H⋯π inter­actions and Cl⋯Cl contacts [Cl⋯Cl = 3.3896 (14) Å]. International Union of Crystallography 2013-03-02 /pmc/articles/PMC3629505/ /pubmed/23634023 http://dx.doi.org/10.1107/S1600536813005217 Text en © Amr et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Amr, Abd El-Galil E.
El-Agrody, Ahmed M.
Sabry, Nermien M.
Ng, Seik Weng
Tiekink, Edward R. T.
2-Amino-4-(4-chloro­phen­yl)-4H-chromeno[8,7-b]pyridine-3-carbonitrile
title 2-Amino-4-(4-chloro­phen­yl)-4H-chromeno[8,7-b]pyridine-3-carbonitrile
title_full 2-Amino-4-(4-chloro­phen­yl)-4H-chromeno[8,7-b]pyridine-3-carbonitrile
title_fullStr 2-Amino-4-(4-chloro­phen­yl)-4H-chromeno[8,7-b]pyridine-3-carbonitrile
title_full_unstemmed 2-Amino-4-(4-chloro­phen­yl)-4H-chromeno[8,7-b]pyridine-3-carbonitrile
title_short 2-Amino-4-(4-chloro­phen­yl)-4H-chromeno[8,7-b]pyridine-3-carbonitrile
title_sort 2-amino-4-(4-chloro­phen­yl)-4h-chromeno[8,7-b]pyridine-3-carbonitrile
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3629505/
https://www.ncbi.nlm.nih.gov/pubmed/23634023
http://dx.doi.org/10.1107/S1600536813005217
work_keys_str_mv AT amrabdelgalile 2amino44chlorophenyl4hchromeno87bpyridine3carbonitrile
AT elagrodyahmedm 2amino44chlorophenyl4hchromeno87bpyridine3carbonitrile
AT sabrynermienm 2amino44chlorophenyl4hchromeno87bpyridine3carbonitrile
AT ngseikweng 2amino44chlorophenyl4hchromeno87bpyridine3carbonitrile
AT tiekinkedwardrt 2amino44chlorophenyl4hchromeno87bpyridine3carbonitrile