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2-[2-(4-Methoxyphenyl)-4,5-diphenyl-1H-imidazol-1-yl]ethanol
In the title compound, C(24)H(22)N(2)O(2), the central imidazole ring makes dihedral angles of 49.45 (8), 88.94 (9) and 19.43 (8)° with the benzene ring and the two phenyl rings, respectively. The dihedral angle between the phenyl rings is 77.86 (9)°, and they form dihedral angles of 49.06 (9) and 6...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3629514/ https://www.ncbi.nlm.nih.gov/pubmed/23634032 http://dx.doi.org/10.1107/S1600536813004285 |
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author | Mohamed, Shaaban Kamel Akkurt, Mehmet Marzouk, Adel A. Abbasov, Vagif. M. Gurbanov, Atash V. |
author_facet | Mohamed, Shaaban Kamel Akkurt, Mehmet Marzouk, Adel A. Abbasov, Vagif. M. Gurbanov, Atash V. |
author_sort | Mohamed, Shaaban Kamel |
collection | PubMed |
description | In the title compound, C(24)H(22)N(2)O(2), the central imidazole ring makes dihedral angles of 49.45 (8), 88.94 (9) and 19.43 (8)° with the benzene ring and the two phenyl rings, respectively. The dihedral angle between the phenyl rings is 77.86 (9)°, and they form dihedral angles of 49.06 (9) and 67.31 (8)° with the benzene ring. In the crystal, molecules are linked by O—H⋯N hydrogen bonds, forming chains along the b axis. These chains are connected by C—H⋯O hydrogen bonds, forming a two-dimensional network parallel to (100). In addition, C—H⋯π interactions are also observed. The terminal C and O atoms of the ethanol group are disordered over two sets of sites with an occupancy ratio of 0.801 (5):0.199 (5). |
format | Online Article Text |
id | pubmed-3629514 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2013 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-36295142013-04-30 2-[2-(4-Methoxyphenyl)-4,5-diphenyl-1H-imidazol-1-yl]ethanol Mohamed, Shaaban Kamel Akkurt, Mehmet Marzouk, Adel A. Abbasov, Vagif. M. Gurbanov, Atash V. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(24)H(22)N(2)O(2), the central imidazole ring makes dihedral angles of 49.45 (8), 88.94 (9) and 19.43 (8)° with the benzene ring and the two phenyl rings, respectively. The dihedral angle between the phenyl rings is 77.86 (9)°, and they form dihedral angles of 49.06 (9) and 67.31 (8)° with the benzene ring. In the crystal, molecules are linked by O—H⋯N hydrogen bonds, forming chains along the b axis. These chains are connected by C—H⋯O hydrogen bonds, forming a two-dimensional network parallel to (100). In addition, C—H⋯π interactions are also observed. The terminal C and O atoms of the ethanol group are disordered over two sets of sites with an occupancy ratio of 0.801 (5):0.199 (5). International Union of Crystallography 2013-03-02 /pmc/articles/PMC3629514/ /pubmed/23634032 http://dx.doi.org/10.1107/S1600536813004285 Text en © Mohamed et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Mohamed, Shaaban Kamel Akkurt, Mehmet Marzouk, Adel A. Abbasov, Vagif. M. Gurbanov, Atash V. 2-[2-(4-Methoxyphenyl)-4,5-diphenyl-1H-imidazol-1-yl]ethanol |
title | 2-[2-(4-Methoxyphenyl)-4,5-diphenyl-1H-imidazol-1-yl]ethanol |
title_full | 2-[2-(4-Methoxyphenyl)-4,5-diphenyl-1H-imidazol-1-yl]ethanol |
title_fullStr | 2-[2-(4-Methoxyphenyl)-4,5-diphenyl-1H-imidazol-1-yl]ethanol |
title_full_unstemmed | 2-[2-(4-Methoxyphenyl)-4,5-diphenyl-1H-imidazol-1-yl]ethanol |
title_short | 2-[2-(4-Methoxyphenyl)-4,5-diphenyl-1H-imidazol-1-yl]ethanol |
title_sort | 2-[2-(4-methoxyphenyl)-4,5-diphenyl-1h-imidazol-1-yl]ethanol |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3629514/ https://www.ncbi.nlm.nih.gov/pubmed/23634032 http://dx.doi.org/10.1107/S1600536813004285 |
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