Ethyl (2E,4E)-5-(3-bromo­phenyl­sulfon­yl)penta-2,4-dienoate

In the title compound, C(13)H(13)BrO(4)S, both C=C double bonds adopt an E conformation. The S atom has a distorted tetra­hedral geometry with bond angles ranging from 102.17 (13) to 119.77 (14)°. The ethyl acrylate substituent adopts an extented conformation with all torsion angles close to 180°. I...

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Detalles Bibliográficos
Autores principales: Sabari, V., Sankar, Ulaganathan, Uma, Ramakrishnan, Aravindhan, S.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3629522/
https://www.ncbi.nlm.nih.gov/pubmed/23634040
http://dx.doi.org/10.1107/S1600536813005771
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author Sabari, V.
Sankar, Ulaganathan
Uma, Ramakrishnan
Aravindhan, S.
author_facet Sabari, V.
Sankar, Ulaganathan
Uma, Ramakrishnan
Aravindhan, S.
author_sort Sabari, V.
collection PubMed
description In the title compound, C(13)H(13)BrO(4)S, both C=C double bonds adopt an E conformation. The S atom has a distorted tetra­hedral geometry with bond angles ranging from 102.17 (13) to 119.77 (14)°. The ethyl acrylate substituent adopts an extented conformation with all torsion angles close to 180°. In the crystal, mol­ecules are linked into centrosymmetric R (2) (2)(14) dimers via pairs of C—H⋯O hydrogen bonds.
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spelling pubmed-36295222013-04-30 Ethyl (2E,4E)-5-(3-bromo­phenyl­sulfon­yl)penta-2,4-dienoate Sabari, V. Sankar, Ulaganathan Uma, Ramakrishnan Aravindhan, S. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(13)H(13)BrO(4)S, both C=C double bonds adopt an E conformation. The S atom has a distorted tetra­hedral geometry with bond angles ranging from 102.17 (13) to 119.77 (14)°. The ethyl acrylate substituent adopts an extented conformation with all torsion angles close to 180°. In the crystal, mol­ecules are linked into centrosymmetric R (2) (2)(14) dimers via pairs of C—H⋯O hydrogen bonds. International Union of Crystallography 2013-03-06 /pmc/articles/PMC3629522/ /pubmed/23634040 http://dx.doi.org/10.1107/S1600536813005771 Text en © Sabari et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Sabari, V.
Sankar, Ulaganathan
Uma, Ramakrishnan
Aravindhan, S.
Ethyl (2E,4E)-5-(3-bromo­phenyl­sulfon­yl)penta-2,4-dienoate
title Ethyl (2E,4E)-5-(3-bromo­phenyl­sulfon­yl)penta-2,4-dienoate
title_full Ethyl (2E,4E)-5-(3-bromo­phenyl­sulfon­yl)penta-2,4-dienoate
title_fullStr Ethyl (2E,4E)-5-(3-bromo­phenyl­sulfon­yl)penta-2,4-dienoate
title_full_unstemmed Ethyl (2E,4E)-5-(3-bromo­phenyl­sulfon­yl)penta-2,4-dienoate
title_short Ethyl (2E,4E)-5-(3-bromo­phenyl­sulfon­yl)penta-2,4-dienoate
title_sort ethyl (2e,4e)-5-(3-bromo­phenyl­sulfon­yl)penta-2,4-dienoate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3629522/
https://www.ncbi.nlm.nih.gov/pubmed/23634040
http://dx.doi.org/10.1107/S1600536813005771
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AT aravindhans ethyl2e4e53bromophenylsulfonylpenta24dienoate

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