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2-Amino-6-methyl-5-{5-[(naphthalen-2-yl­oxy)meth­yl]-1,3,4-oxadiazol-2-ylsulfan­yl}-4-(3-nitro­phen­yl)pyridine-3-carbonitrile

The asymmetric unit of the title compound, C(26)H(18)N(6)O(4)S, contains two independent mol­ecules (A and B). The dihedral angles between the oxadiazole ring and naphthalene ring system are 42.59 (14) and 6.88 (14) Å in mol­ecules A and B, respectively. The dihedral angles between the pyridine and...

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Autores principales: Fun, Hoong-Kun, Chidan Kumar, C. S., Patrao, Prescilla, Khader, A. M. A., Kalluraya, Balakrishna
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3629525/
https://www.ncbi.nlm.nih.gov/pubmed/23634043
http://dx.doi.org/10.1107/S1600536813005837
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author Fun, Hoong-Kun
Chidan Kumar, C. S.
Patrao, Prescilla
Khader, A. M. A.
Kalluraya, Balakrishna
author_facet Fun, Hoong-Kun
Chidan Kumar, C. S.
Patrao, Prescilla
Khader, A. M. A.
Kalluraya, Balakrishna
author_sort Fun, Hoong-Kun
collection PubMed
description The asymmetric unit of the title compound, C(26)H(18)N(6)O(4)S, contains two independent mol­ecules (A and B). The dihedral angles between the oxadiazole ring and naphthalene ring system are 42.59 (14) and 6.88 (14) Å in mol­ecules A and B, respectively. The dihedral angles between the pyridine and benzene rings in A and B are 65.53 (13 )and 87.67 (13) Å, respectively. In the crystal, mol­ecules A and B are linked through a pair of N—H⋯N hydrogen bonds involving one -NH(2) group H atom and second pair of N—H⋯N hydrogen bonds involving the other -NH(2) group H atom, forming an –ABAB– ribbon along [100] containing R (2) (2)(8) and R (2) (2)(12) ring motifs. These ribbons are further connected by weak C—H⋯N, C—H⋯O and C—H⋯π inter­actions, resulting in a three-dimensional network. The crystal studied was a non-merohedral twin with refined components 0.906 (1):0.094 (1).
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spelling pubmed-36295252013-04-30 2-Amino-6-methyl-5-{5-[(naphthalen-2-yl­oxy)meth­yl]-1,3,4-oxadiazol-2-ylsulfan­yl}-4-(3-nitro­phen­yl)pyridine-3-carbonitrile Fun, Hoong-Kun Chidan Kumar, C. S. Patrao, Prescilla Khader, A. M. A. Kalluraya, Balakrishna Acta Crystallogr Sect E Struct Rep Online Organic Papers The asymmetric unit of the title compound, C(26)H(18)N(6)O(4)S, contains two independent mol­ecules (A and B). The dihedral angles between the oxadiazole ring and naphthalene ring system are 42.59 (14) and 6.88 (14) Å in mol­ecules A and B, respectively. The dihedral angles between the pyridine and benzene rings in A and B are 65.53 (13 )and 87.67 (13) Å, respectively. In the crystal, mol­ecules A and B are linked through a pair of N—H⋯N hydrogen bonds involving one -NH(2) group H atom and second pair of N—H⋯N hydrogen bonds involving the other -NH(2) group H atom, forming an –ABAB– ribbon along [100] containing R (2) (2)(8) and R (2) (2)(12) ring motifs. These ribbons are further connected by weak C—H⋯N, C—H⋯O and C—H⋯π inter­actions, resulting in a three-dimensional network. The crystal studied was a non-merohedral twin with refined components 0.906 (1):0.094 (1). International Union of Crystallography 2013-03-06 /pmc/articles/PMC3629525/ /pubmed/23634043 http://dx.doi.org/10.1107/S1600536813005837 Text en © Fun et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Fun, Hoong-Kun
Chidan Kumar, C. S.
Patrao, Prescilla
Khader, A. M. A.
Kalluraya, Balakrishna
2-Amino-6-methyl-5-{5-[(naphthalen-2-yl­oxy)meth­yl]-1,3,4-oxadiazol-2-ylsulfan­yl}-4-(3-nitro­phen­yl)pyridine-3-carbonitrile
title 2-Amino-6-methyl-5-{5-[(naphthalen-2-yl­oxy)meth­yl]-1,3,4-oxadiazol-2-ylsulfan­yl}-4-(3-nitro­phen­yl)pyridine-3-carbonitrile
title_full 2-Amino-6-methyl-5-{5-[(naphthalen-2-yl­oxy)meth­yl]-1,3,4-oxadiazol-2-ylsulfan­yl}-4-(3-nitro­phen­yl)pyridine-3-carbonitrile
title_fullStr 2-Amino-6-methyl-5-{5-[(naphthalen-2-yl­oxy)meth­yl]-1,3,4-oxadiazol-2-ylsulfan­yl}-4-(3-nitro­phen­yl)pyridine-3-carbonitrile
title_full_unstemmed 2-Amino-6-methyl-5-{5-[(naphthalen-2-yl­oxy)meth­yl]-1,3,4-oxadiazol-2-ylsulfan­yl}-4-(3-nitro­phen­yl)pyridine-3-carbonitrile
title_short 2-Amino-6-methyl-5-{5-[(naphthalen-2-yl­oxy)meth­yl]-1,3,4-oxadiazol-2-ylsulfan­yl}-4-(3-nitro­phen­yl)pyridine-3-carbonitrile
title_sort 2-amino-6-methyl-5-{5-[(naphthalen-2-yl­oxy)meth­yl]-1,3,4-oxadiazol-2-ylsulfan­yl}-4-(3-nitro­phen­yl)pyridine-3-carbonitrile
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3629525/
https://www.ncbi.nlm.nih.gov/pubmed/23634043
http://dx.doi.org/10.1107/S1600536813005837
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