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2-Amino-6-methyl-5-{5-[(naphthalen-2-yloxy)methyl]-1,3,4-oxadiazol-2-ylsulfanyl}-4-(3-nitrophenyl)pyridine-3-carbonitrile
The asymmetric unit of the title compound, C(26)H(18)N(6)O(4)S, contains two independent molecules (A and B). The dihedral angles between the oxadiazole ring and naphthalene ring system are 42.59 (14) and 6.88 (14) Å in molecules A and B, respectively. The dihedral angles between the pyridine and...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3629525/ https://www.ncbi.nlm.nih.gov/pubmed/23634043 http://dx.doi.org/10.1107/S1600536813005837 |
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author | Fun, Hoong-Kun Chidan Kumar, C. S. Patrao, Prescilla Khader, A. M. A. Kalluraya, Balakrishna |
author_facet | Fun, Hoong-Kun Chidan Kumar, C. S. Patrao, Prescilla Khader, A. M. A. Kalluraya, Balakrishna |
author_sort | Fun, Hoong-Kun |
collection | PubMed |
description | The asymmetric unit of the title compound, C(26)H(18)N(6)O(4)S, contains two independent molecules (A and B). The dihedral angles between the oxadiazole ring and naphthalene ring system are 42.59 (14) and 6.88 (14) Å in molecules A and B, respectively. The dihedral angles between the pyridine and benzene rings in A and B are 65.53 (13 )and 87.67 (13) Å, respectively. In the crystal, molecules A and B are linked through a pair of N—H⋯N hydrogen bonds involving one -NH(2) group H atom and second pair of N—H⋯N hydrogen bonds involving the other -NH(2) group H atom, forming an –ABAB– ribbon along [100] containing R (2) (2)(8) and R (2) (2)(12) ring motifs. These ribbons are further connected by weak C—H⋯N, C—H⋯O and C—H⋯π interactions, resulting in a three-dimensional network. The crystal studied was a non-merohedral twin with refined components 0.906 (1):0.094 (1). |
format | Online Article Text |
id | pubmed-3629525 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2013 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-36295252013-04-30 2-Amino-6-methyl-5-{5-[(naphthalen-2-yloxy)methyl]-1,3,4-oxadiazol-2-ylsulfanyl}-4-(3-nitrophenyl)pyridine-3-carbonitrile Fun, Hoong-Kun Chidan Kumar, C. S. Patrao, Prescilla Khader, A. M. A. Kalluraya, Balakrishna Acta Crystallogr Sect E Struct Rep Online Organic Papers The asymmetric unit of the title compound, C(26)H(18)N(6)O(4)S, contains two independent molecules (A and B). The dihedral angles between the oxadiazole ring and naphthalene ring system are 42.59 (14) and 6.88 (14) Å in molecules A and B, respectively. The dihedral angles between the pyridine and benzene rings in A and B are 65.53 (13 )and 87.67 (13) Å, respectively. In the crystal, molecules A and B are linked through a pair of N—H⋯N hydrogen bonds involving one -NH(2) group H atom and second pair of N—H⋯N hydrogen bonds involving the other -NH(2) group H atom, forming an –ABAB– ribbon along [100] containing R (2) (2)(8) and R (2) (2)(12) ring motifs. These ribbons are further connected by weak C—H⋯N, C—H⋯O and C—H⋯π interactions, resulting in a three-dimensional network. The crystal studied was a non-merohedral twin with refined components 0.906 (1):0.094 (1). International Union of Crystallography 2013-03-06 /pmc/articles/PMC3629525/ /pubmed/23634043 http://dx.doi.org/10.1107/S1600536813005837 Text en © Fun et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Fun, Hoong-Kun Chidan Kumar, C. S. Patrao, Prescilla Khader, A. M. A. Kalluraya, Balakrishna 2-Amino-6-methyl-5-{5-[(naphthalen-2-yloxy)methyl]-1,3,4-oxadiazol-2-ylsulfanyl}-4-(3-nitrophenyl)pyridine-3-carbonitrile |
title | 2-Amino-6-methyl-5-{5-[(naphthalen-2-yloxy)methyl]-1,3,4-oxadiazol-2-ylsulfanyl}-4-(3-nitrophenyl)pyridine-3-carbonitrile |
title_full | 2-Amino-6-methyl-5-{5-[(naphthalen-2-yloxy)methyl]-1,3,4-oxadiazol-2-ylsulfanyl}-4-(3-nitrophenyl)pyridine-3-carbonitrile |
title_fullStr | 2-Amino-6-methyl-5-{5-[(naphthalen-2-yloxy)methyl]-1,3,4-oxadiazol-2-ylsulfanyl}-4-(3-nitrophenyl)pyridine-3-carbonitrile |
title_full_unstemmed | 2-Amino-6-methyl-5-{5-[(naphthalen-2-yloxy)methyl]-1,3,4-oxadiazol-2-ylsulfanyl}-4-(3-nitrophenyl)pyridine-3-carbonitrile |
title_short | 2-Amino-6-methyl-5-{5-[(naphthalen-2-yloxy)methyl]-1,3,4-oxadiazol-2-ylsulfanyl}-4-(3-nitrophenyl)pyridine-3-carbonitrile |
title_sort | 2-amino-6-methyl-5-{5-[(naphthalen-2-yloxy)methyl]-1,3,4-oxadiazol-2-ylsulfanyl}-4-(3-nitrophenyl)pyridine-3-carbonitrile |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3629525/ https://www.ncbi.nlm.nih.gov/pubmed/23634043 http://dx.doi.org/10.1107/S1600536813005837 |
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