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2-(2-Chlorophenyl)-N-cyclohexyl-2-oxoacetamide
In the title compound, C(14)H(16)ClNO(2), the cyclohexyl ring has a chair conformation. The dihedral angle between the benzene ring and the mean plane of the four planar C atoms of the cyclohexyl ring is 45.2 (3)°. The two carbonyl groups are trans to one another, with an O=C—C=O torsion angle of...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3629535/ https://www.ncbi.nlm.nih.gov/pubmed/23634053 http://dx.doi.org/10.1107/S1600536813005904 |
Sumario: | In the title compound, C(14)H(16)ClNO(2), the cyclohexyl ring has a chair conformation. The dihedral angle between the benzene ring and the mean plane of the four planar C atoms of the cyclohexyl ring is 45.2 (3)°. The two carbonyl groups are trans to one another, with an O=C—C=O torsion angle of −137.1 (3)°. In the crystal, molecules are linked by N—H⋯O hydrogen bonds forming chains propagating along [001]. A region of disordered electron density, situated near the unit-cell corners, was treated using the SQUEEZE routine in PLATON [Spek (2009 ▶). Acta Cryst. D65, 148–155]. It gave a solvent-accessible void of ca 400 Å(3) for only 21 electrons. It is probably due to traces of the solvent of crystallization and was not taken into account during structure refinement. |
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