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2-(2-Chlorophenyl)-N-cyclohexyl-2-oxoacetamide
In the title compound, C(14)H(16)ClNO(2), the cyclohexyl ring has a chair conformation. The dihedral angle between the benzene ring and the mean plane of the four planar C atoms of the cyclohexyl ring is 45.2 (3)°. The two carbonyl groups are trans to one another, with an O=C—C=O torsion angle of...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3629535/ https://www.ncbi.nlm.nih.gov/pubmed/23634053 http://dx.doi.org/10.1107/S1600536813005904 |
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author | Jin, Xiu-Dan Wu, Jin-Long |
author_facet | Jin, Xiu-Dan Wu, Jin-Long |
author_sort | Jin, Xiu-Dan |
collection | PubMed |
description | In the title compound, C(14)H(16)ClNO(2), the cyclohexyl ring has a chair conformation. The dihedral angle between the benzene ring and the mean plane of the four planar C atoms of the cyclohexyl ring is 45.2 (3)°. The two carbonyl groups are trans to one another, with an O=C—C=O torsion angle of −137.1 (3)°. In the crystal, molecules are linked by N—H⋯O hydrogen bonds forming chains propagating along [001]. A region of disordered electron density, situated near the unit-cell corners, was treated using the SQUEEZE routine in PLATON [Spek (2009 ▶). Acta Cryst. D65, 148–155]. It gave a solvent-accessible void of ca 400 Å(3) for only 21 electrons. It is probably due to traces of the solvent of crystallization and was not taken into account during structure refinement. |
format | Online Article Text |
id | pubmed-3629535 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2013 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-36295352013-04-30 2-(2-Chlorophenyl)-N-cyclohexyl-2-oxoacetamide Jin, Xiu-Dan Wu, Jin-Long Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(14)H(16)ClNO(2), the cyclohexyl ring has a chair conformation. The dihedral angle between the benzene ring and the mean plane of the four planar C atoms of the cyclohexyl ring is 45.2 (3)°. The two carbonyl groups are trans to one another, with an O=C—C=O torsion angle of −137.1 (3)°. In the crystal, molecules are linked by N—H⋯O hydrogen bonds forming chains propagating along [001]. A region of disordered electron density, situated near the unit-cell corners, was treated using the SQUEEZE routine in PLATON [Spek (2009 ▶). Acta Cryst. D65, 148–155]. It gave a solvent-accessible void of ca 400 Å(3) for only 21 electrons. It is probably due to traces of the solvent of crystallization and was not taken into account during structure refinement. International Union of Crystallography 2013-03-09 /pmc/articles/PMC3629535/ /pubmed/23634053 http://dx.doi.org/10.1107/S1600536813005904 Text en © Jin and Wu 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Jin, Xiu-Dan Wu, Jin-Long 2-(2-Chlorophenyl)-N-cyclohexyl-2-oxoacetamide |
title | 2-(2-Chlorophenyl)-N-cyclohexyl-2-oxoacetamide |
title_full | 2-(2-Chlorophenyl)-N-cyclohexyl-2-oxoacetamide |
title_fullStr | 2-(2-Chlorophenyl)-N-cyclohexyl-2-oxoacetamide |
title_full_unstemmed | 2-(2-Chlorophenyl)-N-cyclohexyl-2-oxoacetamide |
title_short | 2-(2-Chlorophenyl)-N-cyclohexyl-2-oxoacetamide |
title_sort | 2-(2-chlorophenyl)-n-cyclohexyl-2-oxoacetamide |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3629535/ https://www.ncbi.nlm.nih.gov/pubmed/23634053 http://dx.doi.org/10.1107/S1600536813005904 |
work_keys_str_mv | AT jinxiudan 22chlorophenylncyclohexyl2oxoacetamide AT wujinlong 22chlorophenylncyclohexyl2oxoacetamide |