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2-(2-Chloro­phen­yl)-N-cyclo­hexyl-2-oxoacetamide

In the title compound, C(14)H(16)ClNO(2), the cyclo­hexyl ring has a chair conformation. The dihedral angle between the benzene ring and the mean plane of the four planar C atoms of the cyclo­hexyl ring is 45.2 (3)°. The two carbonyl groups are trans to one another, with an O=C—C=O torsion angle of...

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Detalles Bibliográficos
Autores principales: Jin, Xiu-Dan, Wu, Jin-Long
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3629535/
https://www.ncbi.nlm.nih.gov/pubmed/23634053
http://dx.doi.org/10.1107/S1600536813005904
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author Jin, Xiu-Dan
Wu, Jin-Long
author_facet Jin, Xiu-Dan
Wu, Jin-Long
author_sort Jin, Xiu-Dan
collection PubMed
description In the title compound, C(14)H(16)ClNO(2), the cyclo­hexyl ring has a chair conformation. The dihedral angle between the benzene ring and the mean plane of the four planar C atoms of the cyclo­hexyl ring is 45.2 (3)°. The two carbonyl groups are trans to one another, with an O=C—C=O torsion angle of −137.1 (3)°. In the crystal, mol­ecules are linked by N—H⋯O hydrogen bonds forming chains propagating along [001]. A region of disordered electron density, situated near the unit-cell corners, was treated using the SQUEEZE routine in PLATON [Spek (2009 ▶). Acta Cryst. D65, 148–155]. It gave a solvent-accessible void of ca 400 Å(3) for only 21 electrons. It is probably due to traces of the solvent of crystallization and was not taken into account during structure refinement.
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spelling pubmed-36295352013-04-30 2-(2-Chloro­phen­yl)-N-cyclo­hexyl-2-oxoacetamide Jin, Xiu-Dan Wu, Jin-Long Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(14)H(16)ClNO(2), the cyclo­hexyl ring has a chair conformation. The dihedral angle between the benzene ring and the mean plane of the four planar C atoms of the cyclo­hexyl ring is 45.2 (3)°. The two carbonyl groups are trans to one another, with an O=C—C=O torsion angle of −137.1 (3)°. In the crystal, mol­ecules are linked by N—H⋯O hydrogen bonds forming chains propagating along [001]. A region of disordered electron density, situated near the unit-cell corners, was treated using the SQUEEZE routine in PLATON [Spek (2009 ▶). Acta Cryst. D65, 148–155]. It gave a solvent-accessible void of ca 400 Å(3) for only 21 electrons. It is probably due to traces of the solvent of crystallization and was not taken into account during structure refinement. International Union of Crystallography 2013-03-09 /pmc/articles/PMC3629535/ /pubmed/23634053 http://dx.doi.org/10.1107/S1600536813005904 Text en © Jin and Wu 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Jin, Xiu-Dan
Wu, Jin-Long
2-(2-Chloro­phen­yl)-N-cyclo­hexyl-2-oxoacetamide
title 2-(2-Chloro­phen­yl)-N-cyclo­hexyl-2-oxoacetamide
title_full 2-(2-Chloro­phen­yl)-N-cyclo­hexyl-2-oxoacetamide
title_fullStr 2-(2-Chloro­phen­yl)-N-cyclo­hexyl-2-oxoacetamide
title_full_unstemmed 2-(2-Chloro­phen­yl)-N-cyclo­hexyl-2-oxoacetamide
title_short 2-(2-Chloro­phen­yl)-N-cyclo­hexyl-2-oxoacetamide
title_sort 2-(2-chloro­phen­yl)-n-cyclo­hexyl-2-oxoacetamide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3629535/
https://www.ncbi.nlm.nih.gov/pubmed/23634053
http://dx.doi.org/10.1107/S1600536813005904
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