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2-(4-Fluorobenzylidene)propanedinitrile: monoclinic polymorph
The title compound, C(10)H(5)FN(2), is a monoclinic (P2(1)/c) polymorph of the previously reported triclinic (P-1) form [Antipin et al. (2003 ▶). J. Mol. Struct. 650, 1–20]. The 13 non-H atoms in the title polymorph are almost coplanar (r.m.s. deviation = 0.020 Å); a small twist between the fluoro...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3629574/ https://www.ncbi.nlm.nih.gov/pubmed/23634061 http://dx.doi.org/10.1107/S1600536813006235 |
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author | El-Agrody, Ahmed M. Al-Omar, Mohamed A. Amr, Abd El-Galil E. Ng, Seik Weng Tiekink, Edward R. T. |
author_facet | El-Agrody, Ahmed M. Al-Omar, Mohamed A. Amr, Abd El-Galil E. Ng, Seik Weng Tiekink, Edward R. T. |
author_sort | El-Agrody, Ahmed M. |
collection | PubMed |
description | The title compound, C(10)H(5)FN(2), is a monoclinic (P2(1)/c) polymorph of the previously reported triclinic (P-1) form [Antipin et al. (2003 ▶). J. Mol. Struct. 650, 1–20]. The 13 non-H atoms in the title polymorph are almost coplanar (r.m.s. deviation = 0.020 Å); a small twist between the fluorobenzene and dinitrile groups [C—C—C—C torsion angle = 175.49 (16)°] is evident in the triclinic polymorph. In the crystal, C—H⋯N interactions lead to supramolecular layers parallel to (-101); these are connected by C—F⋯π interactions. |
format | Online Article Text |
id | pubmed-3629574 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2013 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-36295742013-04-30 2-(4-Fluorobenzylidene)propanedinitrile: monoclinic polymorph El-Agrody, Ahmed M. Al-Omar, Mohamed A. Amr, Abd El-Galil E. Ng, Seik Weng Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(10)H(5)FN(2), is a monoclinic (P2(1)/c) polymorph of the previously reported triclinic (P-1) form [Antipin et al. (2003 ▶). J. Mol. Struct. 650, 1–20]. The 13 non-H atoms in the title polymorph are almost coplanar (r.m.s. deviation = 0.020 Å); a small twist between the fluorobenzene and dinitrile groups [C—C—C—C torsion angle = 175.49 (16)°] is evident in the triclinic polymorph. In the crystal, C—H⋯N interactions lead to supramolecular layers parallel to (-101); these are connected by C—F⋯π interactions. International Union of Crystallography 2013-03-09 /pmc/articles/PMC3629574/ /pubmed/23634061 http://dx.doi.org/10.1107/S1600536813006235 Text en © El-Agrody et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers El-Agrody, Ahmed M. Al-Omar, Mohamed A. Amr, Abd El-Galil E. Ng, Seik Weng Tiekink, Edward R. T. 2-(4-Fluorobenzylidene)propanedinitrile: monoclinic polymorph |
title | 2-(4-Fluorobenzylidene)propanedinitrile: monoclinic polymorph |
title_full | 2-(4-Fluorobenzylidene)propanedinitrile: monoclinic polymorph |
title_fullStr | 2-(4-Fluorobenzylidene)propanedinitrile: monoclinic polymorph |
title_full_unstemmed | 2-(4-Fluorobenzylidene)propanedinitrile: monoclinic polymorph |
title_short | 2-(4-Fluorobenzylidene)propanedinitrile: monoclinic polymorph |
title_sort | 2-(4-fluorobenzylidene)propanedinitrile: monoclinic polymorph |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3629574/ https://www.ncbi.nlm.nih.gov/pubmed/23634061 http://dx.doi.org/10.1107/S1600536813006235 |
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