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2-(4-Fluoro­benzyl­idene)propane­dinitrile: monoclinic polymorph

The title compound, C(10)H(5)FN(2), is a monoclinic (P2(1)/c) polymorph of the previously reported triclinic (P-1) form [Anti­pin et al. (2003 ▶). J. Mol. Struct. 650, 1–20]. The 13 non-H atoms in the title polymorph are almost coplanar (r.m.s. deviation = 0.020 Å); a small twist between the fluoro­...

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Autores principales: El-Agrody, Ahmed M., Al-Omar, Mohamed A., Amr, Abd El-Galil E., Ng, Seik Weng, Tiekink, Edward R. T.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3629574/
https://www.ncbi.nlm.nih.gov/pubmed/23634061
http://dx.doi.org/10.1107/S1600536813006235
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author El-Agrody, Ahmed M.
Al-Omar, Mohamed A.
Amr, Abd El-Galil E.
Ng, Seik Weng
Tiekink, Edward R. T.
author_facet El-Agrody, Ahmed M.
Al-Omar, Mohamed A.
Amr, Abd El-Galil E.
Ng, Seik Weng
Tiekink, Edward R. T.
author_sort El-Agrody, Ahmed M.
collection PubMed
description The title compound, C(10)H(5)FN(2), is a monoclinic (P2(1)/c) polymorph of the previously reported triclinic (P-1) form [Anti­pin et al. (2003 ▶). J. Mol. Struct. 650, 1–20]. The 13 non-H atoms in the title polymorph are almost coplanar (r.m.s. deviation = 0.020 Å); a small twist between the fluoro­benzene and dinitrile groups [C—C—C—C torsion angle = 175.49 (16)°] is evident in the triclinic polymorph. In the crystal, C—H⋯N inter­actions lead to supra­molecular layers parallel to (-101); these are connected by C—F⋯π inter­actions.
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spelling pubmed-36295742013-04-30 2-(4-Fluoro­benzyl­idene)propane­dinitrile: monoclinic polymorph El-Agrody, Ahmed M. Al-Omar, Mohamed A. Amr, Abd El-Galil E. Ng, Seik Weng Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(10)H(5)FN(2), is a monoclinic (P2(1)/c) polymorph of the previously reported triclinic (P-1) form [Anti­pin et al. (2003 ▶). J. Mol. Struct. 650, 1–20]. The 13 non-H atoms in the title polymorph are almost coplanar (r.m.s. deviation = 0.020 Å); a small twist between the fluoro­benzene and dinitrile groups [C—C—C—C torsion angle = 175.49 (16)°] is evident in the triclinic polymorph. In the crystal, C—H⋯N inter­actions lead to supra­molecular layers parallel to (-101); these are connected by C—F⋯π inter­actions. International Union of Crystallography 2013-03-09 /pmc/articles/PMC3629574/ /pubmed/23634061 http://dx.doi.org/10.1107/S1600536813006235 Text en © El-Agrody et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
El-Agrody, Ahmed M.
Al-Omar, Mohamed A.
Amr, Abd El-Galil E.
Ng, Seik Weng
Tiekink, Edward R. T.
2-(4-Fluoro­benzyl­idene)propane­dinitrile: monoclinic polymorph
title 2-(4-Fluoro­benzyl­idene)propane­dinitrile: monoclinic polymorph
title_full 2-(4-Fluoro­benzyl­idene)propane­dinitrile: monoclinic polymorph
title_fullStr 2-(4-Fluoro­benzyl­idene)propane­dinitrile: monoclinic polymorph
title_full_unstemmed 2-(4-Fluoro­benzyl­idene)propane­dinitrile: monoclinic polymorph
title_short 2-(4-Fluoro­benzyl­idene)propane­dinitrile: monoclinic polymorph
title_sort 2-(4-fluoro­benzyl­idene)propane­dinitrile: monoclinic polymorph
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3629574/
https://www.ncbi.nlm.nih.gov/pubmed/23634061
http://dx.doi.org/10.1107/S1600536813006235
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