N-Cyclo­hexyl-3-methyl­benzamidine

The title amidine compound, C(14)H(20)N(2), prepared by a one-pot reaction, is asymmetric as only one N atom has an alkyl substituent. The terminal cyclo­hexyl group connected to the amino N atom is located on the other side of the N—C—N skeleton to the 4-methylbenzene ring and has a chair conformat...

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Detalles Bibliográficos
Autores principales: Liu, Rui-Qin, Bai, Sheng-Di, Wang, Tao
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3629577/
https://www.ncbi.nlm.nih.gov/pubmed/23634064
http://dx.doi.org/10.1107/S1600536813006272
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author Liu, Rui-Qin
Bai, Sheng-Di
Wang, Tao
author_facet Liu, Rui-Qin
Bai, Sheng-Di
Wang, Tao
author_sort Liu, Rui-Qin
collection PubMed
description The title amidine compound, C(14)H(20)N(2), prepared by a one-pot reaction, is asymmetric as only one N atom has an alkyl substituent. The terminal cyclo­hexyl group connected to the amino N atom is located on the other side of the N—C—N skeleton to the 4-methylbenzene ring and has a chair conformation. The dihedral angle between the phenyl ring and the NCN plane is 47.87 (12)°. In the crystal, mol­ecules are linked via N—H⋯N hydrogen bonds, forming chains propagating along the a-axis direction.
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spelling pubmed-36295772013-04-30 N-Cyclo­hexyl-3-methyl­benzamidine Liu, Rui-Qin Bai, Sheng-Di Wang, Tao Acta Crystallogr Sect E Struct Rep Online Organic Papers The title amidine compound, C(14)H(20)N(2), prepared by a one-pot reaction, is asymmetric as only one N atom has an alkyl substituent. The terminal cyclo­hexyl group connected to the amino N atom is located on the other side of the N—C—N skeleton to the 4-methylbenzene ring and has a chair conformation. The dihedral angle between the phenyl ring and the NCN plane is 47.87 (12)°. In the crystal, mol­ecules are linked via N—H⋯N hydrogen bonds, forming chains propagating along the a-axis direction. International Union of Crystallography 2013-03-09 /pmc/articles/PMC3629577/ /pubmed/23634064 http://dx.doi.org/10.1107/S1600536813006272 Text en © Liu et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Liu, Rui-Qin
Bai, Sheng-Di
Wang, Tao
N-Cyclo­hexyl-3-methyl­benzamidine
title N-Cyclo­hexyl-3-methyl­benzamidine
title_full N-Cyclo­hexyl-3-methyl­benzamidine
title_fullStr N-Cyclo­hexyl-3-methyl­benzamidine
title_full_unstemmed N-Cyclo­hexyl-3-methyl­benzamidine
title_short N-Cyclo­hexyl-3-methyl­benzamidine
title_sort n-cyclo­hexyl-3-methyl­benzamidine
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3629577/
https://www.ncbi.nlm.nih.gov/pubmed/23634064
http://dx.doi.org/10.1107/S1600536813006272
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AT baishengdi ncyclohexyl3methylbenzamidine
AT wangtao ncyclohexyl3methylbenzamidine

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