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4-(1-Allyl-4,5-diphenyl-1H-imidazol-2-yl)-N,N-dimethyl­aniline

The title compound, C(26)H(25)N(3), crystallizes with four independent mol­ecules, 1–4, in the asymmetric unit of the triclinic unit cell. The allyl substituents on the imidazole rings adopt similar conformations in all four mol­ecules. The imadazole and the 4-and 5-substituted phenyl rings of two p...

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Detalles Bibliográficos
Autores principales: Akkurt, Mehmet, Fronczek, Frank R., Mohamed, Shaaban K., Talybov, Avtandil H., Marzouk, Adel A. E., Abdelhamid, Antar A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3629582/
https://www.ncbi.nlm.nih.gov/pubmed/23634069
http://dx.doi.org/10.1107/S1600536813006326
Descripción
Sumario:The title compound, C(26)H(25)N(3), crystallizes with four independent mol­ecules, 1–4, in the asymmetric unit of the triclinic unit cell. The allyl substituents on the imidazole rings adopt similar conformations in all four mol­ecules. The imadazole and the 4-and 5-substituted phenyl rings of two pairs of molecules in the asymmetric unit stack parallel to (110). In contrast, the dimethyl­aniline systems in these pairs of mol­ecules are almost normal to one another, with dihedral angles of 85.84 (10) and 85.65 (10)° between the benzene rings of the two dimethyl­aniline fragments of mol­ecules 1 and 2, and 3 and 4, respectively. The crystal structure features an extensive series of C—H⋯π inter­actions that link the mol­ecules into undulating rows along the c axis. The crystal studied was a pseudo-merohedral twin with twin law [-100, 0-10, 111] and the BASF parameter refined to 0.513 (3).