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4-(1-Allyl-4,5-diphenyl-1H-imidazol-2-yl)-N,N-dimethylaniline
The title compound, C(26)H(25)N(3), crystallizes with four independent molecules, 1–4, in the asymmetric unit of the triclinic unit cell. The allyl substituents on the imidazole rings adopt similar conformations in all four molecules. The imadazole and the 4-and 5-substituted phenyl rings of two p...
Autores principales: | , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3629582/ https://www.ncbi.nlm.nih.gov/pubmed/23634069 http://dx.doi.org/10.1107/S1600536813006326 |
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author | Akkurt, Mehmet Fronczek, Frank R. Mohamed, Shaaban K. Talybov, Avtandil H. Marzouk, Adel A. E. Abdelhamid, Antar A. |
author_facet | Akkurt, Mehmet Fronczek, Frank R. Mohamed, Shaaban K. Talybov, Avtandil H. Marzouk, Adel A. E. Abdelhamid, Antar A. |
author_sort | Akkurt, Mehmet |
collection | PubMed |
description | The title compound, C(26)H(25)N(3), crystallizes with four independent molecules, 1–4, in the asymmetric unit of the triclinic unit cell. The allyl substituents on the imidazole rings adopt similar conformations in all four molecules. The imadazole and the 4-and 5-substituted phenyl rings of two pairs of molecules in the asymmetric unit stack parallel to (110). In contrast, the dimethylaniline systems in these pairs of molecules are almost normal to one another, with dihedral angles of 85.84 (10) and 85.65 (10)° between the benzene rings of the two dimethylaniline fragments of molecules 1 and 2, and 3 and 4, respectively. The crystal structure features an extensive series of C—H⋯π interactions that link the molecules into undulating rows along the c axis. The crystal studied was a pseudo-merohedral twin with twin law [-100, 0-10, 111] and the BASF parameter refined to 0.513 (3). |
format | Online Article Text |
id | pubmed-3629582 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2013 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-36295822013-04-30 4-(1-Allyl-4,5-diphenyl-1H-imidazol-2-yl)-N,N-dimethylaniline Akkurt, Mehmet Fronczek, Frank R. Mohamed, Shaaban K. Talybov, Avtandil H. Marzouk, Adel A. E. Abdelhamid, Antar A. Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(26)H(25)N(3), crystallizes with four independent molecules, 1–4, in the asymmetric unit of the triclinic unit cell. The allyl substituents on the imidazole rings adopt similar conformations in all four molecules. The imadazole and the 4-and 5-substituted phenyl rings of two pairs of molecules in the asymmetric unit stack parallel to (110). In contrast, the dimethylaniline systems in these pairs of molecules are almost normal to one another, with dihedral angles of 85.84 (10) and 85.65 (10)° between the benzene rings of the two dimethylaniline fragments of molecules 1 and 2, and 3 and 4, respectively. The crystal structure features an extensive series of C—H⋯π interactions that link the molecules into undulating rows along the c axis. The crystal studied was a pseudo-merohedral twin with twin law [-100, 0-10, 111] and the BASF parameter refined to 0.513 (3). International Union of Crystallography 2013-03-09 /pmc/articles/PMC3629582/ /pubmed/23634069 http://dx.doi.org/10.1107/S1600536813006326 Text en © Akkurt et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Akkurt, Mehmet Fronczek, Frank R. Mohamed, Shaaban K. Talybov, Avtandil H. Marzouk, Adel A. E. Abdelhamid, Antar A. 4-(1-Allyl-4,5-diphenyl-1H-imidazol-2-yl)-N,N-dimethylaniline |
title | 4-(1-Allyl-4,5-diphenyl-1H-imidazol-2-yl)-N,N-dimethylaniline |
title_full | 4-(1-Allyl-4,5-diphenyl-1H-imidazol-2-yl)-N,N-dimethylaniline |
title_fullStr | 4-(1-Allyl-4,5-diphenyl-1H-imidazol-2-yl)-N,N-dimethylaniline |
title_full_unstemmed | 4-(1-Allyl-4,5-diphenyl-1H-imidazol-2-yl)-N,N-dimethylaniline |
title_short | 4-(1-Allyl-4,5-diphenyl-1H-imidazol-2-yl)-N,N-dimethylaniline |
title_sort | 4-(1-allyl-4,5-diphenyl-1h-imidazol-2-yl)-n,n-dimethylaniline |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3629582/ https://www.ncbi.nlm.nih.gov/pubmed/23634069 http://dx.doi.org/10.1107/S1600536813006326 |
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