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4-(1-Allyl-4,5-diphenyl-1H-imidazol-2-yl)-N,N-dimethyl­aniline

The title compound, C(26)H(25)N(3), crystallizes with four independent mol­ecules, 1–4, in the asymmetric unit of the triclinic unit cell. The allyl substituents on the imidazole rings adopt similar conformations in all four mol­ecules. The imadazole and the 4-and 5-substituted phenyl rings of two p...

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Autores principales: Akkurt, Mehmet, Fronczek, Frank R., Mohamed, Shaaban K., Talybov, Avtandil H., Marzouk, Adel A. E., Abdelhamid, Antar A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3629582/
https://www.ncbi.nlm.nih.gov/pubmed/23634069
http://dx.doi.org/10.1107/S1600536813006326
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author Akkurt, Mehmet
Fronczek, Frank R.
Mohamed, Shaaban K.
Talybov, Avtandil H.
Marzouk, Adel A. E.
Abdelhamid, Antar A.
author_facet Akkurt, Mehmet
Fronczek, Frank R.
Mohamed, Shaaban K.
Talybov, Avtandil H.
Marzouk, Adel A. E.
Abdelhamid, Antar A.
author_sort Akkurt, Mehmet
collection PubMed
description The title compound, C(26)H(25)N(3), crystallizes with four independent mol­ecules, 1–4, in the asymmetric unit of the triclinic unit cell. The allyl substituents on the imidazole rings adopt similar conformations in all four mol­ecules. The imadazole and the 4-and 5-substituted phenyl rings of two pairs of molecules in the asymmetric unit stack parallel to (110). In contrast, the dimethyl­aniline systems in these pairs of mol­ecules are almost normal to one another, with dihedral angles of 85.84 (10) and 85.65 (10)° between the benzene rings of the two dimethyl­aniline fragments of mol­ecules 1 and 2, and 3 and 4, respectively. The crystal structure features an extensive series of C—H⋯π inter­actions that link the mol­ecules into undulating rows along the c axis. The crystal studied was a pseudo-merohedral twin with twin law [-100, 0-10, 111] and the BASF parameter refined to 0.513 (3).
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spelling pubmed-36295822013-04-30 4-(1-Allyl-4,5-diphenyl-1H-imidazol-2-yl)-N,N-dimethyl­aniline Akkurt, Mehmet Fronczek, Frank R. Mohamed, Shaaban K. Talybov, Avtandil H. Marzouk, Adel A. E. Abdelhamid, Antar A. Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(26)H(25)N(3), crystallizes with four independent mol­ecules, 1–4, in the asymmetric unit of the triclinic unit cell. The allyl substituents on the imidazole rings adopt similar conformations in all four mol­ecules. The imadazole and the 4-and 5-substituted phenyl rings of two pairs of molecules in the asymmetric unit stack parallel to (110). In contrast, the dimethyl­aniline systems in these pairs of mol­ecules are almost normal to one another, with dihedral angles of 85.84 (10) and 85.65 (10)° between the benzene rings of the two dimethyl­aniline fragments of mol­ecules 1 and 2, and 3 and 4, respectively. The crystal structure features an extensive series of C—H⋯π inter­actions that link the mol­ecules into undulating rows along the c axis. The crystal studied was a pseudo-merohedral twin with twin law [-100, 0-10, 111] and the BASF parameter refined to 0.513 (3). International Union of Crystallography 2013-03-09 /pmc/articles/PMC3629582/ /pubmed/23634069 http://dx.doi.org/10.1107/S1600536813006326 Text en © Akkurt et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Akkurt, Mehmet
Fronczek, Frank R.
Mohamed, Shaaban K.
Talybov, Avtandil H.
Marzouk, Adel A. E.
Abdelhamid, Antar A.
4-(1-Allyl-4,5-diphenyl-1H-imidazol-2-yl)-N,N-dimethyl­aniline
title 4-(1-Allyl-4,5-diphenyl-1H-imidazol-2-yl)-N,N-dimethyl­aniline
title_full 4-(1-Allyl-4,5-diphenyl-1H-imidazol-2-yl)-N,N-dimethyl­aniline
title_fullStr 4-(1-Allyl-4,5-diphenyl-1H-imidazol-2-yl)-N,N-dimethyl­aniline
title_full_unstemmed 4-(1-Allyl-4,5-diphenyl-1H-imidazol-2-yl)-N,N-dimethyl­aniline
title_short 4-(1-Allyl-4,5-diphenyl-1H-imidazol-2-yl)-N,N-dimethyl­aniline
title_sort 4-(1-allyl-4,5-diphenyl-1h-imidazol-2-yl)-n,n-dimethyl­aniline
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3629582/
https://www.ncbi.nlm.nih.gov/pubmed/23634069
http://dx.doi.org/10.1107/S1600536813006326
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