2-Amino-4-methyl­pyrimidinium dihydrogen phosphate

A charge-assisted hydrogen-bonding network involving N—H⋯O and O—H⋯O hydrogen bonds stabilizes the crystal of the title salt, C(5)H(8)N(3) (+)·H(2)PO(4) (−). The dihydrogen phosphate anions form one-dimensional chains along [100], via O—H⋯O hydrogen bonds. The 2-amino-4-methyl­pyrimidinium cations a...

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Detalles Bibliográficos
Autores principales: Thomas, Sajesh P., Sunkari, Jyothi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3629583/
https://www.ncbi.nlm.nih.gov/pubmed/23634070
http://dx.doi.org/10.1107/S160053681300648X
Descripción
Sumario:A charge-assisted hydrogen-bonding network involving N—H⋯O and O—H⋯O hydrogen bonds stabilizes the crystal of the title salt, C(5)H(8)N(3) (+)·H(2)PO(4) (−). The dihydrogen phosphate anions form one-dimensional chains along [100], via O—H⋯O hydrogen bonds. The 2-amino-4-methyl­pyrimidinium cations are linked to these chains by means of two different kinds of N—H⋯O hydrogen bonds. Neighbouring chains are linked via C—H⋯N and C—H⋯O hydrogen bonds forming two-dimensional slab-like networks lying parallel to (01-1).

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