2-Amino-4-methyl­pyrimidinium dihydrogen phosphate

A charge-assisted hydrogen-bonding network involving N—H⋯O and O—H⋯O hydrogen bonds stabilizes the crystal of the title salt, C(5)H(8)N(3) (+)·H(2)PO(4) (−). The dihydrogen phosphate anions form one-dimensional chains along [100], via O—H⋯O hydrogen bonds. The 2-amino-4-methyl­pyrimidinium cations a...

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Detalles Bibliográficos
Autores principales: Thomas, Sajesh P., Sunkari, Jyothi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3629583/
https://www.ncbi.nlm.nih.gov/pubmed/23634070
http://dx.doi.org/10.1107/S160053681300648X
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author Thomas, Sajesh P.
Sunkari, Jyothi
author_facet Thomas, Sajesh P.
Sunkari, Jyothi
author_sort Thomas, Sajesh P.
collection PubMed
description A charge-assisted hydrogen-bonding network involving N—H⋯O and O—H⋯O hydrogen bonds stabilizes the crystal of the title salt, C(5)H(8)N(3) (+)·H(2)PO(4) (−). The dihydrogen phosphate anions form one-dimensional chains along [100], via O—H⋯O hydrogen bonds. The 2-amino-4-methyl­pyrimidinium cations are linked to these chains by means of two different kinds of N—H⋯O hydrogen bonds. Neighbouring chains are linked via C—H⋯N and C—H⋯O hydrogen bonds forming two-dimensional slab-like networks lying parallel to (01-1).
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spelling pubmed-36295832013-04-30 2-Amino-4-methyl­pyrimidinium dihydrogen phosphate Thomas, Sajesh P. Sunkari, Jyothi Acta Crystallogr Sect E Struct Rep Online Organic Papers A charge-assisted hydrogen-bonding network involving N—H⋯O and O—H⋯O hydrogen bonds stabilizes the crystal of the title salt, C(5)H(8)N(3) (+)·H(2)PO(4) (−). The dihydrogen phosphate anions form one-dimensional chains along [100], via O—H⋯O hydrogen bonds. The 2-amino-4-methyl­pyrimidinium cations are linked to these chains by means of two different kinds of N—H⋯O hydrogen bonds. Neighbouring chains are linked via C—H⋯N and C—H⋯O hydrogen bonds forming two-dimensional slab-like networks lying parallel to (01-1). International Union of Crystallography 2013-03-13 /pmc/articles/PMC3629583/ /pubmed/23634070 http://dx.doi.org/10.1107/S160053681300648X Text en © Thomas and Sunkari 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Thomas, Sajesh P.
Sunkari, Jyothi
2-Amino-4-methyl­pyrimidinium dihydrogen phosphate
title 2-Amino-4-methyl­pyrimidinium dihydrogen phosphate
title_full 2-Amino-4-methyl­pyrimidinium dihydrogen phosphate
title_fullStr 2-Amino-4-methyl­pyrimidinium dihydrogen phosphate
title_full_unstemmed 2-Amino-4-methyl­pyrimidinium dihydrogen phosphate
title_short 2-Amino-4-methyl­pyrimidinium dihydrogen phosphate
title_sort 2-amino-4-methyl­pyrimidinium dihydrogen phosphate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3629583/
https://www.ncbi.nlm.nih.gov/pubmed/23634070
http://dx.doi.org/10.1107/S160053681300648X
work_keys_str_mv AT thomassajeshp 2amino4methylpyrimidiniumdihydrogenphosphate
AT sunkarijyothi 2amino4methylpyrimidiniumdihydrogenphosphate

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