(Z)-4-[2-(2,4-Dimethyl­phen­yl)hydrazinyl­idene]-3-methyl­pyrazol-5(1H)-one

The mol­ecule of the title compound, C(12)H(14)N(4)O, is roughly planar, with a dihedral angle of 8.0 (8)° between the benzene and pyrazole rings, and an intra­molecular N—H⋯O hydrogen bond forms an S(6) ring motif. In the crystal, mol­ecules are linked into an inversion dimer by a pair of N—H⋯O hyd...

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Detalles Bibliográficos
Autores principales: Sarojini, B. K., Mohan, B. J., Narayana, B., Yathirajan, H. S., Jasinski, Jerry P., Butcher, Ray J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3629586/
https://www.ncbi.nlm.nih.gov/pubmed/23634073
http://dx.doi.org/10.1107/S1600536813006661
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author Sarojini, B. K.
Mohan, B. J.
Narayana, B.
Yathirajan, H. S.
Jasinski, Jerry P.
Butcher, Ray J.
author_facet Sarojini, B. K.
Mohan, B. J.
Narayana, B.
Yathirajan, H. S.
Jasinski, Jerry P.
Butcher, Ray J.
author_sort Sarojini, B. K.
collection PubMed
description The mol­ecule of the title compound, C(12)H(14)N(4)O, is roughly planar, with a dihedral angle of 8.0 (8)° between the benzene and pyrazole rings, and an intra­molecular N—H⋯O hydrogen bond forms an S(6) ring motif. In the crystal, mol­ecules are linked into an inversion dimer by a pair of N—H⋯O hydrogen bonds, which form an R (2) (2)(8) ring motif.
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spelling pubmed-36295862013-04-30 (Z)-4-[2-(2,4-Dimethyl­phen­yl)hydrazinyl­idene]-3-methyl­pyrazol-5(1H)-one Sarojini, B. K. Mohan, B. J. Narayana, B. Yathirajan, H. S. Jasinski, Jerry P. Butcher, Ray J. Acta Crystallogr Sect E Struct Rep Online Organic Papers The mol­ecule of the title compound, C(12)H(14)N(4)O, is roughly planar, with a dihedral angle of 8.0 (8)° between the benzene and pyrazole rings, and an intra­molecular N—H⋯O hydrogen bond forms an S(6) ring motif. In the crystal, mol­ecules are linked into an inversion dimer by a pair of N—H⋯O hydrogen bonds, which form an R (2) (2)(8) ring motif. International Union of Crystallography 2013-03-13 /pmc/articles/PMC3629586/ /pubmed/23634073 http://dx.doi.org/10.1107/S1600536813006661 Text en © Sarojini et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Sarojini, B. K.
Mohan, B. J.
Narayana, B.
Yathirajan, H. S.
Jasinski, Jerry P.
Butcher, Ray J.
(Z)-4-[2-(2,4-Dimethyl­phen­yl)hydrazinyl­idene]-3-methyl­pyrazol-5(1H)-one
title (Z)-4-[2-(2,4-Dimethyl­phen­yl)hydrazinyl­idene]-3-methyl­pyrazol-5(1H)-one
title_full (Z)-4-[2-(2,4-Dimethyl­phen­yl)hydrazinyl­idene]-3-methyl­pyrazol-5(1H)-one
title_fullStr (Z)-4-[2-(2,4-Dimethyl­phen­yl)hydrazinyl­idene]-3-methyl­pyrazol-5(1H)-one
title_full_unstemmed (Z)-4-[2-(2,4-Dimethyl­phen­yl)hydrazinyl­idene]-3-methyl­pyrazol-5(1H)-one
title_short (Z)-4-[2-(2,4-Dimethyl­phen­yl)hydrazinyl­idene]-3-methyl­pyrazol-5(1H)-one
title_sort (z)-4-[2-(2,4-dimethyl­phen­yl)hydrazinyl­idene]-3-methyl­pyrazol-5(1h)-one
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3629586/
https://www.ncbi.nlm.nih.gov/pubmed/23634073
http://dx.doi.org/10.1107/S1600536813006661
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