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2-Amino-5-bromopyridinium 5-chloro-2-hydroxybenzoate
In the 5-chlorosalicylate anion of the title salt, C(5)H(6)BrN(2) (+)·C(7)H(4)ClO(3) (−), an intramolecular O—H⋯O hydrogen bond with an S(6) graph-set motif is formed, so that the anion is essentially planar with a dihedral angle of 1.3 (5)° between the benzene ring and the carboxylate group. In...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3629591/ https://www.ncbi.nlm.nih.gov/pubmed/23634078 http://dx.doi.org/10.1107/S160053681300665X |
Sumario: | In the 5-chlorosalicylate anion of the title salt, C(5)H(6)BrN(2) (+)·C(7)H(4)ClO(3) (−), an intramolecular O—H⋯O hydrogen bond with an S(6) graph-set motif is formed, so that the anion is essentially planar with a dihedral angle of 1.3 (5)° between the benzene ring and the carboxylate group. In the crystal, the protonated N atom and the 2-amino group of the cation are hydrogen bonded to the carboxylate O atoms via a pair of N—H⋯O hydrogen bonds, forming an R (2) (2)(8) ring motif. The crystal structure also features N—H⋯O and weak C—H⋯O interactions, resulting in a layer parallel to the (10-1) plane. |
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