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2-Amino-5-bromo­pyridinium 5-chloro-2-hy­droxy­benzoate

In the 5-chloro­salicylate anion of the title salt, C(5)H(6)BrN(2) (+)·C(7)H(4)ClO(3) (−), an intra­molecular O—H⋯O hydrogen bond with an S(6) graph-set motif is formed, so that the anion is essentially planar with a dihedral angle of 1.3 (5)° between the benzene ring and the carboxyl­ate group. In...

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Autores principales: Thanigaimani, Kaliyaperumal, Khalib, Nuridayanti Che, Arshad, Suhana, Razak, Ibrahim Abdul
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3629591/
https://www.ncbi.nlm.nih.gov/pubmed/23634078
http://dx.doi.org/10.1107/S160053681300665X
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author Thanigaimani, Kaliyaperumal
Khalib, Nuridayanti Che
Arshad, Suhana
Razak, Ibrahim Abdul
author_facet Thanigaimani, Kaliyaperumal
Khalib, Nuridayanti Che
Arshad, Suhana
Razak, Ibrahim Abdul
author_sort Thanigaimani, Kaliyaperumal
collection PubMed
description In the 5-chloro­salicylate anion of the title salt, C(5)H(6)BrN(2) (+)·C(7)H(4)ClO(3) (−), an intra­molecular O—H⋯O hydrogen bond with an S(6) graph-set motif is formed, so that the anion is essentially planar with a dihedral angle of 1.3 (5)° between the benzene ring and the carboxyl­ate group. In the crystal, the protonated N atom and the 2-amino group of the cation are hydrogen bonded to the carboxyl­ate O atoms via a pair of N—H⋯O hydrogen bonds, forming an R (2) (2)(8) ring motif. The crystal structure also features N—H⋯O and weak C—H⋯O inter­actions, resulting in a layer parallel to the (10-1) plane.
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spelling pubmed-36295912013-04-30 2-Amino-5-bromo­pyridinium 5-chloro-2-hy­droxy­benzoate Thanigaimani, Kaliyaperumal Khalib, Nuridayanti Che Arshad, Suhana Razak, Ibrahim Abdul Acta Crystallogr Sect E Struct Rep Online Organic Papers In the 5-chloro­salicylate anion of the title salt, C(5)H(6)BrN(2) (+)·C(7)H(4)ClO(3) (−), an intra­molecular O—H⋯O hydrogen bond with an S(6) graph-set motif is formed, so that the anion is essentially planar with a dihedral angle of 1.3 (5)° between the benzene ring and the carboxyl­ate group. In the crystal, the protonated N atom and the 2-amino group of the cation are hydrogen bonded to the carboxyl­ate O atoms via a pair of N—H⋯O hydrogen bonds, forming an R (2) (2)(8) ring motif. The crystal structure also features N—H⋯O and weak C—H⋯O inter­actions, resulting in a layer parallel to the (10-1) plane. International Union of Crystallography 2013-03-16 /pmc/articles/PMC3629591/ /pubmed/23634078 http://dx.doi.org/10.1107/S160053681300665X Text en © Thanigaimani et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Thanigaimani, Kaliyaperumal
Khalib, Nuridayanti Che
Arshad, Suhana
Razak, Ibrahim Abdul
2-Amino-5-bromo­pyridinium 5-chloro-2-hy­droxy­benzoate
title 2-Amino-5-bromo­pyridinium 5-chloro-2-hy­droxy­benzoate
title_full 2-Amino-5-bromo­pyridinium 5-chloro-2-hy­droxy­benzoate
title_fullStr 2-Amino-5-bromo­pyridinium 5-chloro-2-hy­droxy­benzoate
title_full_unstemmed 2-Amino-5-bromo­pyridinium 5-chloro-2-hy­droxy­benzoate
title_short 2-Amino-5-bromo­pyridinium 5-chloro-2-hy­droxy­benzoate
title_sort 2-amino-5-bromo­pyridinium 5-chloro-2-hy­droxy­benzoate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3629591/
https://www.ncbi.nlm.nih.gov/pubmed/23634078
http://dx.doi.org/10.1107/S160053681300665X
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