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2-Amino-5-bromopyridinium 5-chloro-2-hydroxybenzoate
In the 5-chlorosalicylate anion of the title salt, C(5)H(6)BrN(2) (+)·C(7)H(4)ClO(3) (−), an intramolecular O—H⋯O hydrogen bond with an S(6) graph-set motif is formed, so that the anion is essentially planar with a dihedral angle of 1.3 (5)° between the benzene ring and the carboxylate group. In...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
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International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3629591/ https://www.ncbi.nlm.nih.gov/pubmed/23634078 http://dx.doi.org/10.1107/S160053681300665X |
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author | Thanigaimani, Kaliyaperumal Khalib, Nuridayanti Che Arshad, Suhana Razak, Ibrahim Abdul |
author_facet | Thanigaimani, Kaliyaperumal Khalib, Nuridayanti Che Arshad, Suhana Razak, Ibrahim Abdul |
author_sort | Thanigaimani, Kaliyaperumal |
collection | PubMed |
description | In the 5-chlorosalicylate anion of the title salt, C(5)H(6)BrN(2) (+)·C(7)H(4)ClO(3) (−), an intramolecular O—H⋯O hydrogen bond with an S(6) graph-set motif is formed, so that the anion is essentially planar with a dihedral angle of 1.3 (5)° between the benzene ring and the carboxylate group. In the crystal, the protonated N atom and the 2-amino group of the cation are hydrogen bonded to the carboxylate O atoms via a pair of N—H⋯O hydrogen bonds, forming an R (2) (2)(8) ring motif. The crystal structure also features N—H⋯O and weak C—H⋯O interactions, resulting in a layer parallel to the (10-1) plane. |
format | Online Article Text |
id | pubmed-3629591 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2013 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-36295912013-04-30 2-Amino-5-bromopyridinium 5-chloro-2-hydroxybenzoate Thanigaimani, Kaliyaperumal Khalib, Nuridayanti Che Arshad, Suhana Razak, Ibrahim Abdul Acta Crystallogr Sect E Struct Rep Online Organic Papers In the 5-chlorosalicylate anion of the title salt, C(5)H(6)BrN(2) (+)·C(7)H(4)ClO(3) (−), an intramolecular O—H⋯O hydrogen bond with an S(6) graph-set motif is formed, so that the anion is essentially planar with a dihedral angle of 1.3 (5)° between the benzene ring and the carboxylate group. In the crystal, the protonated N atom and the 2-amino group of the cation are hydrogen bonded to the carboxylate O atoms via a pair of N—H⋯O hydrogen bonds, forming an R (2) (2)(8) ring motif. The crystal structure also features N—H⋯O and weak C—H⋯O interactions, resulting in a layer parallel to the (10-1) plane. International Union of Crystallography 2013-03-16 /pmc/articles/PMC3629591/ /pubmed/23634078 http://dx.doi.org/10.1107/S160053681300665X Text en © Thanigaimani et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Thanigaimani, Kaliyaperumal Khalib, Nuridayanti Che Arshad, Suhana Razak, Ibrahim Abdul 2-Amino-5-bromopyridinium 5-chloro-2-hydroxybenzoate |
title | 2-Amino-5-bromopyridinium 5-chloro-2-hydroxybenzoate |
title_full | 2-Amino-5-bromopyridinium 5-chloro-2-hydroxybenzoate |
title_fullStr | 2-Amino-5-bromopyridinium 5-chloro-2-hydroxybenzoate |
title_full_unstemmed | 2-Amino-5-bromopyridinium 5-chloro-2-hydroxybenzoate |
title_short | 2-Amino-5-bromopyridinium 5-chloro-2-hydroxybenzoate |
title_sort | 2-amino-5-bromopyridinium 5-chloro-2-hydroxybenzoate |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3629591/ https://www.ncbi.nlm.nih.gov/pubmed/23634078 http://dx.doi.org/10.1107/S160053681300665X |
work_keys_str_mv | AT thanigaimanikaliyaperumal 2amino5bromopyridinium5chloro2hydroxybenzoate AT khalibnuridayantiche 2amino5bromopyridinium5chloro2hydroxybenzoate AT arshadsuhana 2amino5bromopyridinium5chloro2hydroxybenzoate AT razakibrahimabdul 2amino5bromopyridinium5chloro2hydroxybenzoate |