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5-Amino-6-methylquinolin-1-ium 3-carboxypropanoate
The asymmetric unit of the title salt, C(10)H(11)N(2) (+)·C(4)H(5)O(4) (−), consists of two independent 5-amino-6-methylquinolin-1-ium cations and two 3-carboxypropanoate anions. Both cations are protonated at the pyridine N atoms and are essentially planar, with maximum deviations of 0.026 (3)...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3629592/ https://www.ncbi.nlm.nih.gov/pubmed/23634079 http://dx.doi.org/10.1107/S1600536813006673 |
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author | Thanigaimani, Kaliyaperumal Khalib, Nuridayanti Che Arshad, Suhana Razak, Ibrahim Abdul |
author_facet | Thanigaimani, Kaliyaperumal Khalib, Nuridayanti Che Arshad, Suhana Razak, Ibrahim Abdul |
author_sort | Thanigaimani, Kaliyaperumal |
collection | PubMed |
description | The asymmetric unit of the title salt, C(10)H(11)N(2) (+)·C(4)H(5)O(4) (−), consists of two independent 5-amino-6-methylquinolin-1-ium cations and two 3-carboxypropanoate anions. Both cations are protonated at the pyridine N atoms and are essentially planar, with maximum deviations of 0.026 (3) and 0.016 (2) Å. In the crystal, the cations and anions are linked via N—H⋯O and O—H⋯O hydrogen bonds, forming a layer parallel to the ab plane. In the layer, weak C—H⋯O hydrogen bonds and π–π stacking interactions, with centroid-to-centroid distances of 3.7283 (15) and 3.8467 (15) Å, are observed. The crystal structure also features weak C—H⋯O hydrogen bonds between the layers. |
format | Online Article Text |
id | pubmed-3629592 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2013 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-36295922013-04-30 5-Amino-6-methylquinolin-1-ium 3-carboxypropanoate Thanigaimani, Kaliyaperumal Khalib, Nuridayanti Che Arshad, Suhana Razak, Ibrahim Abdul Acta Crystallogr Sect E Struct Rep Online Organic Papers The asymmetric unit of the title salt, C(10)H(11)N(2) (+)·C(4)H(5)O(4) (−), consists of two independent 5-amino-6-methylquinolin-1-ium cations and two 3-carboxypropanoate anions. Both cations are protonated at the pyridine N atoms and are essentially planar, with maximum deviations of 0.026 (3) and 0.016 (2) Å. In the crystal, the cations and anions are linked via N—H⋯O and O—H⋯O hydrogen bonds, forming a layer parallel to the ab plane. In the layer, weak C—H⋯O hydrogen bonds and π–π stacking interactions, with centroid-to-centroid distances of 3.7283 (15) and 3.8467 (15) Å, are observed. The crystal structure also features weak C—H⋯O hydrogen bonds between the layers. International Union of Crystallography 2013-03-16 /pmc/articles/PMC3629592/ /pubmed/23634079 http://dx.doi.org/10.1107/S1600536813006673 Text en © Thanigaimani et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Thanigaimani, Kaliyaperumal Khalib, Nuridayanti Che Arshad, Suhana Razak, Ibrahim Abdul 5-Amino-6-methylquinolin-1-ium 3-carboxypropanoate |
title | 5-Amino-6-methylquinolin-1-ium 3-carboxypropanoate |
title_full | 5-Amino-6-methylquinolin-1-ium 3-carboxypropanoate |
title_fullStr | 5-Amino-6-methylquinolin-1-ium 3-carboxypropanoate |
title_full_unstemmed | 5-Amino-6-methylquinolin-1-ium 3-carboxypropanoate |
title_short | 5-Amino-6-methylquinolin-1-ium 3-carboxypropanoate |
title_sort | 5-amino-6-methylquinolin-1-ium 3-carboxypropanoate |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3629592/ https://www.ncbi.nlm.nih.gov/pubmed/23634079 http://dx.doi.org/10.1107/S1600536813006673 |
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