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5-Amino-6-methyl­quinolin-1-ium 3-carb­oxy­propano­ate

The asymmetric unit of the title salt, C(10)H(11)N(2) (+)·C(4)H(5)O(4) (−), consists of two independent 5-amino-6-methyl­quinolin-1-ium cations and two 3-carb­oxy­propano­ate anions. Both cations are protonated at the pyridine N atoms and are essentially planar, with maximum deviations of 0.026 (3)...

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Autores principales: Thanigaimani, Kaliyaperumal, Khalib, Nuridayanti Che, Arshad, Suhana, Razak, Ibrahim Abdul
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3629592/
https://www.ncbi.nlm.nih.gov/pubmed/23634079
http://dx.doi.org/10.1107/S1600536813006673
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author Thanigaimani, Kaliyaperumal
Khalib, Nuridayanti Che
Arshad, Suhana
Razak, Ibrahim Abdul
author_facet Thanigaimani, Kaliyaperumal
Khalib, Nuridayanti Che
Arshad, Suhana
Razak, Ibrahim Abdul
author_sort Thanigaimani, Kaliyaperumal
collection PubMed
description The asymmetric unit of the title salt, C(10)H(11)N(2) (+)·C(4)H(5)O(4) (−), consists of two independent 5-amino-6-methyl­quinolin-1-ium cations and two 3-carb­oxy­propano­ate anions. Both cations are protonated at the pyridine N atoms and are essentially planar, with maximum deviations of 0.026 (3) and 0.016 (2) Å. In the crystal, the cations and anions are linked via N—H⋯O and O—H⋯O hydrogen bonds, forming a layer parallel to the ab plane. In the layer, weak C—H⋯O hydrogen bonds and π–π stacking inter­actions, with centroid-to-centroid distances of 3.7283 (15) and 3.8467 (15) Å, are observed. The crystal structure also features weak C—H⋯O hydrogen bonds between the layers.
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spelling pubmed-36295922013-04-30 5-Amino-6-methyl­quinolin-1-ium 3-carb­oxy­propano­ate Thanigaimani, Kaliyaperumal Khalib, Nuridayanti Che Arshad, Suhana Razak, Ibrahim Abdul Acta Crystallogr Sect E Struct Rep Online Organic Papers The asymmetric unit of the title salt, C(10)H(11)N(2) (+)·C(4)H(5)O(4) (−), consists of two independent 5-amino-6-methyl­quinolin-1-ium cations and two 3-carb­oxy­propano­ate anions. Both cations are protonated at the pyridine N atoms and are essentially planar, with maximum deviations of 0.026 (3) and 0.016 (2) Å. In the crystal, the cations and anions are linked via N—H⋯O and O—H⋯O hydrogen bonds, forming a layer parallel to the ab plane. In the layer, weak C—H⋯O hydrogen bonds and π–π stacking inter­actions, with centroid-to-centroid distances of 3.7283 (15) and 3.8467 (15) Å, are observed. The crystal structure also features weak C—H⋯O hydrogen bonds between the layers. International Union of Crystallography 2013-03-16 /pmc/articles/PMC3629592/ /pubmed/23634079 http://dx.doi.org/10.1107/S1600536813006673 Text en © Thanigaimani et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Thanigaimani, Kaliyaperumal
Khalib, Nuridayanti Che
Arshad, Suhana
Razak, Ibrahim Abdul
5-Amino-6-methyl­quinolin-1-ium 3-carb­oxy­propano­ate
title 5-Amino-6-methyl­quinolin-1-ium 3-carb­oxy­propano­ate
title_full 5-Amino-6-methyl­quinolin-1-ium 3-carb­oxy­propano­ate
title_fullStr 5-Amino-6-methyl­quinolin-1-ium 3-carb­oxy­propano­ate
title_full_unstemmed 5-Amino-6-methyl­quinolin-1-ium 3-carb­oxy­propano­ate
title_short 5-Amino-6-methyl­quinolin-1-ium 3-carb­oxy­propano­ate
title_sort 5-amino-6-methyl­quinolin-1-ium 3-carb­oxy­propano­ate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3629592/
https://www.ncbi.nlm.nih.gov/pubmed/23634079
http://dx.doi.org/10.1107/S1600536813006673
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