4-(6-Benzyl-7-oxo-1,2,3,4,5,5a,5a(1),6,7,7a,8,12b-dodeca­hydro­benzo[f]cyclo­octa­[cd]isoindol-8-yl)benzonitrile

In the title compound, C(31)H(30)N(2)O, the cis-fused cyclo­hexene and cyclo­octane rings adopt boat and boat-chair conformations, respectively. The essentially planar five-membered N-heterocyclic ring [r.m.s. deviation = 0.017 (1) Å] is cis- and trans-fused, respectively, with the cyclo­hexene and...

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Detalles Bibliográficos
Autores principales: Zhang, Yu-Long, Hu, Yi-Min
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3629602/
https://www.ncbi.nlm.nih.gov/pubmed/23634089
http://dx.doi.org/10.1107/S1600536813006880
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author Zhang, Yu-Long
Hu, Yi-Min
author_facet Zhang, Yu-Long
Hu, Yi-Min
author_sort Zhang, Yu-Long
collection PubMed
description In the title compound, C(31)H(30)N(2)O, the cis-fused cyclo­hexene and cyclo­octane rings adopt boat and boat-chair conformations, respectively. The essentially planar five-membered N-heterocyclic ring [r.m.s. deviation = 0.017 (1) Å] is cis- and trans-fused, respectively, with the cyclo­hexene and cyclo­octane rings. In the crystal, mol­ecules are linked into inversion dimers through pairs of weak C—H⋯O inter­actions.
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spelling pubmed-36296022013-04-30 4-(6-Benzyl-7-oxo-1,2,3,4,5,5a,5a(1),6,7,7a,8,12b-dodeca­hydro­benzo[f]cyclo­octa­[cd]isoindol-8-yl)benzonitrile Zhang, Yu-Long Hu, Yi-Min Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(31)H(30)N(2)O, the cis-fused cyclo­hexene and cyclo­octane rings adopt boat and boat-chair conformations, respectively. The essentially planar five-membered N-heterocyclic ring [r.m.s. deviation = 0.017 (1) Å] is cis- and trans-fused, respectively, with the cyclo­hexene and cyclo­octane rings. In the crystal, mol­ecules are linked into inversion dimers through pairs of weak C—H⋯O inter­actions. International Union of Crystallography 2013-03-16 /pmc/articles/PMC3629602/ /pubmed/23634089 http://dx.doi.org/10.1107/S1600536813006880 Text en © Zhang and Hu 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Zhang, Yu-Long
Hu, Yi-Min
4-(6-Benzyl-7-oxo-1,2,3,4,5,5a,5a(1),6,7,7a,8,12b-dodeca­hydro­benzo[f]cyclo­octa­[cd]isoindol-8-yl)benzonitrile
title 4-(6-Benzyl-7-oxo-1,2,3,4,5,5a,5a(1),6,7,7a,8,12b-dodeca­hydro­benzo[f]cyclo­octa­[cd]isoindol-8-yl)benzonitrile
title_full 4-(6-Benzyl-7-oxo-1,2,3,4,5,5a,5a(1),6,7,7a,8,12b-dodeca­hydro­benzo[f]cyclo­octa­[cd]isoindol-8-yl)benzonitrile
title_fullStr 4-(6-Benzyl-7-oxo-1,2,3,4,5,5a,5a(1),6,7,7a,8,12b-dodeca­hydro­benzo[f]cyclo­octa­[cd]isoindol-8-yl)benzonitrile
title_full_unstemmed 4-(6-Benzyl-7-oxo-1,2,3,4,5,5a,5a(1),6,7,7a,8,12b-dodeca­hydro­benzo[f]cyclo­octa­[cd]isoindol-8-yl)benzonitrile
title_short 4-(6-Benzyl-7-oxo-1,2,3,4,5,5a,5a(1),6,7,7a,8,12b-dodeca­hydro­benzo[f]cyclo­octa­[cd]isoindol-8-yl)benzonitrile
title_sort 4-(6-benzyl-7-oxo-1,2,3,4,5,5a,5a(1),6,7,7a,8,12b-dodeca­hydro­benzo[f]cyclo­octa­[cd]isoindol-8-yl)benzonitrile
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3629602/
https://www.ncbi.nlm.nih.gov/pubmed/23634089
http://dx.doi.org/10.1107/S1600536813006880
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AT huyimin 46benzyl7oxo123455a5a1677a812bdodecahydrobenzofcyclooctacdisoindol8ylbenzonitrile

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