2-Benzyl­sulfanyl-N-(1,3-dimethyl­imidazolidin-2-yl­idene)aniline

The mol­ecular structure of the title compound, C(18)H(21)N(3)S, shows a twisted conformation with a dihedral angle of 67.45 (4)° between the aromatic ring planes and an N—C—C—S torsion angle of −5.01 (13)°. The imidazolidine ring and the aniline moiety make a dihedral angle of 56.03 (4)° and the as...

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Detalles Bibliográficos
Autores principales: Flörke, Ulrich, Neuba, Adam, Henkel, Gerald
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3629606/
https://www.ncbi.nlm.nih.gov/pubmed/23634093
http://dx.doi.org/10.1107/S1600536813007101
Descripción
Sumario:The mol­ecular structure of the title compound, C(18)H(21)N(3)S, shows a twisted conformation with a dihedral angle of 67.45 (4)° between the aromatic ring planes and an N—C—C—S torsion angle of −5.01 (13)°. The imidazolidine ring and the aniline moiety make a dihedral angle of 56.03 (4)° and the asscociated C—N—C angle is 125.71 (10)°. The guanidine-like C=N double bond is clearly localized, with a bond length of 1.2879 (14) Å. The C—S—C angle is 102.12 (5)° and the S—C(aromatic) and S—C bond lengths are 1.7643 (11) and 1.8159 (12) Å.

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