2-Benzyl­sulfanyl-N-(1,3-dimethyl­imidazolidin-2-yl­idene)aniline

The mol­ecular structure of the title compound, C(18)H(21)N(3)S, shows a twisted conformation with a dihedral angle of 67.45 (4)° between the aromatic ring planes and an N—C—C—S torsion angle of −5.01 (13)°. The imidazolidine ring and the aniline moiety make a dihedral angle of 56.03 (4)° and the as...

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Detalles Bibliográficos
Autores principales: Flörke, Ulrich, Neuba, Adam, Henkel, Gerald
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3629606/
https://www.ncbi.nlm.nih.gov/pubmed/23634093
http://dx.doi.org/10.1107/S1600536813007101
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author Flörke, Ulrich
Neuba, Adam
Henkel, Gerald
author_facet Flörke, Ulrich
Neuba, Adam
Henkel, Gerald
author_sort Flörke, Ulrich
collection PubMed
description The mol­ecular structure of the title compound, C(18)H(21)N(3)S, shows a twisted conformation with a dihedral angle of 67.45 (4)° between the aromatic ring planes and an N—C—C—S torsion angle of −5.01 (13)°. The imidazolidine ring and the aniline moiety make a dihedral angle of 56.03 (4)° and the asscociated C—N—C angle is 125.71 (10)°. The guanidine-like C=N double bond is clearly localized, with a bond length of 1.2879 (14) Å. The C—S—C angle is 102.12 (5)° and the S—C(aromatic) and S—C bond lengths are 1.7643 (11) and 1.8159 (12) Å.
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spelling pubmed-36296062013-04-30 2-Benzyl­sulfanyl-N-(1,3-dimethyl­imidazolidin-2-yl­idene)aniline Flörke, Ulrich Neuba, Adam Henkel, Gerald Acta Crystallogr Sect E Struct Rep Online Organic Papers The mol­ecular structure of the title compound, C(18)H(21)N(3)S, shows a twisted conformation with a dihedral angle of 67.45 (4)° between the aromatic ring planes and an N—C—C—S torsion angle of −5.01 (13)°. The imidazolidine ring and the aniline moiety make a dihedral angle of 56.03 (4)° and the asscociated C—N—C angle is 125.71 (10)°. The guanidine-like C=N double bond is clearly localized, with a bond length of 1.2879 (14) Å. The C—S—C angle is 102.12 (5)° and the S—C(aromatic) and S—C bond lengths are 1.7643 (11) and 1.8159 (12) Å. International Union of Crystallography 2013-03-20 /pmc/articles/PMC3629606/ /pubmed/23634093 http://dx.doi.org/10.1107/S1600536813007101 Text en © Flörke et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Flörke, Ulrich
Neuba, Adam
Henkel, Gerald
2-Benzyl­sulfanyl-N-(1,3-dimethyl­imidazolidin-2-yl­idene)aniline
title 2-Benzyl­sulfanyl-N-(1,3-dimethyl­imidazolidin-2-yl­idene)aniline
title_full 2-Benzyl­sulfanyl-N-(1,3-dimethyl­imidazolidin-2-yl­idene)aniline
title_fullStr 2-Benzyl­sulfanyl-N-(1,3-dimethyl­imidazolidin-2-yl­idene)aniline
title_full_unstemmed 2-Benzyl­sulfanyl-N-(1,3-dimethyl­imidazolidin-2-yl­idene)aniline
title_short 2-Benzyl­sulfanyl-N-(1,3-dimethyl­imidazolidin-2-yl­idene)aniline
title_sort 2-benzyl­sulfanyl-n-(1,3-dimethyl­imidazolidin-2-yl­idene)aniline
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3629606/
https://www.ncbi.nlm.nih.gov/pubmed/23634093
http://dx.doi.org/10.1107/S1600536813007101
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AT henkelgerald 2benzylsulfanyln13dimethylimidazolidin2ylideneaniline

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