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3,3-Bis(4-bromophenylsulfanyl)-1-methylpiperidin-2-one
In the title compound, C(18)H(17)Br(2)NOS(2), the conformation of the piperidin-2-one ring is based on a half-chair with the methylene C atom diagonally opposite the N atom being 0.649 (3) Å above the plane of the remaining five atoms (r.m.s. deviation = 0.1205 Å). The S atoms occupy axial and bis...
Autores principales: | , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3629608/ https://www.ncbi.nlm.nih.gov/pubmed/23634095 http://dx.doi.org/10.1107/S1600536813006995 |
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author | Zukerman-Schpector, Julio Olivato, Paulo R. Cerqueira Jr, Carlos R. Contieri, Bruna Ng, Seik Weng Tiekink, Edward R. T. |
author_facet | Zukerman-Schpector, Julio Olivato, Paulo R. Cerqueira Jr, Carlos R. Contieri, Bruna Ng, Seik Weng Tiekink, Edward R. T. |
author_sort | Zukerman-Schpector, Julio |
collection | PubMed |
description | In the title compound, C(18)H(17)Br(2)NOS(2), the conformation of the piperidin-2-one ring is based on a half-chair with the methylene C atom diagonally opposite the N atom being 0.649 (3) Å above the plane of the remaining five atoms (r.m.s. deviation = 0.1205 Å). The S atoms occupy axial and bisectional positions, and the dihedral angle between the benzene rings of 59.95 (11)° indicates a splayed disposition. Helical supramolecular chains along the b axis sustained by C—H⋯O interactions is the major feature of the crystal packing. The chains are connected into a three-dimensional architecture by C—H⋯Br and C—H⋯π interactions. |
format | Online Article Text |
id | pubmed-3629608 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2013 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-36296082013-04-30 3,3-Bis(4-bromophenylsulfanyl)-1-methylpiperidin-2-one Zukerman-Schpector, Julio Olivato, Paulo R. Cerqueira Jr, Carlos R. Contieri, Bruna Ng, Seik Weng Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(18)H(17)Br(2)NOS(2), the conformation of the piperidin-2-one ring is based on a half-chair with the methylene C atom diagonally opposite the N atom being 0.649 (3) Å above the plane of the remaining five atoms (r.m.s. deviation = 0.1205 Å). The S atoms occupy axial and bisectional positions, and the dihedral angle between the benzene rings of 59.95 (11)° indicates a splayed disposition. Helical supramolecular chains along the b axis sustained by C—H⋯O interactions is the major feature of the crystal packing. The chains are connected into a three-dimensional architecture by C—H⋯Br and C—H⋯π interactions. International Union of Crystallography 2013-03-20 /pmc/articles/PMC3629608/ /pubmed/23634095 http://dx.doi.org/10.1107/S1600536813006995 Text en © Zukerman-Schpector et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Zukerman-Schpector, Julio Olivato, Paulo R. Cerqueira Jr, Carlos R. Contieri, Bruna Ng, Seik Weng Tiekink, Edward R. T. 3,3-Bis(4-bromophenylsulfanyl)-1-methylpiperidin-2-one |
title | 3,3-Bis(4-bromophenylsulfanyl)-1-methylpiperidin-2-one |
title_full | 3,3-Bis(4-bromophenylsulfanyl)-1-methylpiperidin-2-one |
title_fullStr | 3,3-Bis(4-bromophenylsulfanyl)-1-methylpiperidin-2-one |
title_full_unstemmed | 3,3-Bis(4-bromophenylsulfanyl)-1-methylpiperidin-2-one |
title_short | 3,3-Bis(4-bromophenylsulfanyl)-1-methylpiperidin-2-one |
title_sort | 3,3-bis(4-bromophenylsulfanyl)-1-methylpiperidin-2-one |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3629608/ https://www.ncbi.nlm.nih.gov/pubmed/23634095 http://dx.doi.org/10.1107/S1600536813006995 |
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