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3,3-Bis(4-bromo­phenyl­sulfan­yl)-1-methyl­piperidin-2-one

In the title compound, C(18)H(17)Br(2)NOS(2), the conformation of the piperidin-2-one ring is based on a half-chair with the methyl­ene C atom diagonally opposite the N atom being 0.649 (3) Å above the plane of the remaining five atoms (r.m.s. deviation = 0.1205 Å). The S atoms occupy axial and bis­...

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Detalles Bibliográficos
Autores principales: Zukerman-Schpector, Julio, Olivato, Paulo R., Cerqueira Jr, Carlos R., Contieri, Bruna, Ng, Seik Weng, Tiekink, Edward R. T.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3629608/
https://www.ncbi.nlm.nih.gov/pubmed/23634095
http://dx.doi.org/10.1107/S1600536813006995
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author Zukerman-Schpector, Julio
Olivato, Paulo R.
Cerqueira Jr, Carlos R.
Contieri, Bruna
Ng, Seik Weng
Tiekink, Edward R. T.
author_facet Zukerman-Schpector, Julio
Olivato, Paulo R.
Cerqueira Jr, Carlos R.
Contieri, Bruna
Ng, Seik Weng
Tiekink, Edward R. T.
author_sort Zukerman-Schpector, Julio
collection PubMed
description In the title compound, C(18)H(17)Br(2)NOS(2), the conformation of the piperidin-2-one ring is based on a half-chair with the methyl­ene C atom diagonally opposite the N atom being 0.649 (3) Å above the plane of the remaining five atoms (r.m.s. deviation = 0.1205 Å). The S atoms occupy axial and bis­ectional positions, and the dihedral angle between the benzene rings of 59.95 (11)° indicates a splayed disposition. Helical supra­molecular chains along the b axis sustained by C—H⋯O inter­actions is the major feature of the crystal packing. The chains are connected into a three-dimensional architecture by C—H⋯Br and C—H⋯π inter­actions.
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spelling pubmed-36296082013-04-30 3,3-Bis(4-bromo­phenyl­sulfan­yl)-1-methyl­piperidin-2-one Zukerman-Schpector, Julio Olivato, Paulo R. Cerqueira Jr, Carlos R. Contieri, Bruna Ng, Seik Weng Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(18)H(17)Br(2)NOS(2), the conformation of the piperidin-2-one ring is based on a half-chair with the methyl­ene C atom diagonally opposite the N atom being 0.649 (3) Å above the plane of the remaining five atoms (r.m.s. deviation = 0.1205 Å). The S atoms occupy axial and bis­ectional positions, and the dihedral angle between the benzene rings of 59.95 (11)° indicates a splayed disposition. Helical supra­molecular chains along the b axis sustained by C—H⋯O inter­actions is the major feature of the crystal packing. The chains are connected into a three-dimensional architecture by C—H⋯Br and C—H⋯π inter­actions. International Union of Crystallography 2013-03-20 /pmc/articles/PMC3629608/ /pubmed/23634095 http://dx.doi.org/10.1107/S1600536813006995 Text en © Zukerman-Schpector et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Zukerman-Schpector, Julio
Olivato, Paulo R.
Cerqueira Jr, Carlos R.
Contieri, Bruna
Ng, Seik Weng
Tiekink, Edward R. T.
3,3-Bis(4-bromo­phenyl­sulfan­yl)-1-methyl­piperidin-2-one
title 3,3-Bis(4-bromo­phenyl­sulfan­yl)-1-methyl­piperidin-2-one
title_full 3,3-Bis(4-bromo­phenyl­sulfan­yl)-1-methyl­piperidin-2-one
title_fullStr 3,3-Bis(4-bromo­phenyl­sulfan­yl)-1-methyl­piperidin-2-one
title_full_unstemmed 3,3-Bis(4-bromo­phenyl­sulfan­yl)-1-methyl­piperidin-2-one
title_short 3,3-Bis(4-bromo­phenyl­sulfan­yl)-1-methyl­piperidin-2-one
title_sort 3,3-bis(4-bromo­phenyl­sulfan­yl)-1-methyl­piperidin-2-one
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3629608/
https://www.ncbi.nlm.nih.gov/pubmed/23634095
http://dx.doi.org/10.1107/S1600536813006995
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