Cargando…

Bis(1-benzoyl-7-meth­oxy­naphthalen-2-yl) terephthalate

The title molecule, C(44)H(30)O(8), lies about a crystallographic inversion centre located at the centre of the central benzene ring. The benzene rings in the benzoyl and the terephthalate units make dihedral angles of 67.05 (7)° and 57.57 (7)°, respectively, with the naphthalene ring system. There...

Descripción completa

Detalles Bibliográficos
Autores principales: Sakamoto, Rei, Hijikata, Daichi, Isozaki, Katsuhiro, Yonezawa, Noriyuki, Okamoto, Akiko
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3629609/
https://www.ncbi.nlm.nih.gov/pubmed/23634096
http://dx.doi.org/10.1107/S1600536813007186
Descripción
Sumario:The title molecule, C(44)H(30)O(8), lies about a crystallographic inversion centre located at the centre of the central benzene ring. The benzene rings in the benzoyl and the terephthalate units make dihedral angles of 67.05 (7)° and 57.57 (7)°, respectively, with the naphthalene ring system. There is an intra­molecular C—H⋯O inter­action between the ketonic carbonyl O atom and an H atom on the naphthalene ring system. In the crystal, C—H⋯O inter­action of the benzene ring in the benzoyl group and weak C=O⋯π inter­action [O⋯centroid = 3.375 (2) Å] of the naphthalene ring with the O atom in the ketonic carbonyl group are observed. These inter­actions form layers parallel to the bc plane.