Bis(1-benzoyl-7-meth­oxy­naphthalen-2-yl) terephthalate

The title molecule, C(44)H(30)O(8), lies about a crystallographic inversion centre located at the centre of the central benzene ring. The benzene rings in the benzoyl and the terephthalate units make dihedral angles of 67.05 (7)° and 57.57 (7)°, respectively, with the naphthalene ring system. There...

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Autores principales: Sakamoto, Rei, Hijikata, Daichi, Isozaki, Katsuhiro, Yonezawa, Noriyuki, Okamoto, Akiko
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3629609/
https://www.ncbi.nlm.nih.gov/pubmed/23634096
http://dx.doi.org/10.1107/S1600536813007186
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author Sakamoto, Rei
Hijikata, Daichi
Isozaki, Katsuhiro
Yonezawa, Noriyuki
Okamoto, Akiko
author_facet Sakamoto, Rei
Hijikata, Daichi
Isozaki, Katsuhiro
Yonezawa, Noriyuki
Okamoto, Akiko
author_sort Sakamoto, Rei
collection PubMed
description The title molecule, C(44)H(30)O(8), lies about a crystallographic inversion centre located at the centre of the central benzene ring. The benzene rings in the benzoyl and the terephthalate units make dihedral angles of 67.05 (7)° and 57.57 (7)°, respectively, with the naphthalene ring system. There is an intra­molecular C—H⋯O inter­action between the ketonic carbonyl O atom and an H atom on the naphthalene ring system. In the crystal, C—H⋯O inter­action of the benzene ring in the benzoyl group and weak C=O⋯π inter­action [O⋯centroid = 3.375 (2) Å] of the naphthalene ring with the O atom in the ketonic carbonyl group are observed. These inter­actions form layers parallel to the bc plane.
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spelling pubmed-36296092013-04-30 Bis(1-benzoyl-7-meth­oxy­naphthalen-2-yl) terephthalate Sakamoto, Rei Hijikata, Daichi Isozaki, Katsuhiro Yonezawa, Noriyuki Okamoto, Akiko Acta Crystallogr Sect E Struct Rep Online Organic Papers The title molecule, C(44)H(30)O(8), lies about a crystallographic inversion centre located at the centre of the central benzene ring. The benzene rings in the benzoyl and the terephthalate units make dihedral angles of 67.05 (7)° and 57.57 (7)°, respectively, with the naphthalene ring system. There is an intra­molecular C—H⋯O inter­action between the ketonic carbonyl O atom and an H atom on the naphthalene ring system. In the crystal, C—H⋯O inter­action of the benzene ring in the benzoyl group and weak C=O⋯π inter­action [O⋯centroid = 3.375 (2) Å] of the naphthalene ring with the O atom in the ketonic carbonyl group are observed. These inter­actions form layers parallel to the bc plane. International Union of Crystallography 2013-03-20 /pmc/articles/PMC3629609/ /pubmed/23634096 http://dx.doi.org/10.1107/S1600536813007186 Text en © Sakamoto et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Sakamoto, Rei
Hijikata, Daichi
Isozaki, Katsuhiro
Yonezawa, Noriyuki
Okamoto, Akiko
Bis(1-benzoyl-7-meth­oxy­naphthalen-2-yl) terephthalate
title Bis(1-benzoyl-7-meth­oxy­naphthalen-2-yl) terephthalate
title_full Bis(1-benzoyl-7-meth­oxy­naphthalen-2-yl) terephthalate
title_fullStr Bis(1-benzoyl-7-meth­oxy­naphthalen-2-yl) terephthalate
title_full_unstemmed Bis(1-benzoyl-7-meth­oxy­naphthalen-2-yl) terephthalate
title_short Bis(1-benzoyl-7-meth­oxy­naphthalen-2-yl) terephthalate
title_sort bis(1-benzoyl-7-meth­oxy­naphthalen-2-yl) terephthalate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3629609/
https://www.ncbi.nlm.nih.gov/pubmed/23634096
http://dx.doi.org/10.1107/S1600536813007186
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