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N-Butoxycarbonyl-5-oxo-l-proline ethyl ester
The molecular structure of the title compound, C(12)H(19)NO(5), may be visualized as made up of two nearly perpendicular planes [dihedral angle = 87.39 (12)°] and its crystal structure is a good example of C—H⋯O interactions assuming significance in optimizing supramolecular aggregation in crysta...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3629616/ https://www.ncbi.nlm.nih.gov/pubmed/23634103 http://dx.doi.org/10.1107/S1600536813007265 |
Sumario: | The molecular structure of the title compound, C(12)H(19)NO(5), may be visualized as made up of two nearly perpendicular planes [dihedral angle = 87.39 (12)°] and its crystal structure is a good example of C—H⋯O interactions assuming significance in optimizing supramolecular aggregation in crystals in a molecule which is severely imbalanced in terms of donors to acceptor atoms. The pyrrolidine ring adopts a ((3) T (2)) twist conformation with puckering parameters Q = 0.2630 (4) Å and ϕ = 59 (9)°. The crystal structure features R (2) (4)(10) and R (3) (4)(26) ring motifs formed by four weak C—H⋯O interactions, leading to supramolecular sheets lying parallel to the bc plane. |
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