Methyl (2Z)-2-bromo­methyl-3-(2,4-dichloro­phen­yl)prop-2-enoate

In the title compound C(11)H(9)BrCl(2)O(2), which represents the Z isomer, the methyl­acrylate moiety is essentially planar within 0.039 (2) Å and has an extended trans configuration. The benzene ring makes a dihedral angle of 28.3 (1)° with the mean plane of the methyl­acrylate moiety. The crystal...

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Detalles Bibliográficos
Autores principales: Swaminathan, K., Sethusankar, K., Devaraj, Anthonisamy, Bakthadoss, Manickam
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3629620/
https://www.ncbi.nlm.nih.gov/pubmed/23634107
http://dx.doi.org/10.1107/S1600536813007368
Descripción
Sumario:In the title compound C(11)H(9)BrCl(2)O(2), which represents the Z isomer, the methyl­acrylate moiety is essentially planar within 0.039 (2) Å and has an extended trans configuration. The benzene ring makes a dihedral angle of 28.3 (1)° with the mean plane of the methyl­acrylate moiety. The crystal packing is characterized by C—H⋯O hydrogen bonding and halogen–halogen inter­actions [Cl⋯Cl = 3.486 (3) Å], resulting in the formation of R (2) (2)(11) ring motifs and connecting the mol­ecules into chains propagating along the b axis.

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