Methyl (2Z)-2-bromo­methyl-3-(2,4-dichloro­phen­yl)prop-2-enoate

In the title compound C(11)H(9)BrCl(2)O(2), which represents the Z isomer, the methyl­acrylate moiety is essentially planar within 0.039 (2) Å and has an extended trans configuration. The benzene ring makes a dihedral angle of 28.3 (1)° with the mean plane of the methyl­acrylate moiety. The crystal...

Descripción completa

Detalles Bibliográficos
Autores principales: Swaminathan, K., Sethusankar, K., Devaraj, Anthonisamy, Bakthadoss, Manickam
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3629620/
https://www.ncbi.nlm.nih.gov/pubmed/23634107
http://dx.doi.org/10.1107/S1600536813007368
_version_ 1782266616062410752
author Swaminathan, K.
Sethusankar, K.
Devaraj, Anthonisamy
Bakthadoss, Manickam
author_facet Swaminathan, K.
Sethusankar, K.
Devaraj, Anthonisamy
Bakthadoss, Manickam
author_sort Swaminathan, K.
collection PubMed
description In the title compound C(11)H(9)BrCl(2)O(2), which represents the Z isomer, the methyl­acrylate moiety is essentially planar within 0.039 (2) Å and has an extended trans configuration. The benzene ring makes a dihedral angle of 28.3 (1)° with the mean plane of the methyl­acrylate moiety. The crystal packing is characterized by C—H⋯O hydrogen bonding and halogen–halogen inter­actions [Cl⋯Cl = 3.486 (3) Å], resulting in the formation of R (2) (2)(11) ring motifs and connecting the mol­ecules into chains propagating along the b axis.
format Online
Article
Text
id pubmed-3629620
institution National Center for Biotechnology Information
language English
publishDate 2013
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-36296202013-04-30 Methyl (2Z)-2-bromo­methyl-3-(2,4-dichloro­phen­yl)prop-2-enoate Swaminathan, K. Sethusankar, K. Devaraj, Anthonisamy Bakthadoss, Manickam Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound C(11)H(9)BrCl(2)O(2), which represents the Z isomer, the methyl­acrylate moiety is essentially planar within 0.039 (2) Å and has an extended trans configuration. The benzene ring makes a dihedral angle of 28.3 (1)° with the mean plane of the methyl­acrylate moiety. The crystal packing is characterized by C—H⋯O hydrogen bonding and halogen–halogen inter­actions [Cl⋯Cl = 3.486 (3) Å], resulting in the formation of R (2) (2)(11) ring motifs and connecting the mol­ecules into chains propagating along the b axis. International Union of Crystallography 2013-03-23 /pmc/articles/PMC3629620/ /pubmed/23634107 http://dx.doi.org/10.1107/S1600536813007368 Text en © Swaminathan et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Swaminathan, K.
Sethusankar, K.
Devaraj, Anthonisamy
Bakthadoss, Manickam
Methyl (2Z)-2-bromo­methyl-3-(2,4-dichloro­phen­yl)prop-2-enoate
title Methyl (2Z)-2-bromo­methyl-3-(2,4-dichloro­phen­yl)prop-2-enoate
title_full Methyl (2Z)-2-bromo­methyl-3-(2,4-dichloro­phen­yl)prop-2-enoate
title_fullStr Methyl (2Z)-2-bromo­methyl-3-(2,4-dichloro­phen­yl)prop-2-enoate
title_full_unstemmed Methyl (2Z)-2-bromo­methyl-3-(2,4-dichloro­phen­yl)prop-2-enoate
title_short Methyl (2Z)-2-bromo­methyl-3-(2,4-dichloro­phen­yl)prop-2-enoate
title_sort methyl (2z)-2-bromo­methyl-3-(2,4-dichloro­phen­yl)prop-2-enoate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3629620/
https://www.ncbi.nlm.nih.gov/pubmed/23634107
http://dx.doi.org/10.1107/S1600536813007368
work_keys_str_mv AT swaminathank methyl2z2bromomethyl324dichlorophenylprop2enoate
AT sethusankark methyl2z2bromomethyl324dichlorophenylprop2enoate
AT devarajanthonisamy methyl2z2bromomethyl324dichlorophenylprop2enoate
AT bakthadossmanickam methyl2z2bromomethyl324dichlorophenylprop2enoate

Ejemplares similares