Piperazine-1,4-diium bis­(2,4,5-tricarb­oxy­benzoate) dihydrate

In the title hydrated salt, C(4)H(12)N(2) (2+)·2C(10)H(5)O(8) (−)·2H(2)O, the piperazinediium cation, lying about an inversion center, adopts a chair conformation. The benzene ring of the anion makes dihedral angles of 25.17 (8)° with the carboxyl­ate group and angles of 8.50 (7), 20.07 (7) and 80.8...

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Autores principales: Narayanam, Nagaraju, Gangu, Kranthi Kumar, Kurra, Balakrishna, Mukkamala, Saratchandra Babu
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3629622/
https://www.ncbi.nlm.nih.gov/pubmed/23634109
http://dx.doi.org/10.1107/S160053681300723X
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author Narayanam, Nagaraju
Gangu, Kranthi Kumar
Kurra, Balakrishna
Mukkamala, Saratchandra Babu
author_facet Narayanam, Nagaraju
Gangu, Kranthi Kumar
Kurra, Balakrishna
Mukkamala, Saratchandra Babu
author_sort Narayanam, Nagaraju
collection PubMed
description In the title hydrated salt, C(4)H(12)N(2) (2+)·2C(10)H(5)O(8) (−)·2H(2)O, the piperazinediium cation, lying about an inversion center, adopts a chair conformation. The benzene ring of the anion makes dihedral angles of 25.17 (8)° with the carboxyl­ate group and angles of 8.50 (7), 20.07 (7) and 80.86 (8)° with the three carb­oxy­lic acid groups. In the crystal, the cations, anions and water mol­ecules are connected by O—H⋯O and N—H⋯O hydrogen bonds into double layers parallel to (110).
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spelling pubmed-36296222013-04-30 Piperazine-1,4-diium bis­(2,4,5-tricarb­oxy­benzoate) dihydrate Narayanam, Nagaraju Gangu, Kranthi Kumar Kurra, Balakrishna Mukkamala, Saratchandra Babu Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title hydrated salt, C(4)H(12)N(2) (2+)·2C(10)H(5)O(8) (−)·2H(2)O, the piperazinediium cation, lying about an inversion center, adopts a chair conformation. The benzene ring of the anion makes dihedral angles of 25.17 (8)° with the carboxyl­ate group and angles of 8.50 (7), 20.07 (7) and 80.86 (8)° with the three carb­oxy­lic acid groups. In the crystal, the cations, anions and water mol­ecules are connected by O—H⋯O and N—H⋯O hydrogen bonds into double layers parallel to (110). International Union of Crystallography 2013-03-23 /pmc/articles/PMC3629622/ /pubmed/23634109 http://dx.doi.org/10.1107/S160053681300723X Text en © Narayanam et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Narayanam, Nagaraju
Gangu, Kranthi Kumar
Kurra, Balakrishna
Mukkamala, Saratchandra Babu
Piperazine-1,4-diium bis­(2,4,5-tricarb­oxy­benzoate) dihydrate
title Piperazine-1,4-diium bis­(2,4,5-tricarb­oxy­benzoate) dihydrate
title_full Piperazine-1,4-diium bis­(2,4,5-tricarb­oxy­benzoate) dihydrate
title_fullStr Piperazine-1,4-diium bis­(2,4,5-tricarb­oxy­benzoate) dihydrate
title_full_unstemmed Piperazine-1,4-diium bis­(2,4,5-tricarb­oxy­benzoate) dihydrate
title_short Piperazine-1,4-diium bis­(2,4,5-tricarb­oxy­benzoate) dihydrate
title_sort piperazine-1,4-diium bis­(2,4,5-tricarb­oxy­benzoate) dihydrate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3629622/
https://www.ncbi.nlm.nih.gov/pubmed/23634109
http://dx.doi.org/10.1107/S160053681300723X
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AT mukkamalasaratchandrababu piperazine14diiumbis245tricarboxybenzoatedihydrate

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