2-[3-(4-Chloro­phen­yl)-5-(4-fluoro­phenyl)-4,5-dihydro-1H-pyrazol-1-yl]-4-phenyl-1,3-thia­zole

In the title compound, C(24)H(17)ClFN(3)S, the pyrazole ring is almost planar (r.m.s. deviation = 0.030 Å). With the exception of the methine-bound benzene ring, which forms a dihedral angle of 85.77 (13)° with the pyrazole ring, the remaining non-C atoms lie in an approximate plane (r.m.s. deviatio...

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Autores principales: Abdel-Wahab, Bakr F., Ng, Seik Weng, Tiekink, Edward R. T.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3629623/
https://www.ncbi.nlm.nih.gov/pubmed/23634110
http://dx.doi.org/10.1107/S1600536813007496
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author Abdel-Wahab, Bakr F.
Ng, Seik Weng
Tiekink, Edward R. T.
author_facet Abdel-Wahab, Bakr F.
Ng, Seik Weng
Tiekink, Edward R. T.
author_sort Abdel-Wahab, Bakr F.
collection PubMed
description In the title compound, C(24)H(17)ClFN(3)S, the pyrazole ring is almost planar (r.m.s. deviation = 0.030 Å). With the exception of the methine-bound benzene ring, which forms a dihedral angle of 85.77 (13)° with the pyrazole ring, the remaining non-C atoms lie in an approximate plane (r.m.s. deviation = 0.084 Å) so that overall the mol­ecule has a T-shape. In the crystal, centrosymmetrically related mol­ecules are connected via π–π inter­actions between pyrazole rings [centroid–centroid distance = 3.5370 (15) Å] and these stack along the a axis with no specific inter­actions between them.
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spelling pubmed-36296232013-04-30 2-[3-(4-Chloro­phen­yl)-5-(4-fluoro­phenyl)-4,5-dihydro-1H-pyrazol-1-yl]-4-phenyl-1,3-thia­zole Abdel-Wahab, Bakr F. Ng, Seik Weng Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(24)H(17)ClFN(3)S, the pyrazole ring is almost planar (r.m.s. deviation = 0.030 Å). With the exception of the methine-bound benzene ring, which forms a dihedral angle of 85.77 (13)° with the pyrazole ring, the remaining non-C atoms lie in an approximate plane (r.m.s. deviation = 0.084 Å) so that overall the mol­ecule has a T-shape. In the crystal, centrosymmetrically related mol­ecules are connected via π–π inter­actions between pyrazole rings [centroid–centroid distance = 3.5370 (15) Å] and these stack along the a axis with no specific inter­actions between them. International Union of Crystallography 2013-03-23 /pmc/articles/PMC3629623/ /pubmed/23634110 http://dx.doi.org/10.1107/S1600536813007496 Text en © Abdel-Wahab et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Abdel-Wahab, Bakr F.
Ng, Seik Weng
Tiekink, Edward R. T.
2-[3-(4-Chloro­phen­yl)-5-(4-fluoro­phenyl)-4,5-dihydro-1H-pyrazol-1-yl]-4-phenyl-1,3-thia­zole
title 2-[3-(4-Chloro­phen­yl)-5-(4-fluoro­phenyl)-4,5-dihydro-1H-pyrazol-1-yl]-4-phenyl-1,3-thia­zole
title_full 2-[3-(4-Chloro­phen­yl)-5-(4-fluoro­phenyl)-4,5-dihydro-1H-pyrazol-1-yl]-4-phenyl-1,3-thia­zole
title_fullStr 2-[3-(4-Chloro­phen­yl)-5-(4-fluoro­phenyl)-4,5-dihydro-1H-pyrazol-1-yl]-4-phenyl-1,3-thia­zole
title_full_unstemmed 2-[3-(4-Chloro­phen­yl)-5-(4-fluoro­phenyl)-4,5-dihydro-1H-pyrazol-1-yl]-4-phenyl-1,3-thia­zole
title_short 2-[3-(4-Chloro­phen­yl)-5-(4-fluoro­phenyl)-4,5-dihydro-1H-pyrazol-1-yl]-4-phenyl-1,3-thia­zole
title_sort 2-[3-(4-chloro­phen­yl)-5-(4-fluoro­phenyl)-4,5-dihydro-1h-pyrazol-1-yl]-4-phenyl-1,3-thia­zole
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3629623/
https://www.ncbi.nlm.nih.gov/pubmed/23634110
http://dx.doi.org/10.1107/S1600536813007496
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AT ngseikweng 234chlorophenyl54fluorophenyl45dihydro1hpyrazol1yl4phenyl13thiazole
AT tiekinkedwardrt 234chlorophenyl54fluorophenyl45dihydro1hpyrazol1yl4phenyl13thiazole

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