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5,7-Dihy­droxy-2-(3-hy­droxy-4,5-dimeth­oxy­phen­yl)-6-meth­oxy-4H-chromen-4-one

The title compound, C(18)H(16)O(8), was isolated from the plant Artemisia baldshuanica Krasch et Zarp. The mol­ecule is approximately planar, with the exception of the terminal methyl groups, the C atoms of which devitate from their attached ring planes by 1.243 (5) and 1.168 (5) Å. The dihedral ang...

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Autores principales: Adizov, Shahobiddin M., Mukhamathanova, Rimma F., Turgunov, Kambarali K., Sham’yanov, Ildar D., Tashkhodjaev, Bakhodir
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3629625/
https://www.ncbi.nlm.nih.gov/pubmed/23634112
http://dx.doi.org/10.1107/S1600536813007381
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author Adizov, Shahobiddin M.
Mukhamathanova, Rimma F.
Turgunov, Kambarali K.
Sham’yanov, Ildar D.
Tashkhodjaev, Bakhodir
author_facet Adizov, Shahobiddin M.
Mukhamathanova, Rimma F.
Turgunov, Kambarali K.
Sham’yanov, Ildar D.
Tashkhodjaev, Bakhodir
author_sort Adizov, Shahobiddin M.
collection PubMed
description The title compound, C(18)H(16)O(8), was isolated from the plant Artemisia baldshuanica Krasch et Zarp. The mol­ecule is approximately planar, with the exception of the terminal methyl groups, the C atoms of which devitate from their attached ring planes by 1.243 (5) and 1.168 (5) Å. The dihedral angle between the substituted benzopyran and benzene rings is 5.8 (1)°; this near planarity could be due to conjugation or a packing effect. Intra­molecular O—H⋯O and C—H⋯O hydrogen bonds occur. In the crystal, mol­ecules are connected by O—H⋯O hydrogen bonds involving the hy­droxy and carbonyl groups, forming hydrogen-bonded chains along [001] and [1-10]. The chains are linked by C—H⋯O inter­actions.
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spelling pubmed-36296252013-04-30 5,7-Dihy­droxy-2-(3-hy­droxy-4,5-dimeth­oxy­phen­yl)-6-meth­oxy-4H-chromen-4-one Adizov, Shahobiddin M. Mukhamathanova, Rimma F. Turgunov, Kambarali K. Sham’yanov, Ildar D. Tashkhodjaev, Bakhodir Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(18)H(16)O(8), was isolated from the plant Artemisia baldshuanica Krasch et Zarp. The mol­ecule is approximately planar, with the exception of the terminal methyl groups, the C atoms of which devitate from their attached ring planes by 1.243 (5) and 1.168 (5) Å. The dihedral angle between the substituted benzopyran and benzene rings is 5.8 (1)°; this near planarity could be due to conjugation or a packing effect. Intra­molecular O—H⋯O and C—H⋯O hydrogen bonds occur. In the crystal, mol­ecules are connected by O—H⋯O hydrogen bonds involving the hy­droxy and carbonyl groups, forming hydrogen-bonded chains along [001] and [1-10]. The chains are linked by C—H⋯O inter­actions. International Union of Crystallography 2013-03-23 /pmc/articles/PMC3629625/ /pubmed/23634112 http://dx.doi.org/10.1107/S1600536813007381 Text en © Adizov et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Adizov, Shahobiddin M.
Mukhamathanova, Rimma F.
Turgunov, Kambarali K.
Sham’yanov, Ildar D.
Tashkhodjaev, Bakhodir
5,7-Dihy­droxy-2-(3-hy­droxy-4,5-dimeth­oxy­phen­yl)-6-meth­oxy-4H-chromen-4-one
title 5,7-Dihy­droxy-2-(3-hy­droxy-4,5-dimeth­oxy­phen­yl)-6-meth­oxy-4H-chromen-4-one
title_full 5,7-Dihy­droxy-2-(3-hy­droxy-4,5-dimeth­oxy­phen­yl)-6-meth­oxy-4H-chromen-4-one
title_fullStr 5,7-Dihy­droxy-2-(3-hy­droxy-4,5-dimeth­oxy­phen­yl)-6-meth­oxy-4H-chromen-4-one
title_full_unstemmed 5,7-Dihy­droxy-2-(3-hy­droxy-4,5-dimeth­oxy­phen­yl)-6-meth­oxy-4H-chromen-4-one
title_short 5,7-Dihy­droxy-2-(3-hy­droxy-4,5-dimeth­oxy­phen­yl)-6-meth­oxy-4H-chromen-4-one
title_sort 5,7-dihy­droxy-2-(3-hy­droxy-4,5-dimeth­oxy­phen­yl)-6-meth­oxy-4h-chromen-4-one
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3629625/
https://www.ncbi.nlm.nih.gov/pubmed/23634112
http://dx.doi.org/10.1107/S1600536813007381
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