Cargando…
5,7-Dihydroxy-2-(3-hydroxy-4,5-dimethoxyphenyl)-6-methoxy-4H-chromen-4-one
The title compound, C(18)H(16)O(8), was isolated from the plant Artemisia baldshuanica Krasch et Zarp. The molecule is approximately planar, with the exception of the terminal methyl groups, the C atoms of which devitate from their attached ring planes by 1.243 (5) and 1.168 (5) Å. The dihedral ang...
Autores principales: | , , , , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3629625/ https://www.ncbi.nlm.nih.gov/pubmed/23634112 http://dx.doi.org/10.1107/S1600536813007381 |
_version_ | 1782266617203261440 |
---|---|
author | Adizov, Shahobiddin M. Mukhamathanova, Rimma F. Turgunov, Kambarali K. Sham’yanov, Ildar D. Tashkhodjaev, Bakhodir |
author_facet | Adizov, Shahobiddin M. Mukhamathanova, Rimma F. Turgunov, Kambarali K. Sham’yanov, Ildar D. Tashkhodjaev, Bakhodir |
author_sort | Adizov, Shahobiddin M. |
collection | PubMed |
description | The title compound, C(18)H(16)O(8), was isolated from the plant Artemisia baldshuanica Krasch et Zarp. The molecule is approximately planar, with the exception of the terminal methyl groups, the C atoms of which devitate from their attached ring planes by 1.243 (5) and 1.168 (5) Å. The dihedral angle between the substituted benzopyran and benzene rings is 5.8 (1)°; this near planarity could be due to conjugation or a packing effect. Intramolecular O—H⋯O and C—H⋯O hydrogen bonds occur. In the crystal, molecules are connected by O—H⋯O hydrogen bonds involving the hydroxy and carbonyl groups, forming hydrogen-bonded chains along [001] and [1-10]. The chains are linked by C—H⋯O interactions. |
format | Online Article Text |
id | pubmed-3629625 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2013 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-36296252013-04-30 5,7-Dihydroxy-2-(3-hydroxy-4,5-dimethoxyphenyl)-6-methoxy-4H-chromen-4-one Adizov, Shahobiddin M. Mukhamathanova, Rimma F. Turgunov, Kambarali K. Sham’yanov, Ildar D. Tashkhodjaev, Bakhodir Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(18)H(16)O(8), was isolated from the plant Artemisia baldshuanica Krasch et Zarp. The molecule is approximately planar, with the exception of the terminal methyl groups, the C atoms of which devitate from their attached ring planes by 1.243 (5) and 1.168 (5) Å. The dihedral angle between the substituted benzopyran and benzene rings is 5.8 (1)°; this near planarity could be due to conjugation or a packing effect. Intramolecular O—H⋯O and C—H⋯O hydrogen bonds occur. In the crystal, molecules are connected by O—H⋯O hydrogen bonds involving the hydroxy and carbonyl groups, forming hydrogen-bonded chains along [001] and [1-10]. The chains are linked by C—H⋯O interactions. International Union of Crystallography 2013-03-23 /pmc/articles/PMC3629625/ /pubmed/23634112 http://dx.doi.org/10.1107/S1600536813007381 Text en © Adizov et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Adizov, Shahobiddin M. Mukhamathanova, Rimma F. Turgunov, Kambarali K. Sham’yanov, Ildar D. Tashkhodjaev, Bakhodir 5,7-Dihydroxy-2-(3-hydroxy-4,5-dimethoxyphenyl)-6-methoxy-4H-chromen-4-one |
title | 5,7-Dihydroxy-2-(3-hydroxy-4,5-dimethoxyphenyl)-6-methoxy-4H-chromen-4-one |
title_full | 5,7-Dihydroxy-2-(3-hydroxy-4,5-dimethoxyphenyl)-6-methoxy-4H-chromen-4-one |
title_fullStr | 5,7-Dihydroxy-2-(3-hydroxy-4,5-dimethoxyphenyl)-6-methoxy-4H-chromen-4-one |
title_full_unstemmed | 5,7-Dihydroxy-2-(3-hydroxy-4,5-dimethoxyphenyl)-6-methoxy-4H-chromen-4-one |
title_short | 5,7-Dihydroxy-2-(3-hydroxy-4,5-dimethoxyphenyl)-6-methoxy-4H-chromen-4-one |
title_sort | 5,7-dihydroxy-2-(3-hydroxy-4,5-dimethoxyphenyl)-6-methoxy-4h-chromen-4-one |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3629625/ https://www.ncbi.nlm.nih.gov/pubmed/23634112 http://dx.doi.org/10.1107/S1600536813007381 |
work_keys_str_mv | AT adizovshahobiddinm 57dihydroxy23hydroxy45dimethoxyphenyl6methoxy4hchromen4one AT mukhamathanovarimmaf 57dihydroxy23hydroxy45dimethoxyphenyl6methoxy4hchromen4one AT turgunovkambaralik 57dihydroxy23hydroxy45dimethoxyphenyl6methoxy4hchromen4one AT shamyanovildard 57dihydroxy23hydroxy45dimethoxyphenyl6methoxy4hchromen4one AT tashkhodjaevbakhodir 57dihydroxy23hydroxy45dimethoxyphenyl6methoxy4hchromen4one |