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1,3-Bis(2,3,5,6-tetrafluoro-4-iodophenoxy)-2,2-bis[(2,3,5,6-tetrafluoro-4-iodophenoxy)methyl]propane
In the crystal structure of the title compound, C(29)H(8)F(16)I(4)O(4), short I⋯I and I⋯F contacts, which can be understood as halogen bonds (XBs), represent the strongest intermolecular interactions, consistent with the presence of I and F atoms, and the absence of H atoms, at the periphery of th...
| Autores principales: | , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2013
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3629626/ https://www.ncbi.nlm.nih.gov/pubmed/23634113 http://dx.doi.org/10.1107/S1600536813007605 |
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| author | Cavallo, Gabriella Metrangolo, Pierangelo Pilati, Tullio Resnati, Giuseppe Terraneo, Giancarlo Ursini, Maurizio |
| author_facet | Cavallo, Gabriella Metrangolo, Pierangelo Pilati, Tullio Resnati, Giuseppe Terraneo, Giancarlo Ursini, Maurizio |
| author_sort | Cavallo, Gabriella |
| collection | PubMed |
| description | In the crystal structure of the title compound, C(29)H(8)F(16)I(4)O(4), short I⋯I and I⋯F contacts, which can be understood as halogen bonds (XBs), represent the strongest intermolecular interactions, consistent with the presence of I and F atoms, and the absence of H atoms, at the periphery of the molecule. In addition, π–π stacking interactions between tetrafluoroiodophenyl (TFIP) groups and five short F⋯F interactions are present. |
| format | Online Article Text |
| id | pubmed-3629626 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2013 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-36296262013-04-30 1,3-Bis(2,3,5,6-tetrafluoro-4-iodophenoxy)-2,2-bis[(2,3,5,6-tetrafluoro-4-iodophenoxy)methyl]propane Cavallo, Gabriella Metrangolo, Pierangelo Pilati, Tullio Resnati, Giuseppe Terraneo, Giancarlo Ursini, Maurizio Acta Crystallogr Sect E Struct Rep Online Organic Papers In the crystal structure of the title compound, C(29)H(8)F(16)I(4)O(4), short I⋯I and I⋯F contacts, which can be understood as halogen bonds (XBs), represent the strongest intermolecular interactions, consistent with the presence of I and F atoms, and the absence of H atoms, at the periphery of the molecule. In addition, π–π stacking interactions between tetrafluoroiodophenyl (TFIP) groups and five short F⋯F interactions are present. International Union of Crystallography 2013-03-23 /pmc/articles/PMC3629626/ /pubmed/23634113 http://dx.doi.org/10.1107/S1600536813007605 Text en © Cavallo et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Organic Papers Cavallo, Gabriella Metrangolo, Pierangelo Pilati, Tullio Resnati, Giuseppe Terraneo, Giancarlo Ursini, Maurizio 1,3-Bis(2,3,5,6-tetrafluoro-4-iodophenoxy)-2,2-bis[(2,3,5,6-tetrafluoro-4-iodophenoxy)methyl]propane |
| title | 1,3-Bis(2,3,5,6-tetrafluoro-4-iodophenoxy)-2,2-bis[(2,3,5,6-tetrafluoro-4-iodophenoxy)methyl]propane |
| title_full | 1,3-Bis(2,3,5,6-tetrafluoro-4-iodophenoxy)-2,2-bis[(2,3,5,6-tetrafluoro-4-iodophenoxy)methyl]propane |
| title_fullStr | 1,3-Bis(2,3,5,6-tetrafluoro-4-iodophenoxy)-2,2-bis[(2,3,5,6-tetrafluoro-4-iodophenoxy)methyl]propane |
| title_full_unstemmed | 1,3-Bis(2,3,5,6-tetrafluoro-4-iodophenoxy)-2,2-bis[(2,3,5,6-tetrafluoro-4-iodophenoxy)methyl]propane |
| title_short | 1,3-Bis(2,3,5,6-tetrafluoro-4-iodophenoxy)-2,2-bis[(2,3,5,6-tetrafluoro-4-iodophenoxy)methyl]propane |
| title_sort | 1,3-bis(2,3,5,6-tetrafluoro-4-iodophenoxy)-2,2-bis[(2,3,5,6-tetrafluoro-4-iodophenoxy)methyl]propane |
| topic | Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3629626/ https://www.ncbi.nlm.nih.gov/pubmed/23634113 http://dx.doi.org/10.1107/S1600536813007605 |
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