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1-{[4-(4-{[(2-Oxidonaphthalen-1-yl)methyl­idene]aza­nium­yl}phen­oxy)phen­yl]iminiumylmeth­yl}naphthalen-2-olate

The title Schiff base compound, C(34)H(24)N(2)O(3), was prepared by a condensation reaction of bifunctional aromatic diamine (4,4′-diamino­diphenyl ether) with hy­droxy­naphtaldehyde. The asymmetric unit contains two independent mol­ecules with similar conformations. The compound contains a central...

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Detalles Bibliográficos
Autores principales: Haffar, Djahida, Daoud, Djamel, Douadi, Tahar, Bouzidi, Leila, Chafaa, Salah
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3629627/
https://www.ncbi.nlm.nih.gov/pubmed/23634114
http://dx.doi.org/10.1107/S1600536813007307
Descripción
Sumario:The title Schiff base compound, C(34)H(24)N(2)O(3), was prepared by a condensation reaction of bifunctional aromatic diamine (4,4′-diamino­diphenyl ether) with hy­droxy­naphtaldehyde. The asymmetric unit contains two independent mol­ecules with similar conformations. The compound contains a central oxygen bridge and two functionalized [(E)-(phenyl­iminio)meth­yl]naphthalen-2-olate units. The dihedral angles between the benzene rings linking to the central O atom are 74.64 (19) and 69.85 (18)° in the two independent mol­ecules. Intra­molecular O—H⋯O hydrogen bonding occurs between the protonated imino N atoms and deprotonated hy­droxy O atoms in both mol­ecules. In the crystal, weak C—H⋯O hydrogen bonds are observed.