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1-{[4-(4-{[(2-Oxidonaphthalen-1-yl)methylidene]azaniumyl}phenoxy)phenyl]iminiumylmethyl}naphthalen-2-olate
The title Schiff base compound, C(34)H(24)N(2)O(3), was prepared by a condensation reaction of bifunctional aromatic diamine (4,4′-diaminodiphenyl ether) with hydroxynaphtaldehyde. The asymmetric unit contains two independent molecules with similar conformations. The compound contains a central...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3629627/ https://www.ncbi.nlm.nih.gov/pubmed/23634114 http://dx.doi.org/10.1107/S1600536813007307 |
Sumario: | The title Schiff base compound, C(34)H(24)N(2)O(3), was prepared by a condensation reaction of bifunctional aromatic diamine (4,4′-diaminodiphenyl ether) with hydroxynaphtaldehyde. The asymmetric unit contains two independent molecules with similar conformations. The compound contains a central oxygen bridge and two functionalized [(E)-(phenyliminio)methyl]naphthalen-2-olate units. The dihedral angles between the benzene rings linking to the central O atom are 74.64 (19) and 69.85 (18)° in the two independent molecules. Intramolecular O—H⋯O hydrogen bonding occurs between the protonated imino N atoms and deprotonated hydroxy O atoms in both molecules. In the crystal, weak C—H⋯O hydrogen bonds are observed. |
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