7-Iodo-3,3-diphenyl­octa­hydro­benzo­furan

The title compound, C(20)H(21)IO, was synthesized by cyclo­haloetherification of 2-(cyclo­hex-2-en­yl)-2,2-diphenyl­ethanol in CH(2)Cl(2), and crystallized with two independent mol­ecules in the asymmetric unit. The six-membered cyclo­hexane ring adopts a chair conformation, while the five-membered...

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Detalles Bibliográficos
Autores principales: Sohail, Muhammad, Yao-Feng, Wang, Qi, Wang, Chen, Fu-Xue
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3629630/
https://www.ncbi.nlm.nih.gov/pubmed/23634117
http://dx.doi.org/10.1107/S1600536813007563
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author Sohail, Muhammad
Yao-Feng, Wang
Qi, Wang
Chen, Fu-Xue
author_facet Sohail, Muhammad
Yao-Feng, Wang
Qi, Wang
Chen, Fu-Xue
author_sort Sohail, Muhammad
collection PubMed
description The title compound, C(20)H(21)IO, was synthesized by cyclo­haloetherification of 2-(cyclo­hex-2-en­yl)-2,2-diphenyl­ethanol in CH(2)Cl(2), and crystallized with two independent mol­ecules in the asymmetric unit. The six-membered cyclo­hexane ring adopts a chair conformation, while the five-membered ring adopts an envelope conformation with the fused C atom opposite the O atom as the flap in each case [displacements of the flap atoms = 0.6813 (3) and 0.6679 (3) Å]. In the crystal, mol­ecules are linked via pairs of C—H⋯π inter­actions, forming inversion dimers.
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spelling pubmed-36296302013-04-30 7-Iodo-3,3-diphenyl­octa­hydro­benzo­furan Sohail, Muhammad Yao-Feng, Wang Qi, Wang Chen, Fu-Xue Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(20)H(21)IO, was synthesized by cyclo­haloetherification of 2-(cyclo­hex-2-en­yl)-2,2-diphenyl­ethanol in CH(2)Cl(2), and crystallized with two independent mol­ecules in the asymmetric unit. The six-membered cyclo­hexane ring adopts a chair conformation, while the five-membered ring adopts an envelope conformation with the fused C atom opposite the O atom as the flap in each case [displacements of the flap atoms = 0.6813 (3) and 0.6679 (3) Å]. In the crystal, mol­ecules are linked via pairs of C—H⋯π inter­actions, forming inversion dimers. International Union of Crystallography 2013-03-23 /pmc/articles/PMC3629630/ /pubmed/23634117 http://dx.doi.org/10.1107/S1600536813007563 Text en © Sohail et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Sohail, Muhammad
Yao-Feng, Wang
Qi, Wang
Chen, Fu-Xue
7-Iodo-3,3-diphenyl­octa­hydro­benzo­furan
title 7-Iodo-3,3-diphenyl­octa­hydro­benzo­furan
title_full 7-Iodo-3,3-diphenyl­octa­hydro­benzo­furan
title_fullStr 7-Iodo-3,3-diphenyl­octa­hydro­benzo­furan
title_full_unstemmed 7-Iodo-3,3-diphenyl­octa­hydro­benzo­furan
title_short 7-Iodo-3,3-diphenyl­octa­hydro­benzo­furan
title_sort 7-iodo-3,3-diphenyl­octa­hydro­benzo­furan
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3629630/
https://www.ncbi.nlm.nih.gov/pubmed/23634117
http://dx.doi.org/10.1107/S1600536813007563
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