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(2E)-2-(3-Eth­oxy-2-hy­droxy­benzyl­idene)hydrazinecarboxamide

The title compound, C(10)H(13)N(3)O(3), adopts an E conformation with respect to the azomethine bond and crystallizes in the amide form. A classical intra­molecular O—H⋯N hydrogen bond is present. The two N atoms of the hydrazinecarboxamide unit are also involved in inter­molecular N—H⋯O hydrogen bo...

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Autores principales: Aravindakshan, A. Ambili, Sithambaresan, M., Kurup, M. R. Prathapachandra
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3629631/
https://www.ncbi.nlm.nih.gov/pubmed/23634118
http://dx.doi.org/10.1107/S1600536813007617
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author Aravindakshan, A. Ambili
Sithambaresan, M.
Kurup, M. R. Prathapachandra
author_facet Aravindakshan, A. Ambili
Sithambaresan, M.
Kurup, M. R. Prathapachandra
author_sort Aravindakshan, A. Ambili
collection PubMed
description The title compound, C(10)H(13)N(3)O(3), adopts an E conformation with respect to the azomethine bond and crystallizes in the amide form. A classical intra­molecular O—H⋯N hydrogen bond is present. The two N atoms of the hydrazinecarboxamide unit are also involved in inter­molecular N—H⋯O hydrogen bonds, with the O atom of the hydrazinecarboxamide group acting as the acceptor. Pairs of N—H⋯O hydrogen bond link the mol­ecules into centrosymmetric dimers, which are linked by further N—H⋯O hydrogen bonds into chains along the b axis. The chains are linked by C—H⋯π inter­actions.
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spelling pubmed-36296312013-04-30 (2E)-2-(3-Eth­oxy-2-hy­droxy­benzyl­idene)hydrazinecarboxamide Aravindakshan, A. Ambili Sithambaresan, M. Kurup, M. R. Prathapachandra Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(10)H(13)N(3)O(3), adopts an E conformation with respect to the azomethine bond and crystallizes in the amide form. A classical intra­molecular O—H⋯N hydrogen bond is present. The two N atoms of the hydrazinecarboxamide unit are also involved in inter­molecular N—H⋯O hydrogen bonds, with the O atom of the hydrazinecarboxamide group acting as the acceptor. Pairs of N—H⋯O hydrogen bond link the mol­ecules into centrosymmetric dimers, which are linked by further N—H⋯O hydrogen bonds into chains along the b axis. The chains are linked by C—H⋯π inter­actions. International Union of Crystallography 2013-03-23 /pmc/articles/PMC3629631/ /pubmed/23634118 http://dx.doi.org/10.1107/S1600536813007617 Text en © Aravindakshan et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Aravindakshan, A. Ambili
Sithambaresan, M.
Kurup, M. R. Prathapachandra
(2E)-2-(3-Eth­oxy-2-hy­droxy­benzyl­idene)hydrazinecarboxamide
title (2E)-2-(3-Eth­oxy-2-hy­droxy­benzyl­idene)hydrazinecarboxamide
title_full (2E)-2-(3-Eth­oxy-2-hy­droxy­benzyl­idene)hydrazinecarboxamide
title_fullStr (2E)-2-(3-Eth­oxy-2-hy­droxy­benzyl­idene)hydrazinecarboxamide
title_full_unstemmed (2E)-2-(3-Eth­oxy-2-hy­droxy­benzyl­idene)hydrazinecarboxamide
title_short (2E)-2-(3-Eth­oxy-2-hy­droxy­benzyl­idene)hydrazinecarboxamide
title_sort (2e)-2-(3-eth­oxy-2-hy­droxy­benzyl­idene)hydrazinecarboxamide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3629631/
https://www.ncbi.nlm.nih.gov/pubmed/23634118
http://dx.doi.org/10.1107/S1600536813007617
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