Cargando…
(2E)-2-(3-Ethoxy-2-hydroxybenzylidene)hydrazinecarboxamide
The title compound, C(10)H(13)N(3)O(3), adopts an E conformation with respect to the azomethine bond and crystallizes in the amide form. A classical intramolecular O—H⋯N hydrogen bond is present. The two N atoms of the hydrazinecarboxamide unit are also involved in intermolecular N—H⋯O hydrogen bo...
Autores principales: | , , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3629631/ https://www.ncbi.nlm.nih.gov/pubmed/23634118 http://dx.doi.org/10.1107/S1600536813007617 |
_version_ | 1782266618544390144 |
---|---|
author | Aravindakshan, A. Ambili Sithambaresan, M. Kurup, M. R. Prathapachandra |
author_facet | Aravindakshan, A. Ambili Sithambaresan, M. Kurup, M. R. Prathapachandra |
author_sort | Aravindakshan, A. Ambili |
collection | PubMed |
description | The title compound, C(10)H(13)N(3)O(3), adopts an E conformation with respect to the azomethine bond and crystallizes in the amide form. A classical intramolecular O—H⋯N hydrogen bond is present. The two N atoms of the hydrazinecarboxamide unit are also involved in intermolecular N—H⋯O hydrogen bonds, with the O atom of the hydrazinecarboxamide group acting as the acceptor. Pairs of N—H⋯O hydrogen bond link the molecules into centrosymmetric dimers, which are linked by further N—H⋯O hydrogen bonds into chains along the b axis. The chains are linked by C—H⋯π interactions. |
format | Online Article Text |
id | pubmed-3629631 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2013 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-36296312013-04-30 (2E)-2-(3-Ethoxy-2-hydroxybenzylidene)hydrazinecarboxamide Aravindakshan, A. Ambili Sithambaresan, M. Kurup, M. R. Prathapachandra Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(10)H(13)N(3)O(3), adopts an E conformation with respect to the azomethine bond and crystallizes in the amide form. A classical intramolecular O—H⋯N hydrogen bond is present. The two N atoms of the hydrazinecarboxamide unit are also involved in intermolecular N—H⋯O hydrogen bonds, with the O atom of the hydrazinecarboxamide group acting as the acceptor. Pairs of N—H⋯O hydrogen bond link the molecules into centrosymmetric dimers, which are linked by further N—H⋯O hydrogen bonds into chains along the b axis. The chains are linked by C—H⋯π interactions. International Union of Crystallography 2013-03-23 /pmc/articles/PMC3629631/ /pubmed/23634118 http://dx.doi.org/10.1107/S1600536813007617 Text en © Aravindakshan et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Aravindakshan, A. Ambili Sithambaresan, M. Kurup, M. R. Prathapachandra (2E)-2-(3-Ethoxy-2-hydroxybenzylidene)hydrazinecarboxamide |
title | (2E)-2-(3-Ethoxy-2-hydroxybenzylidene)hydrazinecarboxamide |
title_full | (2E)-2-(3-Ethoxy-2-hydroxybenzylidene)hydrazinecarboxamide |
title_fullStr | (2E)-2-(3-Ethoxy-2-hydroxybenzylidene)hydrazinecarboxamide |
title_full_unstemmed | (2E)-2-(3-Ethoxy-2-hydroxybenzylidene)hydrazinecarboxamide |
title_short | (2E)-2-(3-Ethoxy-2-hydroxybenzylidene)hydrazinecarboxamide |
title_sort | (2e)-2-(3-ethoxy-2-hydroxybenzylidene)hydrazinecarboxamide |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3629631/ https://www.ncbi.nlm.nih.gov/pubmed/23634118 http://dx.doi.org/10.1107/S1600536813007617 |
work_keys_str_mv | AT aravindakshanaambili 2e23ethoxy2hydroxybenzylidenehydrazinecarboxamide AT sithambaresanm 2e23ethoxy2hydroxybenzylidenehydrazinecarboxamide AT kurupmrprathapachandra 2e23ethoxy2hydroxybenzylidenehydrazinecarboxamide |