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2,2-Dichloro-3,7,7,11-tetramethyl-10-azatetracyclo[6.5.0.0(1,3).0(9,11)]tridecane
The title compound, C(16)H(25)Cl(2)N, was synthesized from β-himachalene (3,5,5,9-tetramethyl-2,4a,5,6,7,8-hexahydro-1H-benzocycloheptene), which was isolated from the essential oil of the Atlas cedar (Cedrus Atlantica). The molecule is built up from fused six- and seven-membered rings linked to...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
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International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3629633/ https://www.ncbi.nlm.nih.gov/pubmed/23634120 http://dx.doi.org/10.1107/S1600536813007642 |
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author | Oukhrib, Abdelouahd Benharref, Ahmed Saadi, Mohamed Berraho, Moha El Ammari, Lahcen |
author_facet | Oukhrib, Abdelouahd Benharref, Ahmed Saadi, Mohamed Berraho, Moha El Ammari, Lahcen |
author_sort | Oukhrib, Abdelouahd |
collection | PubMed |
description | The title compound, C(16)H(25)Cl(2)N, was synthesized from β-himachalene (3,5,5,9-tetramethyl-2,4a,5,6,7,8-hexahydro-1H-benzocycloheptene), which was isolated from the essential oil of the Atlas cedar (Cedrus Atlantica). The molecule is built up from fused six- and seven-membered rings linked to two three-membered rings. The six-membered ring shows a half-chair conformation, whereas the seven-membered ring displays a boat conformation. The dihedral angle between the mean planes through the six- and seven-membered rings is 59.8 (2)°. The two three-membered rings lie to one side and each is nearly perpendicular to the six-membered ring, forming dihedral angles of 83.2 (2) and 86.0 (2)°. The absolute structure was established unambiguously from anomalous dispersion effects. No specific intermolecular interactions are noted in the crystal structure. |
format | Online Article Text |
id | pubmed-3629633 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2013 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-36296332013-04-30 2,2-Dichloro-3,7,7,11-tetramethyl-10-azatetracyclo[6.5.0.0(1,3).0(9,11)]tridecane Oukhrib, Abdelouahd Benharref, Ahmed Saadi, Mohamed Berraho, Moha El Ammari, Lahcen Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(16)H(25)Cl(2)N, was synthesized from β-himachalene (3,5,5,9-tetramethyl-2,4a,5,6,7,8-hexahydro-1H-benzocycloheptene), which was isolated from the essential oil of the Atlas cedar (Cedrus Atlantica). The molecule is built up from fused six- and seven-membered rings linked to two three-membered rings. The six-membered ring shows a half-chair conformation, whereas the seven-membered ring displays a boat conformation. The dihedral angle between the mean planes through the six- and seven-membered rings is 59.8 (2)°. The two three-membered rings lie to one side and each is nearly perpendicular to the six-membered ring, forming dihedral angles of 83.2 (2) and 86.0 (2)°. The absolute structure was established unambiguously from anomalous dispersion effects. No specific intermolecular interactions are noted in the crystal structure. International Union of Crystallography 2013-03-28 /pmc/articles/PMC3629633/ /pubmed/23634120 http://dx.doi.org/10.1107/S1600536813007642 Text en © Oukhrib et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Oukhrib, Abdelouahd Benharref, Ahmed Saadi, Mohamed Berraho, Moha El Ammari, Lahcen 2,2-Dichloro-3,7,7,11-tetramethyl-10-azatetracyclo[6.5.0.0(1,3).0(9,11)]tridecane |
title | 2,2-Dichloro-3,7,7,11-tetramethyl-10-azatetracyclo[6.5.0.0(1,3).0(9,11)]tridecane |
title_full | 2,2-Dichloro-3,7,7,11-tetramethyl-10-azatetracyclo[6.5.0.0(1,3).0(9,11)]tridecane |
title_fullStr | 2,2-Dichloro-3,7,7,11-tetramethyl-10-azatetracyclo[6.5.0.0(1,3).0(9,11)]tridecane |
title_full_unstemmed | 2,2-Dichloro-3,7,7,11-tetramethyl-10-azatetracyclo[6.5.0.0(1,3).0(9,11)]tridecane |
title_short | 2,2-Dichloro-3,7,7,11-tetramethyl-10-azatetracyclo[6.5.0.0(1,3).0(9,11)]tridecane |
title_sort | 2,2-dichloro-3,7,7,11-tetramethyl-10-azatetracyclo[6.5.0.0(1,3).0(9,11)]tridecane |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3629633/ https://www.ncbi.nlm.nih.gov/pubmed/23634120 http://dx.doi.org/10.1107/S1600536813007642 |
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