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2,2-Dichloro-3,7,7,11-tetra­methyl-10-aza­tetra­cyclo­[6.5.0.0(1,3).0(9,11)]trideca­ne

The title compound, C(16)H(25)Cl(2)N, was synthesized from β-himachalene (3,5,5,9-tetra­methyl-2,4a,5,6,7,8-hexa­hydro-1H-benzocyclo­heptene), which was isolated from the essential oil of the Atlas cedar (Cedrus Atlantica). The mol­ecule is built up from fused six- and seven-membered rings linked to...

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Autores principales: Oukhrib, Abdelouahd, Benharref, Ahmed, Saadi, Mohamed, Berraho, Moha, El Ammari, Lahcen
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3629633/
https://www.ncbi.nlm.nih.gov/pubmed/23634120
http://dx.doi.org/10.1107/S1600536813007642
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author Oukhrib, Abdelouahd
Benharref, Ahmed
Saadi, Mohamed
Berraho, Moha
El Ammari, Lahcen
author_facet Oukhrib, Abdelouahd
Benharref, Ahmed
Saadi, Mohamed
Berraho, Moha
El Ammari, Lahcen
author_sort Oukhrib, Abdelouahd
collection PubMed
description The title compound, C(16)H(25)Cl(2)N, was synthesized from β-himachalene (3,5,5,9-tetra­methyl-2,4a,5,6,7,8-hexa­hydro-1H-benzocyclo­heptene), which was isolated from the essential oil of the Atlas cedar (Cedrus Atlantica). The mol­ecule is built up from fused six- and seven-membered rings linked to two three-membered rings. The six-membered ring shows a half-chair conformation, whereas the seven-membered ring displays a boat conformation. The dihedral angle between the mean planes through the six- and seven-membered rings is 59.8 (2)°. The two three-membered rings lie to one side and each is nearly perpendicular to the six-membered ring, forming dihedral angles of 83.2 (2) and 86.0 (2)°. The absolute structure was established unambiguously from anomalous dispersion effects. No specific inter­molecular inter­actions are noted in the crystal structure.
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spelling pubmed-36296332013-04-30 2,2-Dichloro-3,7,7,11-tetra­methyl-10-aza­tetra­cyclo­[6.5.0.0(1,3).0(9,11)]trideca­ne Oukhrib, Abdelouahd Benharref, Ahmed Saadi, Mohamed Berraho, Moha El Ammari, Lahcen Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(16)H(25)Cl(2)N, was synthesized from β-himachalene (3,5,5,9-tetra­methyl-2,4a,5,6,7,8-hexa­hydro-1H-benzocyclo­heptene), which was isolated from the essential oil of the Atlas cedar (Cedrus Atlantica). The mol­ecule is built up from fused six- and seven-membered rings linked to two three-membered rings. The six-membered ring shows a half-chair conformation, whereas the seven-membered ring displays a boat conformation. The dihedral angle between the mean planes through the six- and seven-membered rings is 59.8 (2)°. The two three-membered rings lie to one side and each is nearly perpendicular to the six-membered ring, forming dihedral angles of 83.2 (2) and 86.0 (2)°. The absolute structure was established unambiguously from anomalous dispersion effects. No specific inter­molecular inter­actions are noted in the crystal structure. International Union of Crystallography 2013-03-28 /pmc/articles/PMC3629633/ /pubmed/23634120 http://dx.doi.org/10.1107/S1600536813007642 Text en © Oukhrib et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Oukhrib, Abdelouahd
Benharref, Ahmed
Saadi, Mohamed
Berraho, Moha
El Ammari, Lahcen
2,2-Dichloro-3,7,7,11-tetra­methyl-10-aza­tetra­cyclo­[6.5.0.0(1,3).0(9,11)]trideca­ne
title 2,2-Dichloro-3,7,7,11-tetra­methyl-10-aza­tetra­cyclo­[6.5.0.0(1,3).0(9,11)]trideca­ne
title_full 2,2-Dichloro-3,7,7,11-tetra­methyl-10-aza­tetra­cyclo­[6.5.0.0(1,3).0(9,11)]trideca­ne
title_fullStr 2,2-Dichloro-3,7,7,11-tetra­methyl-10-aza­tetra­cyclo­[6.5.0.0(1,3).0(9,11)]trideca­ne
title_full_unstemmed 2,2-Dichloro-3,7,7,11-tetra­methyl-10-aza­tetra­cyclo­[6.5.0.0(1,3).0(9,11)]trideca­ne
title_short 2,2-Dichloro-3,7,7,11-tetra­methyl-10-aza­tetra­cyclo­[6.5.0.0(1,3).0(9,11)]trideca­ne
title_sort 2,2-dichloro-3,7,7,11-tetra­methyl-10-aza­tetra­cyclo­[6.5.0.0(1,3).0(9,11)]trideca­ne
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3629633/
https://www.ncbi.nlm.nih.gov/pubmed/23634120
http://dx.doi.org/10.1107/S1600536813007642
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